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High-Pressure Synthesis of Novel Superhard Phases in the B–C–N–O System

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Abstract

Recent results on high pressure–high temperature synthesis of new superhard phases in the B–C–N–O system (cubic B–C–N phases, diamond-like BC5, rhombohedral B13N2, orthorhombic γ-B28, etc.) are briefly reviewed.

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References

  • Brazhkin, V.V., Solozhenko, V.L., Bugakov, V.I., Dub, S.N., Kurakevych, O.O., Kondrin, M.V., and Lyapin, A.G., (2007), Bulk nanostructured carbon phases prepared from C60: approaching the ‘ideal’ hardness, J. Phys.: Cond. Mat. 19(23), 236209.

    Article  ADS  Google Scholar 

  • Dubrovinskaya, N., Solozhenko, V.L., Miyajima, N., Dmitriev, V., Kurakevych, O.O., and Dubrovinsky, L., (2007), Superhard nanocomposite of dense polymorphs of boron nitride: Noncarbon material has reached diamond hardness, Appl. Phys. Lett. 90(10), 101912.

    Article  ADS  Google Scholar 

  • Hubble, H.W., Kudryashov, I., Solozhenko, V.L., Zinin, P.V., Sharma, S.K., and Ming, L.C., (2004), Raman studies of cubic BC2N, a new superhard phase, J. Raman Spectr. 35(10), 822–825.

    Article  ADS  Google Scholar 

  • Hubert, H., Garvie, L.A.J., Buseck, P.R., Petuskey, W.T., and McMillan, P.F., (1997), High-pressure, high-temperature syntheses in the B–C–N–O system, J. Solid State Chem. 133, 356–364.

    Article  ADS  Google Scholar 

  • Kurakevych, O.O., and Solozhenko, V.L., (2007), Rhombohedral boron subnitride, B13N2, by x-ray powder diffraction, Acta Crystallogr. C 63(9), i80–i82.

    Article  Google Scholar 

  • Kurdyumov, A.V., Solozhenko, V.L., Hubaček, M., Borimchuk, N.I., Zelyavskii, W.B., Ostrovskaya, N.F., and Yarosh, V.V., (2000), Shock synthesis of ternary diamond-like phases in the B C N system, Powder Metall. Metal Ceram. 39(9/100), 467–473.

    Article  Google Scholar 

  • Langenhorst, F., and Solozhenko, V.L., (2002), ATEM-EELS study of new diamond-like phases of the B-C-N system, Phys. Chem. Chem. Phys. 4, 5183–5188.

    Article  Google Scholar 

  • Le Godec, Y., Kurakevych, O.O., Munsch, P., Garbarino, G., and Solozhenko, V.L., (2009), Equation of state of orthorhombic boron, γ-B28. Solid State Comm. 149(33–34), 1356–1358.

    Google Scholar 

  • Mukhanov, V.A., Kurakevych, O.O., and Solozhenko, V.L., (2008a), Thermodynamic aspects of materials’ hardness: prediction of novel superhard high-pressure phases, High Press. Res. 28(4), 531–537.

    Article  ADS  Google Scholar 

  • Mukhanov, V.A., Kurakevych, O.O., and Solozhenko, V.L., (2008b), The interrelation between hardness and compressibility of substances and their structure and thermodynamic properties, J. Superhard Mater. 30(6), 368–378.

    Article  Google Scholar 

  • Oganov, A.R., Chen, J., Gatti,C., Ma, Y., Ma, Y., Glass, C.W., Liu, Z., Yu, T., Kurakevych, O.O., and Solozhenko, V.L., (2009), Ionic high-pressure form of elemental boron, Nature 457(7231), 863–867.

    Article  ADS  Google Scholar 

  • Solozhenko, V.L., (2002), Synthesis of novel superhard phases in the B-C-N system, High Press. Res. 22, 519–524.

    Article  ADS  Google Scholar 

  • Solozhenko, V.L., Andrault, D., Fiquet, G., Mezouar, M., and Rubie, D.C., (2001a), Synthesis of superhard cubic BC2N, Appl. Phys. Lett. 78, 1385–1387.

    Article  ADS  Google Scholar 

  • Solozhenko, V.L., Dub, S.N., and Novikov, N.V., (2001b), Mechanical properties of cubic BC2N, a new superhard phase, Diamond Relat. Mater. 10, 2228–2231.

    Article  ADS  Google Scholar 

  • Solozhenko, V.L., and Kurakevych, O.O., (2008), New boron subnitride B13N2: HP-HT synthesis, structure and equation of state, J. Phys.: Conf. Ser. 121, 062001.

    Article  ADS  Google Scholar 

  • Solozhenko, V.L., and Kurakevych, O.O., (2009), Chemical interaction in the B–BN system at high pressures and temperatures. Synthesis of novel boron subnitrides, J. Solid State Chem. doi: 10.1016/j.jssc.2009.03.003.

    Google Scholar 

  • Solozhenko, V.L., Le Godec, Y., and Kurakevych, O.O., (2006), Solid-state synthesis of boron subnitride, B6N: myth or reality?, Compt. Rend. Chimie 9(11–12), 1472–1475.

    Article  Google Scholar 

  • Solozhenko, V.L., Kurakevych, O.O., Andrault, D., Mezouar, M., and Le Godec, Y. (2007), Patent FR 0702637 Carbure de bore et son procédé de fabrication. – 11/04/2007.

    Google Scholar 

  • Solozhenko, V.L., Kurakevych, O.O., and Oganov, A.R., (2008), On the hardness of a new boron phase, orthorhombic γ-B28, J. Superhard Mater. 30(6), 428–429.

    Article  Google Scholar 

  • Solozhenko, V.L., Kurakevych, O.O., Andrault, D., Le Godec, Y., and Mezouar, M., (2009), Ultimate metastable solubility of boron in diamond: Synthesis of superhard diamondlike BC5, Phys. Rev. Lett. 102(1), 015506.

    Article  ADS  Google Scholar 

  • Tkachev, S.N., Solozhenko, V.L., Zinin, P.V., Manghnani, M.H. and Ming L.C., (2003), Elastic moduli of the superhard cubic BC2N phase by Brillouin scattering, Phys. Rev. B 68(5), 052104.

    Article  ADS  Google Scholar 

  • Zinin, P.V., Solozhenko, V.L., Malkin, A.J., and Ming, L.C., (2005), Atomic force microscopy studies of cubic BC2N, a new superhard phase, J. Mater. Sci. 40(11), 3009–3011.

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. LPMTM-CNRS, Institut Galilée, Université Paris Nord, 99, av. J. B. Clément, Villetaneuse, F-93430, France

    Vladimir L. Solozhenko

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  1. Vladimir L. Solozhenko
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Correspondence to Vladimir L. Solozhenko .

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Editors and Affiliations

  1. , Institute of Solid State Chemistry and M, Novosibirsk State University, Kutateladze 18, Novosibirsk, 630128, Russian Federation

    Elena Boldyreva

  2. , CARS, Argonne National Laboratory, Build, University of Chicago, 9700 South Cass Ave., Argonne, 60439, USA

    Przemyslaw Dera

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Solozhenko, V.L. (2010). High-Pressure Synthesis of Novel Superhard Phases in the B–C–N–O System. In: Boldyreva, E., Dera, P. (eds) High-Pressure Crystallography. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-9258-8_31

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