Abstract
As we saw in Chap. 11, the classical theory proved to be successful for fairly ideal mixtures. Meanwhile, for non-ideal mixtures BCNT can be sufficiently in error [1–4] and even lead to unphysical results as in the case of water-alcohol systems.
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Notes
- 1.
Note in this respect, that \(\overline{{n^s_a}}(n_a)\) is always positive, while the Gibbs excess numbers \(n_i^\mathrm{exc }\) can be both positive and negative.
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Kalikmanov, V.I. (2013). Coarse-Grained Theory of Binary Nucleation. In: Nucleation Theory. Lecture Notes in Physics, vol 860. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3643-8_13
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