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Past Examples of Multipopllutant Air Quality Management and Accountability

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Technical Challenges of Multipollutant Air Quality Management

Abstract

Historically, the primary direction for accountability assessment for exposure has relied on documentation of changes in emissions and ambient air quality as applied to the suite of regulated pollutants. Less attention has been given to retrospective evaluation of the projections for future changes as estimated from air quality modeling, and the evaluation or interpretation of changes in ambient air quality relative to projections. Even less attention has focused until recently on the determining changes or trends in improvement in human health or ecosystems resulting from air quality improvement. In this chapter, we concentrate on the aspects of accountability that should be documented in order to inform decision-makers regarding the effectiveness of management actions. The chapter shows that management actions have achieved pollution reductions, and that these actions have mitigated exposure to ambient air pollution. The principal measures of health and ecological trends over the last two decades have come from epidemiological studies and from measurement of surface water chemistry. The examples discussed do not represent a complete review of the range of actions taken and their consequences to air quality measures. However, they do provide the reader with some examples of change and trends relevant to multipollutant considerations, and give perspective to the use of management tools to achieve air quality goals.

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Notes

  1. 1.

    In addition to ozone, photochemical oxidants include short-lived oxygenated intermediates, peroxides, nitric acid, and NO3 radical. These species are estimated to represent about 10% of the total oxidant concentration; the remainder is said to be ozone.

  2. 2.

    Selective VOC reduction by reactivity is under consideration as an efficient means of managing ozone, and one formal U.S. action has been taken for consideration of organic coatings. In some states, e.g., California, VOC reactivity is taken into account in the management of VOCs to reduce ozone concentrations (e.g., Avery 2006).

  3. 3.

    As of March 2008, the U.S. NAAQS was changed by the EPA Administrator from 0.080 ppm 8-h average of daily maxima to 0.075 ppm 8-h average of daily maxima, changing the non-attainment designations across the country.

  4. 4.

    The current picture of increases in tropospheric ozone concentrations in the northern hemisphere is more complex that a simple monotonic increase, and varies by geographical region as noted by Oltmans et al. (2006); Vingarzan and Taylor (2003).

  5. 5.

    SUM06 ozone concentration is defined as the hourly ozone concentration above 0.06 ppm, summed over 12 h (8 a.m.–8 p.m.) during a three-month period. SUM06 was intended to measure the exposure of vegetation and crops during the growing season, proposed as a U.S. secondary ambient standard.

  6. 6.

    A limitation in this approach is the use of observational data assimilation to constrain the forecasting model, which may preclude testing the forecast results with independent observations. The forecasting would have to be done without adjusting the model forecast with ambient data.

  7. 7.

    Prior to the 1980, particulate air quality goals were established on a mass basis using the measure of total suspended particles (TSP), based on gravimetric determination of filter collection over 24 h. This measurement used a sampler collecting particles roughly £35 μm in diameter.

  8. 8.

    Regulated pollutants for Canada, the United States, and Mexico are defined in the List of Terms.

  9. 9.

    Diesel engine emission are currently not listed a HAP under the CAA.

  10. 10.

    Mercury from soils can be natural or anthropogenic in origin. The latter consists of mercury deposited from the atmosphere in the past and stored in the soil for an unknown period of time before release.

  11. 11.

    Hypothetically this may be more than a coincidence with lower sulfur fuels, and application of control technologies may have had an unexpected consequence of reducing mercury emissions.

  12. 12.

    This interpretation has been questioned in that there were changes in water quality management practices taking place at the same time, and modeling indicated that the global mercury contribution was large in the Everglades (see for example the review of Pollman et al. 2007).

  13. 13.

    Global population exposure to mercury from the marine fish supply, including tuna and swordfish or other predatory species, may be large, but exposure is highly uncertain.

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Acknowledgments

We acknowledge the following contributing authors: Doug Burns, Elton Chan, Tom Clair, Tom Dann, John J. Jansen, Leonard Levin, David McLaughlin, Luisa T. Molina, Armando Retama, Richard D. Scheffe, Robert Vet, Miguel Zavala

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Hidy, G.M., Brook, J.R., Demerjian, K.L. (2011). Past Examples of Multipopllutant Air Quality Management and Accountability. In: Hidy, G., Brook, J., Demerjian, K., Molina, L., Pennell, W., Scheffe, R. (eds) Technical Challenges of Multipollutant Air Quality Management. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0304-9_12

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