Abstract
Étang Saumâtre (also known as Lac Azuéi, Lago del Fondo, or Yainagua) is a brackish lake located in eastern Haiti. Sources of irrigation and drinking water for the surrounding communities in Thomazeau, Ganthier, and Fond Parisien are freshwater springs and shallow wells tapping the complex fractured aquifer system surrounding Étang Saumâtre. In some groundwater samples, we found concentrations of trace metals exceeding World Health Organization guideline values. Lake sediment trace metal concentrations were also high. For example, chromium (Cr) ranged from 26.24 to 198.44 mg/kg, exceeding the USEPA sediment quality guideline value for heavily polluted. High concentrations of potentially toxic trace metals in both lake sediments and groundwater suggest that the population relying on this lake for drinking water, irrigation, and subsistence fishing may be at risk for metal-induced health effects. By understanding the geochemical behavior of redox-sensitive trace metals such as Cr, in the context of limnology and long-term fate and transport within the system, our results provide unique insights into the geochemical controls on remobilization of redox metals from the sediments and the potential impact of future environmental change on the sediment and water quality in this system.
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References
Allen MR, Ingram WJ (2002) Constraints on future changes in climate and the hydrologic cycle. Nature 419(6903):224–232
Atkins PW (2006) Shriver and Atkins inorganic chemistry. Oxford University Press, Oxford
Binfordll MW, Dorsey KT (1991) Reconstruction of Caribbean climate change over the past 10,500 years. Nature 352:29
Bueno R et al (2008) The Caribbean and climate change: the costs of inaction. Tufts University, Medford. Accessed, 10(09). http://ase.tufts.edu/gdae/Pubs/rp/Caribbean-full-Eng.pdf
Calais E et al (2010) Transpressional rupture of an unmapped fault during the 2010 Haiti earthquake. Nat Geosci 3(11):794–799
Carpenter SR et al (1998) Nonpoint pollution of surface waters with phosphorus and nitrogen. Ecol Appl 8(3):559–568
Dieter H (2011) Drinking water toxicology in its regulatory framework. In: Treatise on water science. Elsevier, Oxford, pp 377–415
Doney SC et al (2009) Ocean acidification: the other CO2 problem. Mar Sci 1:169–192
Durack PJ, Wijffels SE, Matear RJ (2012) Ocean salinities reveal strong global water cycle intensification during 1950 to 2000. Science 336(6080):455–458
Edward R (2006) Calculation and uses of mean sediment quality guideline quotients: a critical review. Environ Sci Technol 40(6):1726–1736
Fagel N et al (2010) Geochemical evidence (C, N and Pb isotopes) of recent anthropogenic impact in south-central Chile from two environmentally distinct lake sediment records. J Quatern Sci 25(7):1100–1112
Farmer J, Lovell M (1986) Natural enrichment of arsenic in Loch Lomond sediments. Geochim Cosmochim Acta 50(9):2059–2067
Fendorf S, Wielinga BW, Hansel CM (2000) Chromium transformations in natural environments: the role of biological and abiological processes in chromium(VI) reduction. Int Geol Rev 42(8):691–701
Galloway JN et al (2008) Transformation of the nitrogen cycle: recent trends, questions, and potential solutions. Science 320(5878):889–892
Gąsiorowski M, Sienkiewicz E (2010) 20th century acidification and warming as recorded in two alpine lakes in the Tatra Mountains (South Poland, Europe). Sci Total Environ 408(5):1091–1101
Giesy JP, Hoke RA (1990) Freshwater sediment quality criteria: toxicity bioassessment. In: Baudo R, Giesy J, Muntau H (eds) Sediments: chemistry and toxicity of in-place pollutants. Lewis Publishers, Chelsea, pp 265–348
Hadden RL, Minson SG (2010) The geology of Haiti: an annotated bibliography of Haiti’s geology, geography and earth science. Army Geospatial Center, Alexandria, DTIC Document
Hannigan RE, Sholkovitz ER (2001) The development of middle rare earth element enrichments in freshwaters: weathering of phosphate minerals. Chem Geol 175(3–4):495–508
Higuera-Gundy A et al (1999) A 10,300 14C yr record of climate and vegetation change from Haiti. Quatern Res 52(2):159–170
Holser WT (1997) Evaluation of the application of rare-earth elements to paleoceanography. Palaeogeogr Palaeoclimatol Palaeoecol 132(1–4):309–323
Horowitz AJ (1991) Primer on sediment-trace element chemistry. 2
Ingersoll CG et al (2001) Predictions of sediment toxicity using consensus-based freshwater sediment quality guidelines. Arch Environ Contam Toxicol 41(1):8–21
IPCC (2007) The physical science basis. Contribution of working group I to the fourth assessment report of the intergovernmental panel on climate change. Cambridge University Press, Cambridge/New York, 996 p
Jordão CP, Pereira JL, Jham GN (1997) Chromium contamination in sediment, vegetation and fish caused by tanneries in the State of Minas Gerais, Brazil. Sci Total Environ 207(1):1–11
Kakuwa Y, Matsumoto R (2006) Cerium negative anomaly just before the Permian and Triassic boundary event – the upward expansion of anoxia in the water column. Palaeogeogr Palaeoclimatol Palaeoecol 229(4):335–344
Kazi TG et al (2009) The correlation of arsenic levels in drinking water with the biological samples of skin disorders. Sci Total Environ 407(3):1019–1026
Kendall C, McDonnell JJ (1998) Isotope tracers in catchment hydrology. Elsevier Science, Amsterdam
Kotaś J, Stasicka Z (2000) Chromium occurrence in the environment and methods of its speciation. Environ Pollut 107(3):263–283
Langard S, Schrauzer GN (1984) Biological and environmental aspects of chromium. Biol Trace Elem Res 6(6):539–539
Li S et al (2009) Water quality in the upper Han River basin, China: the impacts of land use/land cover in riparian buffer zone. J Hazard Mater 165(1–3):317–324
Li HB et al (2012) Lead contamination and source in Shanghai in the past century using dated sediment cores from urban park lakes. Chemosphere 88(10):1161–1169
Liu SM et al (2003) Nutrients in the Changjiang and its tributaries. Biogeochemistry 62(1):1–18
Luo W et al (2010) Ecological risk assessment of arsenic and metals in sediments of coastal areas of northern Bohai and Yellow Seas, China. AMBIO: J Hum Environ 39(6):367–375
MacDonald DD, Ingersoll C, Berger T (2000) Development and evaluation of consensus-based sediment quality guidelines for freshwater ecosystems. Arch Environ Contam Toxicol 39(1):20–31
Mann P et al (1983) Development of pull-apart basins. J Geol 91:529–554
McLennan SM (1989) Rare earth elements in sedimentary rocks; influence of provenance and sedimentary processes. Rev Mineral Geochem 21(1):169–200
Nassef M et al (2006) Determination of some heavy metals in the environment of Sadat industrial city. In: Proceeding of the 2nd environmental physics conference, Cairo University, Egypt, 2006, pp 145–152
Nriagu JO, Nieboer E (1988) Chromium in the natural and human environments. Wiley-Interscience, New York
Pais I, Jones JB (1997) The handbook of trace elements. CRC Press, Boca Raton
Robbins JA, Edgington DN (1975) Determination of recent sedimentation rates in Lake Michigan using Pb-210 and Cs-137. Geochim Cosmochim Acta 39(3):285–304
Rosenmeier MF et al (2004) Recent eutrophication in the Southern Basin of Lake Petén Itzá, Guatemala: human impact on a large tropical lake. Hydrobiologia 511(1):161–172
Salbu B, Steinnes E (1995) Trace elements in natural waters. CRC Press, Boca Raton
Schelske CL et al (1994) Low-background gamma counting: applications for 210 Pb dating of sediments. J Paleolimnol 10(2):115–128
Schroder S, Grotzinger J (2007) Evidence for anoxia at the Ediacaran-Cambrian boundary: the record of redox-sensitive trace elements and rare earth elements in Oman. J Geol Soc 164(1):175
Schüring J (2000) Redox: fundamentals, processes, and applications. Springer, Heidelberg
Sebrell WH et al (1959) Appraisal of nutrition in Haiti. Am J Clin Nutr 7(5):538–584
Sharp Z (2007) Principles of stable isotope geochemistry. Pearson Education, Upper Saddle River
Smith S et al (2011) Anthropogenic sulfur dioxide emissions: 1850–2005. Atmos Chem Phys 11(3):1101–1116
Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell Scientific Publications, Oxford
USEPA (2012a) Basic information – contaminated sediments
USEPA (2012b) Method detection/quantitation and calibration forum on environmental measurements. Office of the Science Advisor, US EPA
WHO (2012) WHO drinking-water quality. WHO
Xu L et al (2011) Sediment records of Sb and Pb stable isotopic ratios in Lake Qinghai. Microchem J 97(1):25–29
Zhu J, Olsen CR (2009) Beryllium-7 atmospheric deposition and sediment inventories in the Neponset River estuary, Massachusetts, USA. J Environ Radioact 100(2):192–197
Acknowledgements
This research was funded, in part, by NSF 0959666 (Hannigan and Christian), NSF 1062374, and by a UMass President’s Science and Technology grant (Hannigan). Additional support was provided by the Department of Environmental, Earth, and Ocean Sciences at UMass, Boston.
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Eisen-Cuadra, A., Christian, A.D., Dorval, E., Broadaway, B., Herron, J., Hannigan, R.E. (2013). Metal Geochemistry of a Brackish Lake: Étang Saumâtre, Haiti. In: Censi, P., Darrah, T., Erel, Y. (eds) Medical Geochemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4372-4_9
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