Abstract
Structural features of organic-inorganic layer compounds are surveyed, with special reference to factors influencing the interaction between the organic and inorganic components. The role of chirality and of guest molecules included in the inorganic layers is emphasised, and new examples of superlattices formed from different stacking types are described.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Day, P. (1985) Organic-inorganic layer compounds: Physical properties and chemical reactionsPhil. Trans. Roy. Soc A314, 145–158
Day, P. (1978) Chemical Classification of structures and properties of low-dimensional inorganic compoundsAnn. N.Y. Acad Sci. 313, 9–24
Day, P. (1983) Low-dimensional solidsChem. in Brit. 19, 306–314
Bellitto, C. and Day, P. (1992) Organic-intercalated halogenochromates(II): Low-dimensional magnetsJ. Mat.Chem.,2 (3), 265–271
Kurmoo, M., Mallah, T., Marsden, L., Allan. M., Friend, R.H., Pratt, F.L., Hayes, W., Chasseau, D., Bravic, G., Ducasse, L. and Day, P. (1992) Structure and properties of tris[bis(ethylenedithio)tetrathiafulvalenium]tetrachloro-copper(II) hydrate, (BEDT-TTF)3CuCl4.H2O: First evidence for coexistence of localised and conduction electrons in a metallic charge-transfer salt,J. Am. Chem. Soc 114, 10722–10729
Kurmoo, M., Graham, A.W., Day, P., Coles, SJ., Hursthouse, M.B., Caulfield, J.L., Singleton, J., Pratt, F.L., Hayes, W., Ducasse, L. and Guionneau, P. (1995) Superconducting and semiconducting magnetic charge transfer salts: (BEDT-TTF)4AFe(C2O4)3.C6H5CN (A = H2O, K, NH4)J. Am. Chem. Soc 117, 12209–12217
Coronado, E., Galan-Mascaros, J.R., Gomez-Garcia, CJ. and Laukhin, V. (2000) Co-existence of ferromagnetism and metallic conductivity in a molecular-based layer compound, Nature 408, 447–448
Rashid, S., Turner, S.S., Day, P., Light, M.E., Hursthouse, M.B., Firth, S. and Clark, R.J.H. (2001) The first molecular charge transfer salt containing proton channelsChem. Commun. 1462–1463
Akutsu-Sato, A., Akutsu, H., Turner, S.S., Le Pevelen, D., Day, P., Light, M.E., Hursthouse, M.B., Akutagawa, T. and Nakamura T. (2003) Structures and physical properties of BEDT-TTF salts containing channels of protons,Synth. Met. 135–136, 135–136
Gamble, E.R. (1978) The layered chalcogenides: some chemistry and physics, Ann. N.Y. Acad. Scie., 313,86–110
Kind, R., Pleasko, S., Arend, H., Blinc, R., Zeks, B., Seliger, J., Lozar, B., Slak, J., Levstik, A., Filipic, C
Structural Domains and Phase Transitions in Organic-Intercalated Layer Perovskite Halide Salts (RNH3)2MX4: Optical Micrography and Diffraction, N.W.J. Avery and P. Day, J. Cryst. Gowth, 73, 268–274(1985)
Carling, S.G., Day, P. and Visser, D. (1990) Crystal and magnetic structures of layer phosphatesActa Cryst. A46, (Suppl) C-278
Carling, S.G., Day, P. and Visser, D. (1993) Weak ferromagnetic behaviour of the manganese alkylphosphonate hydrates MnCnH2n+lPO3.H2O, n = 1–4J. Sol. St. Chem. 106, 1–4
Kepert, CJ., Kurmoo, M. and Day, P. (1997) Semiconducting charge-transfer salts of BEDT-TTF [bis(ethylenedithio)tetrathiafulvalene] with hexachlorometallate (IV) anions, J. Mat. Chem., 7 (2), 221–228
Yamochi, H., Kamatsu, T., Matsukawa, N., Saito, G., Mori, T., Kusonoki, M. and Sakaguchi, K. (1993), Structural aspects of the ambient-pressure BEDT-TTF superconductors,J. Am. Chem. Soc, 115, 11319–11327
Kurmoo, M., Pritchard, K., Talham, D., Day, P., Stringer, A.M. and Howard, J.A.K. (1990) Crystal structure and physical properties of a metallic charge transfer salt (BEDT-TTF)2Ag(CN)2.H2OActa Cryst. B46, 348–354
Martin, L., Turner, S.S., Day, P., Howard, J.A.K., Malik, K.M.A., Hursthouse, M.B., Uruichi, M. and Yakushi, K. (2001) Crystal chemistry and physical properties of superconducting and semiconducting charge transfer salts (BEDT-TTF)4[AIMI1I(C2O4)3]C6H5CN (A1 = H3O, NH4, K; M = Ti, Cr, Fe, Co, Gd, Al; BEDT-TTF = bisethylenedithiotetrathiafulvalene)Inorg. Chem. 40, 1363–1371
Werner, A. and Poupardin, J. (1914)Ber. Dtsch. Chem. Ges. 47, 1955
Decurtins, S., Schmalle, H.W., Oswald, H.R., Linden, A., Ensling, J., Gutlich, P. and Hauser, A. (1994), A polymeric two-dimensional mixed-metal network. Crystal structure and magnetic properties of [PPh4][MnCr(OX)3]n, Inorg. Chim. Acta 216, 65–73
Martin, L., Turner, S.S., Day, P., Malik, K.M.A., Coles and Hursthouse, M.B. (1999) Polymorphism based on molecular stereoisomerism in tris(oxalato) Cr(III) salts of bedt-ttf (bis(ethylenedithio)tetrathiafulvalene)J.C.S. Chem. Commun. 513–514
Rashid, S., Turner, S.S., Le Pevel, D., Day, P., Light, M.E., Hursthouse, M.B., Firth, S. and Clark, R.J.H. (2001) ¦Â“-(BFDT-TTF)4[(H3O)Cr(C2O4)3]CH2Cl2: Effect of included solvent on structure and properties of a conducting molecular charge transfer saltInorg. Chem. 40, 5304–5306
Prokhorova, T.G., Khasanov, S.S., Zorina, L.V., Buravov, L.I., Tkacheva, V.A., Kaskakov, A.A., Morgunov, R.B., Gener, M. Canadell, E., Chibaeva, R.P. and Yagubskii, E.. (2003), Molecular metals based on BEDT-TTF radical cation salts with magnetic metal oxalates as counterions: ¦Â“-(BEDT- TTF)4A[M(C2O4)3] DMF (A = NH4 +, K+; M = CrIII, FeIII)Adv. Funct. Mater. 13, 1–9
Turner, S.S., Day, P. Malik, K.M.A. and Hursthouse, M.B. (1999) Effect of template molecule on the conductivity of the molecular metals ¦Â-(BEDT-TTF)4[(H2O) Fe(C2O4)3. template] (template = benzonitrile, pyridine)Inorg. Chem. 38, 3543–3549
Akutsu, H., Akutsu-Sato, A., Turner, S.S., Le Pevelen, D., Day, P., Laukhin, V., Klehe, A.-K., Singleton, J., Tocher, D.A., Probert, M.R. and Howard, J.A.K. (2002) Effect of included guest molecules on the normal state conductivity and superconductivity of ¦Â“-(ET)4[(H3O)Ga(C2O4)3].G (G = pyridine, nitrobenzene)J. Am. Chem. Soc. 124, 12430–12431
Coldea, A.I. Bangara, A.F., Singleton, J., Ardavan, A., Akutsu-Sato, A., Akutsu, H., Turner, S.S. and Day,P., Fermi surface topology of the new metals ¦Â“-(BEDT-TTF)4[(H3O)M(C2O4)3]C5H5N (M = Cr, Ga)Synth. Met., in press
Bangura, A.F., Coldea, A.I. Singleton, J., Ardavan, A., Klehe, A.-K., Akutsu-Sato, A., Akutsu, H., Turner, S.S. and Day,P., (2003) Magnetotransport measurements on ¦Â“-(BEDT-TTF)4 [(H3O)Ga(C2O4)3]. C6H5NO2 Synth. Met. 137, 1313–1314
Akutsu, H., Akutsu-Sato, A., Turner, S.S. and Day, P., Superlattices of donor stacking in the molecular charge transfer salts (BEDT-TTF)4[(NH4)M(C2O4)3].G (M = Fe, Ga; G = phenylacetonitrile, acetophenone, phenylmethylformamide)Angew. Chem. in preparation
Turner, S.S., Le Pevelen, D. and Day, P. (2003) Interaction between cation and anion sublattices in molecular charge transfer salts: Structural conditions for ferrimagnetismSynth. Met. 133–134, 133–134
Nakamura, T., Akutagawa, T., Honda, K., Underhill, A.E., Coomber, A.T. and Friend, R.H. (1998), A molecular metal with ion-conducting channelsNature 394, 159–162
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2004 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Day, P. (2004). Organic-inorganic Hybrids: the Best of Both Worlds?. In: Ouahab, L., Yagubskii, E. (eds) Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics. NATO Science Series, vol 139. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1027-6_4
Download citation
DOI: https://doi.org/10.1007/978-94-007-1027-6_4
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-1942-5
Online ISBN: 978-94-007-1027-6
eBook Packages: Springer Book Archive