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Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes

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Heterogenized Homogeneous Catalysts for Fine Chemicals Production

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 33))

Abstract

Homogeneous catalysts, which are mixed with the reactants at the molecular level, typically show the highest activity and selectivity as they offer chemically well-defined active sites and are not limited by heat and mass transport. However, an inherent disadvantage of the homogeneous catalysis is the need to separate the catalyst from a product after the reaction. Therefore, solid or immobilized homogeneous catalysts are preferred in industry. In this contribution we pay attention to chemoselectivity, regioselectivity and enantioselectivity in the synthesis of fine chemicals by means of hydrogenation reactions with immobilised homogeneous complexes. Preferential hydrogenation of one functional group in a molecule over another is the chemoselective process, while regioselective hydrogenation is the preferential formation of one constitutional isomer of the product in a reaction in which other isomers may also be formed, and the stereoselective hydrogenation is the formation of an excess of one stereoisomer over others. Homogeneous and heterogeneous catalytic transfer hydrogenations (CTH) were additionally introduced as alternative methods to the classical hydrogenation processes. They utilise a different hydrogen source from molecular hydrogen and can find their use for reduction of any type of groups.

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Acknowledgments

Authors wish to express their thanks to the Czech – Hungarian bilateral project Mobility Contact “Advanced Catalytic Reactions for Fine Chemicals” No. MEB 040802.

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Authors and Affiliations

  1. Department of Organic Chemistry, University of Szeged, Dóm tér 8, 6720, Szeged, Hungary

    Agnes Zsigmond, Ferenc Notheisz, Petr Kluson & Tomas Floris

Authors
  1. Agnes Zsigmond
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  2. Ferenc Notheisz
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  3. Petr Kluson
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  4. Tomas Floris
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Correspondence to Agnes Zsigmond .

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Editors and Affiliations

  1. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Pierluigi Barbaro

  2. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Francesca Liguori

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Zsigmond, A., Notheisz, F., Kluson, P., Floris, T. (2010). Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes. In: Barbaro, P., Liguori, F. (eds) Heterogenized Homogeneous Catalysts for Fine Chemicals Production. Catalysis by Metal Complexes, vol 33. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3696-4_9

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