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Phosphine Acetylenic Macrocycles and Cages: Synthesis and Reactivity

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Book cover Phosphorus Compounds

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 37))

Abstract

The syntheses, structural properties, and reactivities are reviewed for phosphine-acetylenic macrocycles and cages. These compounds are of current interest for their phosphorus-containing π-conjugated molecular frameworks. A distinction is made between organic compounds, in which the building blocks are assembled by consecutive transformations, and organometallic structures, in which the coordinative ability of phosphorus is employed to assemble the monomeric building blocks.

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  1. Department of Chemistry and Pharmaceutical Sciences, Faculty of Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands

    Wannes Weymiens, J. Chris Slootweg & Koop Lammertsma

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  1. Wannes Weymiens
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  2. J. Chris Slootweg
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  3. Koop Lammertsma
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  1. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Maurizio Peruzzini

  2. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Luca Gonsalvi

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Weymiens, W., Slootweg, J.C., Lammertsma, K. (2011). Phosphine Acetylenic Macrocycles and Cages: Synthesis and Reactivity. In: Peruzzini, M., Gonsalvi, L. (eds) Phosphorus Compounds. Catalysis by Metal Complexes, vol 37. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3817-3_2

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