Abstract
A new heterogeneous catalyst for ring opening metathesis polymerization (ROMP) has been prepared by immobilization of [RuCl2(p-cymene)]2 on siliceous mesoporous molecular sieves SBA-15. Activity of the catalyst was tested in ROMP of norbornene. Filtration test proved that the catalytic activity is bound to the solid phase. Catalyst could be easily separated from reaction mixture in contrast to the corresponding homogeneous system and therefore polymer with reduced amounts of catalyst residues was obtained.
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Bek, D., Balcar, H., Sedláček, J. (2010). [RuCl2(p-Cymene)]2 Immobilized on Mesoporous Molecular Sieves SBA-15 as Catalyst for ROMP of Norbornene. In: Dragutan, V., Demonceau, A., Dragutan, I., Finkelshtein, E.S. (eds) Green Metathesis Chemistry. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3433-5_25
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DOI: https://doi.org/10.1007/978-90-481-3433-5_25
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-3431-1
Online ISBN: 978-90-481-3433-5
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