Abstract
The model of the grain boundary structure in terms of intrinsic dislocation networks does not enable to satisfactorily account for grain boundary energy and functional property differences. It does not take into account the five microscopic degrees of freedom and the local relaxations that lead to more stable structures. Furthermore, it does not consider the different types of bonding between atoms depending on the metallic, ionic or covalent crystal character.
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Priester, L. (2013). Atomic Order of Grain Boundaries. In: Grain Boundaries. Springer Series in Materials Science, vol 172. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4969-6_3
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