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Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics pp 19–44Cite as

Design of Organic (Super)Conductors and Study of Their Physical Properties

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Part of the book series: NATO Science Series ((NAII,volume 139))

Abstract

The molecular design and requirements for organic (super)conductors based on charge-transfer (CT) complexes of BO, ET and their analogues are described in terms of ionicity, stacking manner and self-assembling ability. The crystal and electronic structures of 10 K class κ-type BEDT-TTF (ET) superconductors are presented concerning with the electron correlation and the anisotropy of the electronic structure. At ambient pressure, owing to the strong spin frustration, a Mott insulator κ- (ET)2Cu2(CN)3 undergoes a non-spin-ordered ground state instead of the spin-ordered state. It also exhibits a superconducting state under a weak uni-axial strain. The appearance of the superconducting state by reducing the spin frustration is an evidence that the magnetic interactions are essential to realize the superconducting state.

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  1. Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto, 606-8502, Japan

    Gunzi Saito, Hideki Yamochi, Mitsuhiko Maesato, Yukihiro Yoshida, Akira Ota & Yasuhiro Shimizu

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  1. Laboratoire de Chimie du Solide et Inorganique Moléculaire, LCSIM, UMR CNRS 6511, Institut de Chimie de Rennes, Université de Rennes, Rennes Cedex, France

    Lahcène Ouahab

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    Eduard Yagubskii

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Saito, G., Yamochi, H., Maesato, M., Yoshida, Y., Ota, A., Shimizu, Y. (2004). Design of Organic (Super)Conductors and Study of Their Physical Properties. In: Ouahab, L., Yagubskii, E. (eds) Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics. NATO Science Series, vol 139. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1027-6_2

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