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Comparison of Surface and Bulk Properties of Pendant and Hybrid Fluorosilicones

  • Cedric Pasquet
  • Claire Longuet
  • Siska Hamdani-Devarennes
  • Bruno AmeduriEmail author
  • François GanachaudEmail author
Part of the Advances in Silicon Science book series (ADSS, volume 4)

Abstract

The most common fluorosilicone polymer commercialized to date is polymethyltrifluoropropylsiloxane. However, the low content of is the perfluorinated groups in the polymer 36.5 wt% does not fulfill the requirements of some high tech applications, particularly when swelling properties or degradation at high temperatures are concerned. A number of strategies have been employed to increase the fluorine content of fluorosilicone polymers. One elegant way is to introduce into the silicone chain, either as a pendant group or inside the backbone, perfluorinated groups of increasing size (typically C6 or higher). We refer to silicones with perfluorinated chains introduced as side groups as “pendant silicones” whereas those carrying fluorine atoms in the main backbone are called “hybrid silicones”. The most popular synthesis techniques of such polymers are briefly discussed here. A full fuller comparison is given of the two classes of polymers in terms of surface, mechanical, swelling and thermal properties.

Keywords

Polymethyltrifluoropropylsiloxane Pendant and hybrid fluorosilicones Synthesis and surface properties Thermal Swelling and mechanical properties 

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Copyright information

© Springer Science+Business Media Dordrecht 2012

Authors and Affiliations

  • Cedric Pasquet
    • 1
    • 2
  • Claire Longuet
    • 3
  • Siska Hamdani-Devarennes
    • 1
    • 3
  • Bruno Ameduri
    • 1
    Email author
  • François Ganachaud
    • 1
    • 2
    Email author
  1. 1.Institut Charles Gerhardt, Equipe “Ingénierie et Architectures Macromoléculaires”UMR5253 CNRS, ENSCMMontpellier CedexFrance
  2. 2.IMP@INSA, UMR5223 CNRS, INSA-LyonVilleurbanne CedexFrance
  3. 3.Ecole des Mines d’Alès, CMGDAlèsFrance

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