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Metal Complexes with Anionic Polyphosphorus Chains as Potential Precursors for the Synthesis of Metal Phosphides

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Phosphorus Compounds

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 37))

Abstract

While the synthesis, reactivity and properties of organic oligophosphanes have already been intensively studied, the number of metal complexes of the related anionic species described in the literature is still small. This chapter reviews the different synthetic methods for the preparation of metal complexes of catena-oligophosphanediides, as well as the reactivity of the (P4R4) 2− and (P4HR4) − ions. In addition, a brief review on the potential application of metal oligophosphanides as precursors for the preparation of metal-rich phosphides (MP x , where x < 1), monophosphides (MP) and phosphorus-rich polyphosphides (MP x , where x > 1) is given.

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Authors and Affiliations

  1. Departamento de Química Inorgánica y Analítica, E.S.C.E.T., Universidad Rey Juan Carlos, Calle Tulipán sn, 28933, Móstoles, Spain

    Santiago Gómez-Ruiz

  2. Institut für Anorganische Chemie der Universität Leipzig, Johannisallee 29, 04103, Leipzig, Germany

    Evamarie Hey-Hawkins

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  1. Santiago Gómez-Ruiz
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  1. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Maurizio Peruzzini

  2. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Luca Gonsalvi

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Gómez-Ruiz, S., Hey-Hawkins, E. (2011). Metal Complexes with Anionic Polyphosphorus Chains as Potential Precursors for the Synthesis of Metal Phosphides. In: Peruzzini, M., Gonsalvi, L. (eds) Phosphorus Compounds. Catalysis by Metal Complexes, vol 37. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3817-3_4

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