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Multilayer Films and Capsules of Sodium Carboxymethylcellulose and Polyhexamethylenguanidine Hydrochloride

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Abstract

The complexation of polyhexamethylenguanidine hydrochloride (PHMG) and sodium carboxymethylcellulose (CMC) was investigated for different conditions. Mixing of equiconcentrated aqueous solutions of the polyelectrolytes was found to result in the formation of an insoluble interpolyelectrolyte complex with an overweight of carboxymethylcellulose. A step-by-step formation of stable, irreversibly adsorbed multilayer film of the polymers was demonstrated using the quartz crystal microbalance method. Unusually thick polymer shells with a large number of loops and tails of the polyanion were formed by the method of layer-by-layer self-assembly of PHMG and CMC on spherical CaCO3 particles. Hollow multilayer capsules stable in neutral media were obtained by dissolution of the inorganic matrix in EDTA solution.

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References

  1. G. Sukhorukov, A. Fery, H. Möhwald, Prog. Polym. Sci. 30, 885 (2005).

    Article  Google Scholar 

  2. K. Glinel, C. Dejugnat, M. Prevot, B. Schöler, M. Schönhoff, R. Klitzing, Colloids and Surfaces A: Physicochem. Eng. Aspects 303, 3 (2007).

    Article  Google Scholar 

  3. A.A. Antipov, G.B. Sukhorukov, Advances in Colloid and Interface Science 111, 49 (2004).

    Article  Google Scholar 

  4. B.G. De Geest, N.N. Sanders, G.B. Sukhorukov, J. Demeester, S.C. De Smedt, Chem. Soc. Rev. 36, 636 (2007).

    Article  Google Scholar 

  5. S.A. Sukhishvili, Current Opinion in Colloid & Interface Science 10, 37 (2005).

    Article  Google Scholar 

  6. J.A. Jaber, J.B. Schlenoff, Current Opinion in Colloid & Interface Science 11, 324 (2006).

    Article  Google Scholar 

  7. M. Schönhoff, V. Ball, A.R. Bausch, C. Dejugnat, N. Delorme, K. Glinel, R. Klitzing, R. Steitz, Colloids and Surfaces A: Physicochem. Eng. Aspects 303, 14 (2007).

    Article  Google Scholar 

  8. D.V. Volodkin, A.I. Petrov, M. Prevot, and G.B. Sukhorukov, Langmuir 20, 3398 (2004).

    Article  Google Scholar 

  9. N.V. Guzenko, A.L. Gabchak, E.M. Pakhlov, Polymer Journal 30, 331 (2008).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, General Naumov Street 17, 03164, Kyiv, Ukraine

    Nataliia Guzenko, Oleksandra Gabchak & Evgenij Pakhlov

Authors
  1. Nataliia Guzenko
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  2. Oleksandra Gabchak
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  3. Evgenij Pakhlov
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Corresponding author

Correspondence to Nataliia Guzenko .

Editor information

Editors and Affiliations

  1. , Inst. of Nanostructure Tech. & Analytics, University of Kassel, Heinrich-Plett-Str. 40, Kassel, 34132, Germany

    Johann Peter Reithmaier

  2. , Faculty of Technology and Metallurgy, University "Sts. Cyril and Methodius", Rugjer Boskovic 16, Skopje, 1000, Macedonia

    Perica Paunovic

  3. , Dept. of Mathematics and Natural Science, University of Kassel, Heinrich-Plett-Str. 40, Kassel, 34132, Germany

    Wilhelm Kulisch

  4. , Inst. of Nanostructure Technologies and, University of Kassel, Heinrich-Plett-Str. 40, Kassel, 34132, Germany

    Cyril Popov

  5. Technology & Metallurgy, Dept. Physics, University of Chemical, St. Kliment Ohridski Blvd. 8, Sofia, 1756, Bulgaria

    Plamen Petkov

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Guzenko, N., Gabchak, O., Pakhlov, E. (2011). Multilayer Films and Capsules of Sodium Carboxymethylcellulose and Polyhexamethylenguanidine Hydrochloride. In: Reithmaier, J., Paunovic, P., Kulisch, W., Popov, C., Petkov, P. (eds) Nanotechnological Basis for Advanced Sensors. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0903-4_7

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