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Structure of AgI-AsSe Glasses by Raman Scattering and Ab Initio Calculations

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Nanotechnological Basis for Advanced Sensors

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Abstract

We report a structure investigation of (AsSe)100−x(AgI)x bulk glasses using Raman spectroscopy and ab initio calculations. Raman spectra recorded at off-resonance conditions indicate appreciable structural changes caused by the incorporation of AgI into the base glass structure. Ab-initio and density functional theory calculations were employed to study the geometric and vibrational properties of molecular units that are parts of the glass structure.

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References

  1. A.V. Kolobov, Editor, Photo-induced Metastability in Amorphous Semiconductors, Wiley-VCH, Weinheim (2003).

    Google Scholar 

  2. R.K. Willardson and E.R. Weber, Editors, Semiconducting Chalcogenide Glass III: Applications of chalcogenide glasses, Semiconductors and Semimetals vol. 80, Elsevier Academic Press (2004).

    Google Scholar 

  3. T. Petkova, C. Popov, T. Hineva, P. Petkov, G. Socol, E. Axente, C.N. Mihailescu, I.N. Mihailescu, J.P. Reithmaier, Appl. Surface Sci. 255 5318 (2009).

    Article  ADS  Google Scholar 

  4. B. Monchev, D. Filenko, N. Nikolov, C. Popov, T. Ivanov, P. Petkov, I. W. Rangelow, Appl. Phys. A 87, 31 (2007).

    Article  ADS  Google Scholar 

  5. A.E. Owen, J. Non-Cryst. Solids 35–36, 999 (1980).

    Article  Google Scholar 

  6. Yu.G Vlasov, E.A. Bychkov, A.V. Legin, Talanta, 41, 1059 (1994).

    Article  Google Scholar 

  7. T. Hineva, T. Petkova, P. Petkov, V. Mikli, C.N. Mihailescu, I.N. Mihailescu, J. Phys., Conf. Ser. 113, 012023 (2008).

    Google Scholar 

  8. A. Schafer, C. Huber and R. Ahlrichs, J. Chem. Phys. 100, 5829 (1994).

    Article  ADS  Google Scholar 

  9. E.J. Smail and G. M. Sheldrick, Acta Cryst. B 29, 2014 (1973).

    Article  Google Scholar 

  10. J. Bastow and H. J. Whitfield, J. Chem. Soc., Dalton, 1739 (1973).

    Google Scholar 

  11. A.V. Kolobov, S.R. Elliot, Phil. Mag. B 71, 1 (1995).

    Google Scholar 

  12. W. Bues, M. Somer and W. Brockner, Z. Naturforsch. 35b, 1063 (1980).

    Google Scholar 

  13. T. Usuki, S. Saito, K. Nakajima, O. Uemura, Y. Kameda, T. Kamiyama, M.J. Sakurai, Non-Cryst. Sol. 312, 570 (2002).

    Article  ADS  Google Scholar 

  14. T. Petkova, P. Petkov, P. Jovari, I. Kaban, W. Hoyer, A. Schops, A. Webbe, B. Beuneu, J. Non-Cryst. Solids 353, 2045 (2007).

    Article  ADS  Google Scholar 

  15. R.J.H. Clark and D.M. Rippon, J. Mol. Spectrosc. 52, 58 (1974).

    Article  ADS  Google Scholar 

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Author information

Authors and Affiliations

  1. Institute of Chemical Engineering and High Temperature Chemical Processes, Foundation for Research and Technology Hellas, 1414, Patras, GR-26504, Greece

    Ofeliya Kostadinova, A. Chrissanthopoulos & S. N. Yannopoulos

  2. Laboratory of Advanced Materials Research, Department of Silicate Technology, University of Chemical Technology and Metallurgy, Sofia, Bulgaria

    Ofeliya Kostadinova

  3. Institute of Electrochemistry and Energy Systems (IEES), Bulgarian Academy of Sciences, Sofia, Bulgaria

    T. Petkova

  4. Department of Chemistry, University of Patras, Patras, GR-26504, Greece

    A. Chrissanthopoulos

  5. Thin Films Technology Laboratory, Department of Physics, University of Chemical Technology and Metallurgy, KI. Ohridsky Blvd.8, 1756, Sofia, Bulgaria

    Plamen Petkov

Authors
  1. Ofeliya Kostadinova
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  2. T. Petkova
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  3. A. Chrissanthopoulos
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  4. Plamen Petkov
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  5. S. N. Yannopoulos
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Corresponding author

Correspondence to S. N. Yannopoulos .

Editor information

Editors and Affiliations

  1. , Inst. of Nanostructure Tech. & Analytics, University of Kassel, Heinrich-Plett-Str. 40, Kassel, 34132, Germany

    Johann Peter Reithmaier

  2. , Faculty of Technology and Metallurgy, University "Sts. Cyril and Methodius", Rugjer Boskovic 16, Skopje, 1000, Macedonia

    Perica Paunovic

  3. , Dept. of Mathematics and Natural Science, University of Kassel, Heinrich-Plett-Str. 40, Kassel, 34132, Germany

    Wilhelm Kulisch

  4. , Inst. of Nanostructure Technologies and, University of Kassel, Heinrich-Plett-Str. 40, Kassel, 34132, Germany

    Cyril Popov

  5. Technology & Metallurgy, Dept. Physics, University of Chemical, St. Kliment Ohridski Blvd. 8, Sofia, 1756, Bulgaria

    Plamen Petkov

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© 2011 Springer Science+Business Media B.V.

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Kostadinova, O., Petkova, T., Chrissanthopoulos, A., Petkov, P., Yannopoulos, S.N. (2011). Structure of AgI-AsSe Glasses by Raman Scattering and Ab Initio Calculations. In: Reithmaier, J., Paunovic, P., Kulisch, W., Popov, C., Petkov, P. (eds) Nanotechnological Basis for Advanced Sensors. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0903-4_23

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