Abstract
The aim of this work is to develop a technique of introducing selected ferroelectric materials (TGS, NaNO2, NaNO3, KNO3, ADP and KDP) into porous glasses with various average pore dimensions. The major efforts have been focused on the investigations of the influence of the pore size on physical properties and phase transition of nanocrystals embedded into porous matrix with different methods. The ferroelectrics have been introduced into porous glasses from the melt and a water solution. The results of electrical (dielectric, pyroelectric) and thermal (dilatometric and calorimetric) measurements have shown that the observed sequences of phase transitions in ferroelectric materials embedded into the porous glasses are similar to that in bulk crystals. The relationship between phase transition and melt temperatures versus average values of pore dimensions has been determined. The experimentally observed shift of phase transition temperatures is the superposition of the size effect and pressure effect created by the difference of thermal expansion coefficients of ferroelectrics nanoparticles and glass matrix.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Scott JF (2002) Ferroelectrics memories. Springer, Berlin/Heidelberg/New York
Beskrovny A, Golosovsky I, Fokin A, Kumzerov Yu, Kurbakov A, Naberezhnov A, Vakhrushev S (2002) Structure evolution and formation of a pre-melted state in NaNO2 confined within porous glass. Appl Phys A 74:S1001–S1003
Tien Ch, Charnaya EV, Lee MK, Baryshnikov SV, Sun SY, Michel D, Böhlmann W (2005) Coexistence of melted and ferroelectric states in sodium nitrite within mesoporous sieves. Phys Rev B 72. doi:104105-1-104105-6
Jang EK, Woo JW, Yu I (1995) Rochelle salt nanocrystals embedded in porous glass. Application of Ferroelectrics, 1994.ISAF’94. Proceedings of the Ninth IEE International Symposium. CH34 16-50-7803-1847-1/95/1995IEEE:210–213
Balabinskaya AS, Ivanova EN, Ivanova MS, Kumzerov Yu A, Pan’kova SV, Poborchii VV, Romanov SG, Solovyev VG, Khanin SD (2005) Investigation into the electrical and optical properties of sodium nitrite and sodium nitrate nanoparticles in regular porous matrices. Glass Phys Chem 31:330–336
Rysiakiewicz-Pasek E, Lukaszewski P, Bogdanska J (2000) Investigation of correlation between mechanical properties and structure of porous glasses. Opt Appl XXX:173
Rysiakiewicz-Pasek E, Poprawski R, Polanska J, Urbanowicz A, Sieradzki A (2006) Properties of porous glasses with embedded ferroelectric materials. J Non-Cryst Solids 352:4309–4314
Zhong WL, Wang YG, Zhang PL, Qu BD (1994) Phenomenological study of the size effect on phase transitions in ferroelectric particles. Phys Rev B 50:698
Strukov BA, Davitadze ST, Shulman SG, Goltzman BV, Lemanov VV (2004) Ferroelectrics 301:157
Rysiakiewicz-Pasek E, Komar J, Ciżman A, Poprawski R (2010) Calorimetric investigations of NaNO3 and NaNO2 embedded into porous glasses. J Non-Cryst Solids 356:661–663
Beskrovny AI, Vasilovskii SG, Vakhrushev SB, Kurdyukov DA, Zvorykina OI, Naberezhnov AA, Okuneva NM, Tovar M, Rysiakiewicz-Pasek E, Jaguś P (2010) Temperature dependences of the order parameter for sodium nitrite embedded into porous glasses and opals. Phys Solid State 52(5):1092–1097
Mu R, Jin F, Morgan SH, Henderson DO, Silberman E (1994) The possible crossover effects of NaNO3 confined in porous media: from bulk to clusters. J Chem Phys 100:7749
Poprawski R, Rysiakiewicz-Pasek E, Sieradzki A, Ciżman A, Polańska J (2007) Ferroelectric phase transitions in KNO3 embedded into porous glasses. J Non-Cryst Solids 353:4457–4461
Sieradzki A, Komar J, Rysiakiewicz-Pasek E, Ciżman A, Poprawski R (2010) Calorimetric investigations of phase transitions in KNO3 embedded into porous glasses. Ferroelectrics 402(1):60–65
Landoldt HH, Börnstein R (1982) Group III crystal and solid state physics. Springer, Berlin/Heidelberg/New York
Chandra S, Kumar A (1990) Proton conduction in some solid hydrates and KDP-ferroelectric family materials. Solid State Ion 40:863
Diosa JE, Vargas RA, Albinsson L (2004) Dielectric relaxation of KH2PO4 above room temperature. Phys Status Solidi (b) 241:1369
Colla EV, Fokin AV, Kumzerov Yu A (1997) Ferroelectrcs properties of nanosize KDP particles. Solid State Commun 103(2):127–130
Marciniszyn T, Poprawski R, Komar J, Sieradzki A (2010) Phase transition in NH4H2PO4-porous glass composites. Phase Transit 83(10–11):909–916
Sieradzki A, Ciżman A, Poprawski R, Marciniszyn T, Rysiakiewicz-Pasek E (2011) Electrical conductivity and phase transitions in KDP- and ADP-porous glass nanocomposites. J Adv Dielectr 1:337–343
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2012 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Rysiakiewicz-Pasek, E., Poprawski, R., Ciżman, A., Sieradzki, A. (2012). Nanocomposite Materials – Ferroelectric Nanoparticles Incorporated into Porous Matrix. In: Shunin, Y., Kiv, A. (eds) Nanodevices and Nanomaterials for Ecological Security. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4119-5_16
Download citation
DOI: https://doi.org/10.1007/978-94-007-4119-5_16
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-4118-8
Online ISBN: 978-94-007-4119-5
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)