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Coordination-Driven Supramolecular Assembly of Phosphole-Based π-Conjugated Ligands

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Phosphorus Compounds

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 37))

Abstract

π-chromophores having a (2-pyridyl)phosphole moiety act as heteroditopic P,N-chelates towards a large range of transition metals. Due to the different nature of the donor atoms in these ligands, stereoselective coordination chemistry processes allow organizing of these derivatives into sophisticated architectures. Coordination-driven synthesis of C 2-symmetrical metallic complexes active in non-linear optics (NLO) and chiral metal-bis(azahelicene phosphole) assemblies are described. Furthermore, 1-phenyl-bis(2-pyridyl)phosphole can act as a N,P,N-chelate with bridging P-atoms in a very original coordination mode to stabilize a variety of metal dimers. Use of such Cu(I) dimers as molecular clips allows the characterization of π-stacked [2,2]metallacyclophanes that self-assemble in a very general way in the solid state along π-stacked columns.

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Authors and Affiliations

  1. Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France

    J. Crassous, C. Lescop & R. Réau

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  1. J. Crassous
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  2. C. Lescop
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  3. R. Réau
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Editors and Affiliations

  1. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Maurizio Peruzzini

  2. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Luca Gonsalvi

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Crassous, J., Lescop, C., Réau, R. (2011). Coordination-Driven Supramolecular Assembly of Phosphole-Based π-Conjugated Ligands. In: Peruzzini, M., Gonsalvi, L. (eds) Phosphorus Compounds. Catalysis by Metal Complexes, vol 37. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3817-3_11

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