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Temperature Ferroelastic Phase Transition in Hydroxyapatite. Hydroxyl Solubility, Configuration Heat-Capacity, Hysteresis Effect, Elasticity Modulus

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Carbon Nanomaterials in Clean Energy Hydrogen Systems - II

Part of the book series: NATO Science for Peace and Security Series C: Environmental Security ((NAPSC,volume 2))

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Abstract

The statistical theory of ferroelastic-paraelastic phase transition has been elaborated in this paper. The equation of thermodynamic equilibrium state has been examined and the temperature of transition between phases has been estimated. The calculation of temperature dependence of hydroxyl solubility in crystal has been carried out. The manifestation hysteresis effect has been considered. The temperature dependence of elastic compliance and elasticity modulus has been evaluated and the verity of the rule of “negative two” and Curie-Weiss law has been found. The dependence configuration heat capacity on temperature has been calculated, its extremality has been ascertained and the abrupt change of heat capacity has been defined in the point of phase transition. The established regularities are consistent qualitatively with literature experimental data.

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Authors and Affiliations

  1. Dnepropetrovsk National University, 72 Gagarin str, Dnepropetrovsk, 49000, Ukraine

    Z. A. Matysina

  2. Institute for Problems of Materials Science of NAS of Ukraine, Department # 67, 3 Krzhyzhanovsky str, Kiev, 03142, Ukraine

    S. Yu. Zaginaichenko, D. V. Schur & N. A. Shvachko

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  1. Z. A. Matysina
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  2. S. Yu. Zaginaichenko
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  3. D. V. Schur
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  4. N. A. Shvachko
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Correspondence to S. Yu. Zaginaichenko .

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Editors and Affiliations

  1. , Institute of Hydrogen and Solar Energy, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03150, Ukraine

    Svetlana Yu. Zaginaichenko

  2. , Inst. for Problems of Materials Science, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03150, Ukraine

    Dmitry V. Schur

  3. , Inst. for Problems of Materials Science, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03142, Ukraine

    Valeriy V. Skorokhod

  4. International Association for Hydrogen E, University of Miami, 5794 SW 40 St. # 303, Miami, 33155, Florida, USA

    Ayfer Veziroglu

  5. , Department of Mechanical Engineering, Gazi University, Yukselis Street 5, Ankara, Turkey

    Beycan İbrahimoğlu

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Matysina, Z.A., Zaginaichenko, S.Y., Schur, D.V., Shvachko, N.A. (2011). Temperature Ferroelastic Phase Transition in Hydroxyapatite. Hydroxyl Solubility, Configuration Heat-Capacity, Hysteresis Effect, Elasticity Modulus. In: Zaginaichenko, S., Schur, D., Skorokhod, V., Veziroglu, A., İbrahimoğlu, B. (eds) Carbon Nanomaterials in Clean Energy Hydrogen Systems - II. NATO Science for Peace and Security Series C: Environmental Security, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0899-0_27

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