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Multiproperties Molecular Materials: Synergy between Electrical Conductivity and Magnetic Interactions

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Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics

Part of the book series: NATO Science Series ((NAII,volume 139))

Abstract

Recently, considerable efforts were done with the aim to design and to investigate new molecule-based materials involving interplay and synergy between multiple physical properties. This contribution emphasizes on materials combining magnetism and electrical behaviors. We will remind some fundamental background and constraints to design molecular materials with these physical properties and then we will discuss some examples to illustrate the achievements and the perspectives in this area. Three kinds of materials are presented, namely (DIETS)n(Et4N)(Cr(CN)6), [BDH- TTP][Cr(iso)2(NCS)4] and [Cu(hfac)2(TTF-py)2]. The former is based on -I…NC- interaction, the second is based on both π…π and S…S interactions and the last one is a coordination complex containing TTF units as ligands reflecting a covalent link between conducting and paramagnetic systems.

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Authors and Affiliations

  1. Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR 6511 CNRS-Université de Rennes 1, Groupe Matériaux Moléculaires, Institut de Chimie de Rennes, Campus de Beaulieu, 35042 Rennes cedex, France

    Lahcène Ouahab

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  1. Lahcène Ouahab
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Editors and Affiliations

  1. Laboratoire de Chimie du Solide et Inorganique Moléculaire, LCSIM, UMR CNRS 6511, Institut de Chimie de Rennes, Université de Rennes, Rennes Cedex, France

    Lahcène Ouahab

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    Eduard Yagubskii

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Ouahab, L. (2004). Multiproperties Molecular Materials: Synergy between Electrical Conductivity and Magnetic Interactions. In: Ouahab, L., Yagubskii, E. (eds) Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics. NATO Science Series, vol 139. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1027-6_6

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  • DOI: https://doi.org/10.1007/978-94-007-1027-6_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1942-5

  • Online ISBN: 978-94-007-1027-6

  • eBook Packages: Springer Book Archive

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