Skip to main content

Effect of pH on the Floatability of Base Metal Sulphides PGMs

  • Chapter
  • First Online:
IAENG Transactions on Engineering Technologies

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 170))

Abstract

This study investigated the effect of pH on the recovery and grade of the Platinum Group Metals (PGMs) and base metal sulphides from the UG2 ore of the bushveld complex. This was achieved through running a series of test work in a Denver flotation cell at varying pH 6–11 at constant reagent dosage. The UG-2 reef is characterized by two predominant gangue phases i.e., chromite and silicate, that have significantly different physical and chemical properties. The test work was aimed at evaluating which pH produces the best recoveries, and finding the effect of the chrome content in these recoveries. A pH of 9 produced the highest recovery compared to other pH values. However, the highest PGM grade was attained at a pH of 6 which is slightly acidic. Ideally this trend could be expected since the collectors (xanthates) are more stable in alkaline medium. The higher PGM recovery was also accompanied by higher chrome content as a result of their similar chemical properties.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Muzenda E, Afolabi AS, Ntuli F, Abdulkareem AS (2011) Lecture notes in engineering and computer science. In: Proceedings of the world congress on engineering and computer science 2011, WCECS, San Francisco, USA, pp 609–612, 19–21 October 2011

    Google Scholar 

  2. Fuerstenau DW (1982) Mineral-water interfaces and the electrical double layer, in: principles of flotation. In: King RP (ed) (SAIMM, Monograph, Johannesburg Series, 1982) pp 17–30

    Google Scholar 

  3. Wills BA, Napier-Munn T (2006) Wills’ mineral processing technology: an introduction to the practical aspects of ore treatment and mineral recovery (Butterworth-Heinemann 2006). Elsevier Publisher, Great Britain

    Google Scholar 

  4. Tasdemir A, Tasdemir T, Oteyaka B (2007) The effect of particle size and some operating parameters in the separation tank and the downcomer on the Jameson cell recovery. Miner Eng 20:1331–1336

    Article  Google Scholar 

  5. Fredriksson A, Holmgren A, Forsling W (2006) Kinetics of collector adsorption on mineral surface. Miner Eng 19:6–8

    Article  Google Scholar 

  6. Wills BA, Napier-Munn T (1997) Wills’ mineral processing technology: An introduction to the practical aspects of ore treatment and mineral recovery 7th edn. Elsevier, Great Britain

    Google Scholar 

  7. Wiese J, Harris P, Bradshaw D (2005) The influence of reagent suite in the flotation of ores from the Merensky reef. Miner Eng 18:189–198

    Article  Google Scholar 

  8. Wiese J, Harris P, Bradshaw D (2005) Investigation of the role and interactions of dithiophosphate collector in the flotation of sulphides from the Merensky reef. Miner Eng 18:792–800

    Google Scholar 

  9. Wiese J, Harris P, Bradshaw D (2006) The role of reagent suite in optimizing pentlandite recoveries from the Merensky reef. Miner Eng 19:1290–1300

    Article  Google Scholar 

  10. Kelebek S, Demir U, Sahbaz O, Ucar A, Cinar M, Karaguzel O, Oteyaka B (2008) The effect of dodecylamine, kerosene and pH on batch flotation of Turkey’s Tuncbilek coal. Int J Miner Process 88:3–4

    Article  Google Scholar 

  11. Harris PJ (1982) Principles of flotation: mineral-water interfaces and the electrical double layer. S Afr Inst Min Metall 3:237

    Google Scholar 

  12. Hughes TC (2005) AM-2 a hydroxamate flotation collector reagent for oxides and oxide mineral systems. vol 3. Aust J Min, 58–59

    Google Scholar 

  13. Bruckard WJ, Kyriakidis I, Woodcock JT (2007) The flotation of metallic arsenic as a function of pH and pulp potential—a single mineral study. Int J Miner Process 84:1–4

    Article  Google Scholar 

  14. Peyerl W (1983) The metallurgical implications of the mode of occurrence of platinum group metals in Merensky reef and UG2 chromitite of the Bushveld igneous complex, vol 7. Special Publication of Geology Society of South Africa, South Africa pp 295–300

    Google Scholar 

  15. Schouwstra P, Kinloch ED (2000) A short geological review of the Bushveld complex. Amplats Research Centre, South Africa

    Google Scholar 

  16. Ballhaus C, Sylvester P (2000) PGE enrichment processes in the Merensky reef. J Petroleum 41:454–561

    Google Scholar 

  17. Cawthorn RG, Merkle RKW, Viljoen MV (2002) Platinum—group elements deposits in the Bushveld complex, South Africa. In: Cabri LJ (ed) The geology, geochemistry, mineralogy, mineral benefiation of the platinum group elements, vol 54. Canadian Institute of Mining, Metallurgy and Petroleum, Canada pp 389–430

    Google Scholar 

  18. Cilek EC (2009) The effect of Hydrodynamic conditions on true flotation and intrainment flotation of complex sulphide ore. Int J Miner Process 90(1–4):34–44

    Google Scholar 

  19. Viljo AM, Viljoen B, Van Wyk E, Van Heerden FR (1998) Distribution and chemotaxonomic significance of flavonoids in Aloe (Asphodelaceae). Plant Syst Evol 211:31–42

    Article  Google Scholar 

  20. Valenta MM (2007) Balancing the reagent suite to optimize grade and recovery. Miner Eng 20(10):1–6

    Article  Google Scholar 

  21. Wiese J, Harris P, Bradshaw D (2007) The response of sulphide and gangue minerals in selected Merensky ores to increased depressant dosages. Miner Eng 20:986–995

    Article  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the financial supports of the National Research Foundation (NRF) and Universities of South Africa and Johannesburg.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ayo Samuel Afolabi .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Afolabi, A.S., Muzenda, E., Abdulkareem, S.A. (2013). Effect of pH on the Floatability of Base Metal Sulphides PGMs. In: Kim, H., Ao, SI., Rieger, B. (eds) IAENG Transactions on Engineering Technologies. Lecture Notes in Electrical Engineering, vol 170. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4786-9_19

Download citation

  • DOI: https://doi.org/10.1007/978-94-007-4786-9_19

  • Published:

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-007-4785-2

  • Online ISBN: 978-94-007-4786-9

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics