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Simulation of Distributed Detection of Ammonia Gas

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Computational Modelling and Advanced Simulations

Part of the book series: Computational Methods in Applied Sciences ((COMPUTMETHODS,volume 24))

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Abstract

A basic theoretical model of a distributed fiber optic system for detection and location of ammonia leaks is proposed and employed in computer simulations of principal system characteristics. The simulated system consists of an optical time-domain reflectometer (OTDR) interrogating a sensing optical fiber composed of silica core and polymer cladding doped with a reagent. The simulated processes include gas diffusion into the cladding, conversion of the reagent in presence of the analyte, time- and space-evolution of polarizability and absorption coefficient, propagation of the primary light pulse along the fiber, interaction of the pulse with the cladding and generation of a backscattered light signal registered afterwards by the OTDR detector. Juxtaposition of the simulated results and the demands laid on a real system results in several recommendations for further development and optimization of such sensing systems.

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Notes

  1. 1.

    Sylgard (Dow Corning) is a commercial thermo-cross-linkable fiber cladding material based on polysiloxane formulation.

  2. 2.

    Further on, we suppose that the radial co-ordinate is discretized into 100 intervals.

  3. 3.

    Both fused silica and polysiloxane resin matrix contains extended siloxane network, though differing in its density and topology.

  4. 4.

    Maximum of the absorption band is observed at \(\lambda _{\max } = 740{\textrm{ nm}}\).

  5. 5.

    The ammonia accumulated within the cladding during the exposition is to be expected as the main source of possible discrepancies.

  6. 6.

    However, sensing reversibility issues have to be carefully considered in this case.

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Acknowledgements

The research has been supported by the Ministry of Education, Youth and Sports of the Czech Republic, grants MSM6840770040 and MSM6840770021.

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Correspondence to L. Kalvoda .

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Sýkora, O., Aubrecht, J., Klepáček, R., Kalvoda, L. (2011). Simulation of Distributed Detection of Ammonia Gas. In: Murín, J., Kompiš, V., Kutiš, V. (eds) Computational Modelling and Advanced Simulations. Computational Methods in Applied Sciences, vol 24. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0317-9_7

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  • DOI: https://doi.org/10.1007/978-94-007-0317-9_7

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  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-007-0316-2

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