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Green Metathesis Chemistry pp 157–171Cite as

Functionalisation of Vinylsubstituted (Poly)Siloxanes and Silsesquioxanes via Cross-Metathesis and Silylative Coupling Transformations

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Abstract

Applications of the catalytic transformations of vinyl group at silicon, i.e., cross-metathesis, silylative coupling with olefins and silylative coupling with acetylenes for functionalisation of vinylsubstituted (poly)organosiloxanes were overviewed. Cross-metathesis and silylative coupling of olefins with vinylsilicon compounds catalysed by ruthenium complexes were shown to constitute two valuable, complementary synthetic routes leading to functionalised (poly)siloxanes, cyclosiloxanes, silsesquioxanes and spherosilicates of great practical importance. Moreover, first examples of selective synthesis of variety of siloxanes with acetylene functionality via silylative coupling of acetylenes with vinylsiloxanes were described.

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Author information

Authors and Affiliations

  1. Adam Mickiewicz University, Faculty of Chemistry, Grunwaldzka 6, 60-780, Poznań, Poland

    Bogdan Marciniec & Cezary Pietraszuk

Authors
  1. Bogdan Marciniec
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  2. Cezary Pietraszuk
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Corresponding author

Correspondence to Bogdan Marciniec .

Editor information

Editors and Affiliations

  1. Romanian Academy, Institute of Organic Chemistry Bucharest, Romania

    Valerian Dragutan  & Ileana Dragutan  & 

  2. University of Liège, Institute of Chemistry Liège, Belgium

    Albert Demonceau

  3. Russian Academy of Sciences Topchiev Institute of Petrochemical Synthesis Moscow, Russia

    Eugene Sh. Finkelshtein

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Marciniec, B., Pietraszuk, C. (2010). Functionalisation of Vinylsubstituted (Poly)Siloxanes and Silsesquioxanes via Cross-Metathesis and Silylative Coupling Transformations. In: Dragutan, V., Demonceau, A., Dragutan, I., Finkelshtein, E.S. (eds) Green Metathesis Chemistry. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3433-5_12

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