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Covalent Heterogenization of Asymmetric Catalysts on Polymers and Nanoparticles

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Heterogenized Homogeneous Catalysts for Fine Chemicals Production

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 33))

Abstract

The development of enantioselective processes involving the use of catalytic species covalently bonded onto polymers and nanoparticles has gained a considerable importance over the last decade, as sustainability concerns have deeply influenced the practice of chemistry. In this review, an overview is given of the different strategies followed for the covalent immobilization of ligand–metal assemblies (for metal catalysis) and catalytic organic molecules (for organocatalysis) onto organic polymers and nanoparticles, paying special attention to the factors that control catalytic activity and enantioselectivity. Efforts devoted to the development of continuous flow processes with immobilized catalysts of these types are also reviewed.

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Authors and Affiliations

  1. Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans, 16, E-43007, Tarragona, Spain

    Ciril Jimeno, Sonia Sayalero & Miquel A. Pericàs

  2. Departament de Química Orgànica, Universitat de Barcelona, E-08028, Barcelona, Spain

    Miquel A. Pericàs

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  1. Ciril Jimeno
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  2. Sonia Sayalero
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  3. Miquel A. Pericàs
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Correspondence to Miquel A. Pericàs .

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  1. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Pierluigi Barbaro

  2. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Francesca Liguori

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Jimeno, C., Sayalero, S., Pericàs, M.A. (2010). Covalent Heterogenization of Asymmetric Catalysts on Polymers and Nanoparticles. In: Barbaro, P., Liguori, F. (eds) Heterogenized Homogeneous Catalysts for Fine Chemicals Production. Catalysis by Metal Complexes, vol 33. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3696-4_4

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