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Rényi Entropy and Complexity

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Abstract

Several important properties of the Rényi entropy and Rényi entropy power are presented. Uncertainty relations for the Rényi entropy including uncertainty relations for single particle densities of many particle systems in position and momentum spaces are discussed. Connection between Fisher information and Rényi entropy is studied. The Fisher-Rényi information plane and entropic product are presented.

Position and momentum space Rényi entropies of order α are presented for ground-state neutral atoms with atomic numbers Z=1–103. It is emphasized that the values of α≤1 (α≥1) stress the shell structure for position-space (momentum-space) Rényi entropies. Position and momentum space relative Rényi entropies of order α are presented for ground-state neutral atoms with atomic numbers Z=1–103. Simple hydrogen-like model densities are used as the reference. A relationship with the atomic radius and quantum capacitance is also discussed.

The relationship between the statistical complexity and the Rényi entropy is studied. A recently introduced, one-parameter extension of the LMC complexity is presented.

The maximum Rényi entropy principle is used to generalize the Thomas-Fermi model. A simple relation between the dimension and the Rényi parameter is emphasized.

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References

  1. Shannon CE (1948) A mathematical theory of communication. Bell Syst Tech J 27:379–423

    Google Scholar 

  2. Sears SB, Parr RG, Dinur U (1980) On the quantum-mechanical kinetic-energy as a measure of the information in a distribution. Isr J Chem 19:165–173

    CAS  Google Scholar 

  3. Gadre SR (1984) Information entropy and Thomas-Fermi theory. Phys Rev A 30:620–621

    Article  Google Scholar 

  4. Gadre SR, Sears SB, Chakravorty SJ, Bendale RD (1985) Some novel characteristics of atomic information entropies. Phys Rev A 32:2602–2606

    Article  CAS  Google Scholar 

  5. Tripathi AN, Sagar RP, Esquivel RO, Smith VH Jr (1992) Electron correlation in momentum space—the beryllium-atom isoelectronic sequence. Phys Rev A 45:4385–4392

    Article  CAS  Google Scholar 

  6. Yánez RJ, Van Assche W, Dehesa JS (1994) Position and momentum information entropies of the D-dimensional harmonic-oscillator and hydrogen-atom. Phys Rev A 32:3065–3079

    Article  Google Scholar 

  7. Hó M, Sagar RP, Smith VH Jr, Esquivel RO (1994) Atomic information entropies beyond the Hartree-Fock limit. J Phys B 27:5149–5157

    Article  Google Scholar 

  8. Hó M, Sagar RP, Pérez-Jordá JM, Smith VH Jr, Esquivel RO (1994) A molecular study of molecular information entropies. Chem Phys Lett 219:15–20

    Article  Google Scholar 

  9. Nagy Á, Parr RG (1996) Information entropy as a measure of the quality of an approximate electronic wave function. Int J Quant Chem 58:323–327

    Article  CAS  Google Scholar 

  10. Guevara NL, Sagar RP, Esquivel RO (2003) Shannon-information entropy sum as a correlation measure in atomic systems. Phys Rev A 67:012507

    Article  Google Scholar 

  11. Guevara NL, Sagar RP, Esquivel RO (2003) Information uncertainty-type inequalities in atomic systems. J Chem Phys 119:7030–7036

    Article  CAS  Google Scholar 

  12. Guevara NL, Sagar RP, Esquivel RO (2005) Local correlation measures in atomic systems. J Chem Phys 122:084101

    Google Scholar 

  13. Moustakidis ChC, Massen SE (2005) Dependence of information entropy of uniform Fermi systems on correlations and thermal effects. Phys Rev B 71:045102

    Article  Google Scholar 

  14. Sen KD (2005) Characteristic features of Shannon information entropy of confined atoms. J Chem Phys 123:074110

    CAS  Google Scholar 

  15. Fisher RA (1925) Theory of statistical estimation. Proc Camb Philos Soc 22:700–725

    Article  Google Scholar 

  16. Frieden BR (1989) Fisher information as the basis for the Schrodinger wave-equation. Am J Phys 57:1004–1008

    Article  Google Scholar 

  17. Reginatto M (1998) Derivation of the equations of nonrelativistic quantum mechanics using the principle of minimum Fisher information. Phys Rev A 58:1775–1778

    Article  CAS  Google Scholar 

  18. Frieden BR (1998) Physics from Fisher information. A unification. Cambridge University Press, Cambridge

    Book  Google Scholar 

  19. Nalewajski R (2003) Information principles in the theory of electronic structure. Chem Phys Lett 372:28–34

    Article  CAS  Google Scholar 

  20. Nagy Á (2003) Fisher information in density functional theory. J Chem Phys 119:9401–9405

    Article  CAS  Google Scholar 

  21. Romera E, Sánchez-Morena P, Dehesa JS (2005) The Fisher information of single-particle systems with a central potential. Chem Phys Lett 414:468–472

    Article  CAS  Google Scholar 

  22. Nagy Á (2006) Fisher information in a two-electron entangled artificial atom. Chem Phys Lett 425:154–156

    Article  CAS  Google Scholar 

  23. Nagy Á, Sen KD (2006) Atomic Fisher information versus atomic number. Phys Lett A 360:291–293

    Article  CAS  Google Scholar 

  24. Hornyák I, Nagy Á (2007) Phase-space Fisher information. Chem Phys Lett 437:132–137

    Article  Google Scholar 

  25. Romera E, Dehesa JS (2004) The Fisher-Shannon information plane, an electron correlation tool. J Chem Phys 120:8906–8912

    Article  CAS  Google Scholar 

  26. Romera E (2002) Stam’s principle D-dimensional uncertainty-like relationships and some atomic properties. Mol Phys 100:3325–3329

    Article  CAS  Google Scholar 

  27. Nagy Á, Sen KD (2006) Atomic Fisher information versus atomic number. Phys Lett A 360:291–293

    Article  CAS  Google Scholar 

  28. Liu SB (2007) On the relationship between densities of Shannon entropy and Fisher information for atoms and molecules. J Chem Phys 126:191107

    Article  Google Scholar 

  29. Nagy Á (2007) Fisher information and Steric effect. Chem Phys Lett 449:212–215

    Article  CAS  Google Scholar 

  30. Nagy Á, Liu SB (2008) Local wave-vector, Shannon and Fisher information. Phys Lett A 372:1654–1656

    Article  CAS  Google Scholar 

  31. Szabó JB, Sen KD, Nagy Á (2008) The Fisher-Shannon information plane for atoms. Phys Lett A 372:2428–2430

    Article  Google Scholar 

  32. Rényi A (1961) In: Proceedings of fourth Berkeley symp on mathematics, statistics and probability, vol 1. Univ California Press, Berkeley, p 547

    Google Scholar 

  33. Gühne O, Lewenstein M (2004) Entropic uncertainty relations and entanglement. Phys Rev A 70:022316

    Article  Google Scholar 

  34. Adesso G, Serafini A, Illuminati F (2004) Extremal entanglement and mixedness in continuous variable systems. Phys Rev A 70:022318

    Article  Google Scholar 

  35. Bovino A, Castagnolli G, Ekert A, Horodecki P, Alves CM, Serfienko AV (2005) Direct measurement of nonlinear properties of bipartite quantum states. Phys Rev Lett 95:240407

    Article  Google Scholar 

  36. Renner R, Gisin N, Kraus B (2005) Information-theoretic security proof for quantum-key-distribution protocols. Phys Rev A 72:012332

    Article  Google Scholar 

  37. Giovannetti V, Lloyd S (2004) Additivity properties of a Gaussian channel. Phys Rev A 69:062307

    Article  Google Scholar 

  38. Lévay P, Nagy S, Pipek J (2005) Elementary formula for entanglement entropies of fermionic systems. Phys Rev A 72:022302

    Article  Google Scholar 

  39. Romera E, de los Santos F (2008) Fractional revivals through Renyi uncertainty relations. Phys Rev A 78:013837

    Article  Google Scholar 

  40. Arbo DG, Reinhold CO, Burgdörfer J, Pattanayak AK, Stokely CL, Zhao W, Lancaster JC, Dunning FB (2003) Pulse-induced focusing of Rydberg wave packets. Phys Rev A 67:063401

    Article  Google Scholar 

  41. Romera E, Nagy Á (2008) Rényi information of atoms. Phys Lett A 372:4918–4922

    Article  CAS  Google Scholar 

  42. Nagy Á, Romera E (2009) Relative Rényi entropy for atoms. Int J Quant Chem 109:2490–2494

    Article  CAS  Google Scholar 

  43. Romera E, Nagy Á (2008) Fisher-Rényi entropy product and information plane. Phys Lett A 372:6823–6825

    Article  CAS  Google Scholar 

  44. López-Ruiz R, Mancini HL, Calbet X (1995) A statistical measure of complexity. Phys Lett A 209:321–326

    Article  Google Scholar 

  45. Nagy Á, Romera E (2009) Maximum Renyi entropy principle and the generalized Thomas-Fermi model. Phys Lett A 373:844–846

    Article  CAS  Google Scholar 

  46. Hirschman IJ (1957) A note on entropy. Am J Math 79:152–156

    Article  Google Scholar 

  47. Bialynicki-Birula I, Mycielski I (1975) Uncertainty relations for information entropy in wave mechanics. Commun Math Phys 44:129–132

    Article  Google Scholar 

  48. Beckner W (1975) Inequalities in Fourier-analysis. Ann Math 102:159–182

    Article  Google Scholar 

  49. Dembo A, Cover TM, Thomas JA (1991) Information theoretic inequalities. IEEE Trans Inf Theory 37:1501–1518

    Article  Google Scholar 

  50. Bialynicki-Birula I (2006) Formulation of the uncertainty relations in terms of the Renyi entropies. Phys Rev A 74:052101

    Article  Google Scholar 

  51. Koga T, Kanayama K, Watanabe S, Thakkar AJ (1999) Analytical Hartree-Fock wave functions subject to cusp and asymptotic constraints: He to Xe, Li+ to Cs+, H to I. Int J Quant Chem 71:491–497

    Article  CAS  Google Scholar 

  52. Koga T, Kanayama K, Watanabe S, Imai T, Thakkar AJ (2000) Analytical Hartree-Fock wave functions for the atoms Cs to Lr. Theor Chem Acc 104:411–413

    CAS  Google Scholar 

  53. Sagar RP, Ramirez JC, Esquivel RO, Ho M, Smith VH Jr (2001) Shannon entropies and logarithmic mean excitation energies from cusp- and asymptotic-constrained model densities. Phys Rev A 63:022509

    Article  Google Scholar 

  54. Sagar RB, Guevara NL (2008) Relative entropy and atomic structure. J Mol Struct, Theochem 857:72–77

    Article  CAS  Google Scholar 

  55. Ellenbogen JC (2006) Neutral atoms behave much like classical spherical capacitors. Phys Rev A 74:034501

    Article  Google Scholar 

  56. Iafrate GJ, Hess K, Krieger JB, Macucci M (1995) Capacitive nature of atomic-sized structures. Phys Rev B 52:10737–10739

    Article  CAS  Google Scholar 

  57. Perdew JP (1988) Correction. Phys Rev B 37:4267–4267

    Article  Google Scholar 

  58. Vignat C, Bercher JF (2003) Analysis of signals in the Fisher-Shannon information plane. Phys Lett A 312:27–33

    Article  CAS  Google Scholar 

  59. Zozor S, Portesi M, Vignat C (2008) Some extensions of the uncertainty principle. Physica A 387:19–20

    Article  Google Scholar 

  60. Hoffmann Ostenhof M, Hoffmann Ostenhof T (1977) “Schrödinger inequalities” and asymptotic behavior of the electron density of atoms and molecules. Phys Rev A 16:1782–1785

    Article  CAS  Google Scholar 

  61. Carlen EA (1991) Superadditivity of Fisher information and logarithmic Sobolev inequalities. J Funct Anal 101:194–211

    Article  Google Scholar 

  62. Carbó R, Arnau J, Leyda L (1980) How similar is a molecule to another—an electron-density measure of similarity between 2 molecular-structures. Int J Quant Chem 17:1185–1189

    Article  Google Scholar 

  63. Borgou A, Godefroid M, Indelicato P, De Proft F, Geerlings P (2007) Quantum similarity study of atomic density functions: insights from information theory and the role of relativistic effects. J Chem Phys 126:044102

    Article  Google Scholar 

  64. Angulo JC (2007) Atomic quantum similarity indices in position and momentum spaces. J Chem Phys 126:044106

    CAS  Google Scholar 

  65. Oniescu O (1966) C R Acad Sci Paris A 263:25

    Google Scholar 

  66. Hall MJW (1999) Universal geometric approach to uncertainty, entropy, and information. Phys Rev A 59:2602–2615

    Article  CAS  Google Scholar 

  67. Pennini F, Plastino A (2007) Localization estimation and global vs local information measures. Phys Lett A 365:263–267

    Article  CAS  Google Scholar 

  68. Hyman AS, Yaniger SI, Liebman JL (1978) Interrelations among X-ray-scattering, electron-densities, and ionization-potentials. Int J Quant Chem 19:757–766

    Article  Google Scholar 

  69. Pipek J, Varga I (1997) Statistical electron densities. Int J Quant Chem 64:85–93

    Article  CAS  Google Scholar 

  70. Borgou A, De Proft F, Geerlings P, Sen KD (2007) Complexity of Dirac-Fock atom increases with atomic number. Chem Phys Lett 44:186–191

    Article  Google Scholar 

  71. Romera E, López-Ruiz R, Sanudo J, Nagy Á (2009) Generalized statistical complexity and Fisher-Rényi entropy product in the H-atom. Int Rev Phys (IREPHY) 3:207–211

    Google Scholar 

  72. Levy M (1979) Universal variational functionals of electron-densities, 1st-order density-matrices, and natural spin-orbitals and solution of the v-representability problem. Proc Natl Acad Sci USA 76:6062–6065

    Article  CAS  Google Scholar 

  73. Lieb EH (1983) Density functional for coulomb systems. Int J Quant Chem 24:243–277

    Article  CAS  Google Scholar 

  74. Thomas LH (1927) The calculation of atomic fields. Proc Camb Philos Soc 23:542–548

    Article  CAS  Google Scholar 

  75. Fermi E (1928) Eine statistische Methode zur Bestimmung einiger Eigenschaften des Atoms und ihre Anwendung auf die Theorie des periodischen Systems der Elemente. Z Phys 48:73–79

    Article  CAS  Google Scholar 

  76. Kventsel GF, Katriel J (1981) Thomas-Fermi atom in N-dimensions. Phys Rev A 24:2299–2301

    Article  CAS  Google Scholar 

  77. March NH (1985) Scaling properties of total energy of heavy positive-ions in d-dimensions. J Math Phys 26:554–555

    Article  CAS  Google Scholar 

  78. Holas A, March NH (1994) Perturbation and density-gradient expansions in d-dimensions. Philos Mag 69:787–798

    Google Scholar 

  79. March NH, Kais S (1997) Kinetic energy functional derivative for the Thomas-Fermi atom in D dimensions. Int J Quant Chem 65:411–413

    Article  CAS  Google Scholar 

  80. Shivamoggi BK (1998) Thomas-Fermi theory in an n-dimensional space. Physica A 248:195–206

    Article  CAS  Google Scholar 

  81. Janes ET (1957) Information theory and statistical mechanics. Phys Rev 106:620–630

    Article  Google Scholar 

  82. Janes ET (1957) Information theory and statistical mechanics. II. Phys Rev 108:171–190

    Article  Google Scholar 

  83. Sanudo J, Pacheco AF (2006) Electrons in a box: Thomas-Fermi solution. Can J Phys 84:833–844

    Article  CAS  Google Scholar 

  84. Schuck P, Vinas X (2000) Thomas-Fermi approximation for Bose-Einstein condensates in traps. Phys Rev A 61:043603

    Article  Google Scholar 

  85. Cappelluti E, Delle Site L (2002) Generalized Thomas-Fermi approach for systems under pressure. Physica A 303:481–492

    Article  Google Scholar 

  86. Hodak M, Lu W, http://meetings.aps.org/link/BAPS.2006.MAR.V27.8

  87. Massen, Panos (2001) A link of information entropy and kinetic energy for quantum many-body systems. Phys Lett A 280:65–69

    Article  CAS  Google Scholar 

  88. Debnath L, Mikusinski P (2005) Introduction to Hilbert spaces. Academic Press, San Diego

    Google Scholar 

  89. López-Ruiz R, Nagy Á, Romera E, Sanudo J (2009) A generalized statistical complexity measure: applications to quantum systems. J Math Phys 50:123528

    Article  Google Scholar 

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Acknowledgements

E.R. acknowledges the Spanish project FQM-165/0207 (Junta de Andalucía) and No. FIS2008-01143. Á.N. acknowledges grant OTKA No. T67923. The work was also supported by the TAMOP 4.2.1/B-09/1/KONV-2010-0007 project. The project is co-financed by the European Union and the European Social Fund.

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Nagy, Á., Romera, E. (2011). Rényi Entropy and Complexity. In: Sen, K. (eds) Statistical Complexity. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3890-6_7

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