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Activation of Cycloolefin Metathesis by Ultrasonic Irradiation

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Green Metathesis Chemistry

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Abstract

The present research focuses on the impact of power ultrasound on the synthesis of the tungsten-based metathesis catalytic system WCl6/Me4Sn and its activity in ring-opening metathesis polymerization of cyclooctene and cyclododecene. As compared to corresponding silent ROMP reactions with this mild catalytic system, altered reaction kinetics and different product selectivity have been found. Rate acceleration and an enhancement of oligomer formation have been clearly evidenced. The demonstrated possibility of employing technical grade solvents in ROMP induced by WCl6/Me4Sn is a further gain of the ultrasound strategy. Under the right conditions, ultrasound may thus promote greener, more cost effective and sustainable metathetic procedures.

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Author information

Authors and Affiliations

  1. Institute of Organic Chemistry of the Romanian Academy, 202B Spl. Independentei, 060023, Bucharest, Romania

    Ileana Dragutan, Valerian Dragutan & Petru Filip

  2. University of Liège, Sart Tilman, Liège, Belgium

    Albert Demonceau

Authors
  1. Ileana Dragutan
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  2. Valerian Dragutan
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  3. Petru Filip
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  4. Albert Demonceau
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Corresponding author

Correspondence to Ileana Dragutan .

Editor information

Editors and Affiliations

  1. Romanian Academy, Institute of Organic Chemistry Bucharest, Romania

    Valerian Dragutan  & Ileana Dragutan  & 

  2. University of Liège, Institute of Chemistry Liège, Belgium

    Albert Demonceau

  3. Russian Academy of Sciences Topchiev Institute of Petrochemical Synthesis Moscow, Russia

    Eugene Sh. Finkelshtein

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Dragutan, I., Dragutan, V., Filip, P., Demonceau, A. (2010). Activation of Cycloolefin Metathesis by Ultrasonic Irradiation. In: Dragutan, V., Demonceau, A., Dragutan, I., Finkelshtein, E.S. (eds) Green Metathesis Chemistry. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3433-5_20

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