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Ruthenium Catalysts Bearing Carboxylate Ligand

  • Conference paper
Green Metathesis Chemistry

Abstract

Novel class of ruthenium complex bearing carboxylate function is described in this highlight. Chemical activation of 14 providing highly active metathesis catalysts is discussed. New catalytic system due to high affinity to silica gel allow to efficient catalyst removal to obtain colorless products with low ruthenium contamination. Unique structural motif allows to introduce new carboxylate and sulfonate derived ligands without use of silver or thallium salts. Latest results of metathesis with derivative of 14 in ionic liquids and aqueous emulsions are presented

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References

  1. Trnka TM, Grubbs RH (2001) Acc Chem Res 34:18–29;

    Article  CAS  Google Scholar 

  2. Grubbs RH (ed.) (2003) Handbook of metathesis. Wiley-VCH, Weinheim, p. 1204;

    Google Scholar 

  3. Schrock RR, Hoveyda AH (2003) Angew Chem 115:4740–4782; Angew Chem Int Ed 42:4592–4633;

    Article  Google Scholar 

  4. Connon SJ, Blechert S (2003) Angew Chem 115:1944–1968; Angew Chem Int Ed 42:1900–1923;

    Article  Google Scholar 

  5. Astruc D (2005) New J Chem 29:42–56;

    Article  CAS  Google Scholar 

  6. Dragutan V, Dragutan I, Verpoort F (2005) Platinum Metals Rev 49:33–40

    Article  CAS  Google Scholar 

  7. Clavier H, Grela K, Kirschning A, Mauduit M, Nolan SP (2007) Angew Chem Int Ed 46:6786–6801

    Article  CAS  Google Scholar 

  8. Krause JO, Nuyken O, Wurst K, Buchmeiser MR (2004) Chem Eur J 10:777–784;

    Article  CAS  Google Scholar 

  9. Halbach TS, Mix S, Fischer D, Maechling S, Krause JO, Sievers C, Blechert S, Nuyken O, Buchmeiser MR (2005) J Org Chem 70:4687–4694;

    Article  CAS  Google Scholar 

  10. Mayr M, Wang D, Kröll R, Schuler N, Prühs S, Fürstner A, Buchmeiser MR (2005) Adv Synth Catal 347:484–492;

    Article  CAS  Google Scholar 

  11. Krause JO, Lubbad SH, Nuyken O, Buchmeiser MR (2003) Macromol Rapid Commun 24:875–878;

    Article  CAS  Google Scholar 

  12. Krause JO, Lubbad SH, Nuyken O, Buchmeiser MR (2003) Adv Synth Catal 345:996–1004

    Article  CAS  Google Scholar 

  13. Monfette S, Fogg DE (2006) Organometallics 25:1940–1944

    Article  CAS  Google Scholar 

  14. Zhang W, Liu P, Jin K, He R (2007) J Mol Catal A: Chem 275:194–199

    Article  CAS  Google Scholar 

  15. Samec JSM, Grubbs RH (2008) Chem Eur J 14:2686–2692

    Article  Google Scholar 

  16. Bieniek M, Bujok R, Cabaj M, Lugan N, Lavigne G, Arlt D, Grela K (2006) J Am Chem Soc 128:13652–13653

    Article  CAS  Google Scholar 

  17. Michrowska A, Mennecke K, Kunz U, Kirschning A, Grela K (2006) J Am Chem Soc 128:13261–13267

    Article  CAS  Google Scholar 

  18. Gawin R, Makal A, Woźniak K, Mauduit M, Grela K (2007) Angew Chem Int Ed 46:7206–7209

    Article  CAS  Google Scholar 

  19. Barbasiewicz M, Bieniek M, Michrowska A, Szadkowska A, Makal A, Woźniak K, Grela K (2007) Adv Synth Catal 349:193–203

    Article  CAS  Google Scholar 

  20. Goldup SM, Pilkington CJ, White AJP, Burton A, Barrett AGM (2006) J Org Chem 71:6185–6191

    Article  CAS  Google Scholar 

  21. Michrowska A, Gułajski Ł, Grela K (2006) Chem Commun 841–843;

    Google Scholar 

  22. Grela K, Kim M (2003) Eur J Org Chem 963–966

    Google Scholar 

  23. Kirschning A, Gułajski Ł, Mennecke K, Meyer A, Busch T, Grela K (2008) Synlett: 2692–2696;

    Google Scholar 

  24. Gułajski Ł, Michrowska A, Narożnik J, Kaczmarska Z, Rupnicki L, Grela K (2008) ChemSusChem 1:103–109;

    Article  Google Scholar 

  25. Michrowska A, Gułajski Ł, Kaczmarska Z, Mennecke K, Kirschning A, Grela K (2006) Green Chem 8:685–688

    Article  CAS  Google Scholar 

  26. Śledź P, Mauduit M, Grela K (2008) Chem Soc Rev 37:2433–2442;

    Article  Google Scholar 

  27. Rix D, Caïjo F, Laurent I, Gułajski Ł, Grela K, Mauduit M (2007) Chem Commun 3771–3773;

    Google Scholar 

  28. Audic N, Clavier H, Mauduit M, Guillemin J-C (2003) J Am Chem Soc 125:9248–9249;

    Article  CAS  Google Scholar 

  29. Clavier H, Nolan SP, Mauduit M (2008) Organometallics 27:2287–2292

    Article  CAS  Google Scholar 

  30. Gawin R, Grela K, Mauduit M unpublished results

    Google Scholar 

  31. Burtscher D, Grela K (2008) Angew Chem Int Ed. 48:442–454

    Article  Google Scholar 

  32. Lipshutz BH, Aguinaldo GT, Ghorai S, Voigtritter K (2008) Org Lett 10:1325–1328;

    Article  CAS  Google Scholar 

  33. Lipshutz BH, Ghorai S, Aguinaldo GT (2008) Adv Synth Catal 350:953–956;

    Article  CAS  Google Scholar 

  34. Lipshutz BH, Ghorai S (2008) Aldrichim Acta 41:59–72

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland

    Rafał Gawin & Karol Grela

Authors
  1. Rafał Gawin
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  2. Karol Grela
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Corresponding author

Correspondence to Rafał Gawin .

Editor information

Editors and Affiliations

  1. Romanian Academy, Institute of Organic Chemistry Bucharest, Romania

    Valerian Dragutan  & Ileana Dragutan  & 

  2. University of Liège, Institute of Chemistry Liège, Belgium

    Albert Demonceau

  3. Russian Academy of Sciences Topchiev Institute of Petrochemical Synthesis Moscow, Russia

    Eugene Sh. Finkelshtein

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Gawin, R., Grela, K. (2010). Ruthenium Catalysts Bearing Carboxylate Ligand. In: Dragutan, V., Demonceau, A., Dragutan, I., Finkelshtein, E.S. (eds) Green Metathesis Chemistry. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3433-5_6

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