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Phenoxy–Imine Group 4 Metal Complexes for Olefin (co)Polymerization Including Polar Monomer Copolymerization

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Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 36))

Abstract

About 50 years after the discovery of Ziegler–Natta catalysts, phenoxy–imine-based group 4 transition metal complexes (FI catalysts) emerged as the next frontier catalysts for the controlled (co)polymerization of olefinic monomers. FI catalysts are highly versatile catalysts capable of producing a wide range of novel polymer architectures. The inherent electronic and structural features of FI catalysts and the accessibility and variability of the phenoxy–imine ligands offer precise control over olefin polymerization. This chapter deals with the key features of FI catalysts, homopolymerization and copolymerization by FI catalysts, and the value-added olefin-based materials that can be produced with FI catalysts.

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Authors and Affiliations

  1. Research Center, Mitsui Chemicals, Inc., 580-32 Nagaura, Sodegaura, Chiba, 299-0265, Japan

    Akihiko Iwashita, Haruyuki Makio & Terunori Fujita

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  1. Akihiko Iwashita
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  2. Haruyuki Makio
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  3. Terunori Fujita
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Correspondence to Terunori Fujita .

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Editors and Affiliations

  1. CSIC-Universidad de Sevilla., Instituto de Investigaciones Químicas, C/ Americo Vespucio 49, Sevilla, 41092, Spain

    Juan CAMPORA

  2. ICCOM, Florence research area, National Council of Research - CNR, Via Madonna del Piano 10, Florence, 50019, Italy

    Giuliano GIAMBASTIANI

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Iwashita, A., Makio, H., Fujita, T. (2011). Phenoxy–Imine Group 4 Metal Complexes for Olefin (co)Polymerization Including Polar Monomer Copolymerization. In: CAMPORA, J., GIAMBASTIANI, G. (eds) Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II. Catalysis by Metal Complexes, vol 36. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0696-5_1

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