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Polymers and Copolymers Containing Covalently Bonded Polyhedral Oligomeric Silsesquioxanes Moieties

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Applications of Polyhedral Oligomeric Silsesquioxanes

Part of the book series: Advances in Silicon Science ((ADSS,volume 3))

Abstract

The use of polyhedral oligomeric silsesquioxanes (POS or POSS®) as a moiety in polymers and copolymers is an area of research that has gained tremendous popularity in recent years. A number of excellent review articles have been published [1-8], as well as articles that elaborate on the larger field of silsesquioxanes [9-10]. In this chapter, we discuss T8 POS compounds, which are represented by the general formula Si8O12R8, where R is an organic group, or group suitable for polymerization or grafting. For ease of illustration, we have chosen to schematically represent the POS moiety as a cubic structure in many of the subsequent schemes that will appear in this chapter; this representation is shown in Fig. 4.1.

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Authors and Affiliations

  1. Department of Polymer Science and Engineering, University of Massachusetts Amherst, 120 Governors Drive, Amherst, MA, 01002, USA

    Katherine Grace Williams, Samuel Paul Gido & Edward Bryan Coughlin

  2. Department of Polymer Science and Engineering, University of Massachusetts Amherst, Amherst, MA, USA

    Katherine Grace Williams, Samuel Paul Gido & Edward Bryan Coughlin

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  1. Katherine Grace Williams
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  2. Samuel Paul Gido
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  1. Michigan Molecular Institute, W. Saint Andrews Rd. 1910, Midland, 48640, Michigan, USA

    Claire Hartmann-Thompson

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Williams, K.G., Gido, S.P., Coughlin, E.B. (2011). Polymers and Copolymers Containing Covalently Bonded Polyhedral Oligomeric Silsesquioxanes Moieties. In: Hartmann-Thompson, C. (eds) Applications of Polyhedral Oligomeric Silsesquioxanes. Advances in Silicon Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3787-9_4

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