Abstract
Model simulations were performed using the CB05 chemical mechanism containing the base and updated toluene mechanisms for the eastern US. The updated toluene mechanism increased monthly mean 8-h ozone by 1.0–2.0ppbv in urban areas of Chicago, the northeast US, Detroit, Cleveland, and Cincinnati compared to those with the base toluene chemistry. The updated chemistry reduced mean bias and root mean square error in ozone predictions when compared with observations greater than 85ppbv and increased mean secondary organic aerosol from toluene by a maximum of 4%.
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References
Appel KW, Gilliland AB, Sarwar G, Gilliam RC (2007) Evaluation of the Community Multiscale Air Quality (CMAQ) model version 4.5: Sensitivities impacting model performance Part I-Ozone. Atmos Environ 41:9603–9615
Byun D, Schere KL (2006) Review of the governing equations, computational algorithms, and other components of the Models-3 Community Multiscale Air Quality (CMAQ) modeling system. Appl Mech Rev 59:51–77
Calvert JG, Atkinson R, Becker KH, Kamens RM, Seinfeld JH, Wallington TJ, Yarwood G (2002) The mechanisms of atmospheric oxidation of aromatic hydrocarbons. Oxford University Press, New York, 566pp
Grell G, Dudhia J, Stauffer D (1994) A description of the fifth-generation Penn State/NCAR Mesoscale model (MM5). NCAR Technical Note NCAR/TN-398 + STR
Pleim JE (2007) A combined local and nonlocal closure model for the atmospheric boundary layer. Part I: Model description and testing. J Appl Meteor Climatol 46:1383–1395
Schwede D, Pouliot G, Pierce T (2005) Changes to the biogenic emissions inventory system version 3 (BEIS3). In: 4th annual CMAS Models-3 Users’ conference, 26–28 Sept 2005, UNC-Chapel Hill. Available at http://www.cmascenter.org/html/2005_conference/abstracts/2_7.pdf
Whitten GZ, Heo G, Kimura Y, McDonald-Buller E, Allen D, Carter WPL, Yarwood G (2010) A new condensed toluene mechanism for Carbon Bond: CB05-TU. Atmos Environ 44(40):5346–5355
Yarwood G, Rao S, Yocke M, Whitten G (2005) Updates to the carbon bond chemical mechanism: CB05. Final report to the U.S. EPA, RT-0400675. Available at www.camx.com
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© 2011 Springer Science+Business Media B.V.
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Sarwar, G., Appel, K.W., Mathur, R., Schere, K. (2011). Examining the Impact of an Updated Toluene Mechanism on Air Quality in the Eastern US. In: Steyn, D., Trini Castelli, S. (eds) Air Pollution Modeling and its Application XXI. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1359-8_38
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DOI: https://doi.org/10.1007/978-94-007-1359-8_38
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