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Homogeneous and Heterogeneous Catalytic Processes Promoted by Organoactinides

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The Chemistry of the Actinide and Transactinide Elements

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Abstract

During the last two decades, the chemistry of organoactinides has flourished, reaching a high level of sophistication. The use of organoactinide complexes as stoichiometric or catalytic compounds to promote synthetically important organic transformations has matured due to their rich, complex, and uniquely informative organometallic chemistry. Compared to early or late transition metal complexes, the actinides sometimes exhibit parallel and sometimes totally different reactivities for similar processes. In many instances the regiospecific and chemical selectivities displayed by organoactinide complexes are complementary to that observed for other transition metal complexes. Several recent review articles (Edelman et al., 1995; Edelmann and Gun’ko, 1997; Ephritikhine, 1997; Hitchcock et al., 1997; Berthet and Ephritikhine, 1998; Blake et al., 1998; Edelmann and Lorenz, 2000), dealing mostly with the synthesis of new actinide complexes, confirm the broad and rapidly expanding scope of this field.

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Authors
  1. Carol J. Burns
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  2. Moris S. Eisen
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Editors and Affiliations

  1. Argonne National Laboratory, Argonne, Illinois, USA

    Lester R. Morss

  2. Lawrence Berkeley National Laboratory, Berkeley, California, USA

    Norman M. Edelstein

  3. University of Liège, Berkeley, Liège, Belgium

    Jean Fuger

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Burns, C.J., Eisen, M.S. (2010). Homogeneous and Heterogeneous Catalytic Processes Promoted by Organoactinides. In: Morss, L.R., Edelstein, N.M., Fuger, J. (eds) The Chemistry of the Actinide and Transactinide Elements. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0211-0_26

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