Abstract
The composition of air within a street canyon is determined by the composition of background air mixed in from above, advection of air into and out of the canyon, emissions from within the street, and the mixing and chemical processing of pollutants within the canyon. This paper describes a modelling study of street canyon atmospheric composition, integrating the combined effects of emissions, dynamics and chemistry. The research builds upon an existing dynamical model of canyon atmospheric motion (Large Eddy Simulation model) by adding a detailed chemical reaction scheme.
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References
Baker J, Walker HL, Cai XM (2004) A study of the dispersion and transport of reactive pollutants in and above street canyons – a large eddy simulation. Atmos Environ 38(39):6883–6892. doi:10.1016/j.atmosenv.2004.08.051
Cai XM, Barlow JF, Belcher SE (2008) Dispersion and transfer of passive scalars in and above street canyons – large-eddy simulations. Atmos Environ 42(23):5885–5895. doi:10.1016/j.atmosenv.2008.03.040
Cui ZQ, Cai XM, Baker CJ (2004) Large-eddy simulation of turbulent flow in a street canyon. Q J R Meteorol Soc 130(599):1373–1394. doi:10.1256/qj.02.150
Saunders SM, Jenkin ME, Derwent RG, Pilling MJ (1997) World wide web site of a master chemical mechanism (mcm) for use in tropospheric chemistry models. Atmos Environ 31(8):1249–1249
Jenkin ME, Watson LA, Utembe SR, Shallcross DE (2008) A common representative intermediates (cri) mechanism for voc degradation. Part 1: Gas phase mechanism development. Atmos Environ 42(31):7185–7195. doi:10.1016/j.atmosenv.2008.07.028
Watson LA, Shallcross DE, Utembe SR, Jenkin ME (2008) A common representative intermediates (cri) mechanism for voc degradation. Part 2: Gas phase mechanism reduction. Atmos Environ 42(31):7196–7204. doi:10.1016/j.atmosenv.2008.07.034
Acknowledgments
The authors would like to thank Dr. Mike Jenkin and Professor Dudley Shallcross for the provision of the Common Representatives Intermediates mechanism version 2-R5. VB also thanks the University of Birmingham for award of a Ph.D. scholarship.
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Bright, V.B., Bloss, W.J., Cai, X. (2011). Street Canyon Atmospheric Composition: Coupling Dynamics and Chemistry. In: Steyn, D., Trini Castelli, S. (eds) Air Pollution Modeling and its Application XXI. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1359-8_11
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DOI: https://doi.org/10.1007/978-94-007-1359-8_11
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