Abstract
Addition polymerization of norbornenes bearing Me3Si-substituents was studied in the presence of Ni and Pd-containing catalyst systems. The main attention was paid to synthesis of bis(trimethylsilyl)norbornenes and their behaviour in the addition polymerization conditions. Unlike mono(trimethylsilyl)norbornene they were inactive in addition homopolymerization. However, their copolymerization with norbornene and its alkyl derivatives was successfully realized. Poly(5-(trimethylsilyl)norbornene) demonstrated high gas transport parameters in respect to hydrocarbon gases.
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Gringolts, M.L., Rogan, Y.V., Bermeshev, M.V., Lakhtin, V.G., Finkelshtein, E.S. (2010). Behavior of Silyl-Containing Norbornenes in the Conditions of Addition Polymerization. In: Dragutan, V., Demonceau, A., Dragutan, I., Finkelshtein, E.S. (eds) Green Metathesis Chemistry. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3433-5_26
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DOI: https://doi.org/10.1007/978-90-481-3433-5_26
Publisher Name: Springer, Dordrecht
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