Abstract
Laser ablation of iron in an organic solvent (pentane, hexane, or decane) was performed using an air-tight cell to produce iron carbide nanoparticles. Mössbauer spectra of the nanoparticles were obtained at room temperature. They revealed that the nanoparticles consisted of two paramagnetic components and magnetic components. The two paramagnetic components were a high-spin Fe(II) species and an amorphous iron carbide containing a large amount of carbon. Whereas the magnetic components measured at room temperature exhibited superparamagnetism, those measured at low temperature were fitted by a combination of four sextets, which were assigned to Fe7 C 3. The Fe7 C 3 yield was higher in higher molecular weight solvents. Transmission electron microscopy (TEM) images of the samples showed that the nanoparticles were spherical with diameters in the range 10–100 nm.
This is a preview of subscription content, log in via an institution.
Preview
Unable to display preview. Download preview PDF.
References
Pérez-Cabero, M., Taboada, J.B., Guerrero-Ruiz, A., Overweg A.R., Rodríguez-Ramos, I.: Phys. Chem. Chem. Phys. 8, 1230 (2006)
de Resende, V., De Grave, E., Peigney A., Laurent, C.: J. Phys. Chem. C 112, 5756 (2008)
Kopelev, N., Chechersky, V., Nath, A., Wang, Z.L., Kuzmann, E., Zhang, B., Via, G.H.: Chem. Mater. 7, 1419–1421 (1995)
David, B., Pizúrová, N., Schneeweiss, O., Bezdička, P., Morjan, I., Alexandrescu, R.: J. Alloys Compd. 378, 112–116 (2004)
Bi, X.-X., Ganguly, B., Huffman, G., Huggins F., Endo, M.: Mater J. Res. 8, 1666 (1993)
Tanaka, T., Nasu, S., Ishihara, K.N., Shingu, P.H.: J. Less Common Met. 171, 237 (1991)
Mafune, F., Kondow, T.: Chem. Phys. Lett. 372, 199 (2003)
Tarasenko, N.V., Butsun, A.V., Nevar, E.A., Savastenko, N.A.: Appl. Surf. Sci. 252, 4439 (2006)
Yeh, Y., Yeh, M., Lee, Y., Yeh, C.: Chem. Lett. 1998, 1183 (1998)
Yamada, Y., Yoshida, H., Kouno, K.: J. Phys. Conf. Ser. 217, 012096 (2010)
Wickman H.H., Wertheim, G.K.: In: Goldanski V.I., Herber, R.H. (eds.) Chemical applications of Mössbauer spectroscopy, chapter 11. Academic Press Inc., New York (1968)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer Science+Business Media B.V.
About this paper
Cite this paper
Matsue, T., Yamada, Y., Kobayashi, Y. (2013). Iron carbide nanoparticles produced by laser ablation in organic solvent. In: Yoshida, Y. (eds) ICAME 2011. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4762-3_27
Download citation
DOI: https://doi.org/10.1007/978-94-007-4762-3_27
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-4761-6
Online ISBN: 978-94-007-4762-3
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)