Abstract
A synthetic pure water fluid inclusion showing a wide temperature range of metastability (Th − Tn ͌ 50°C; temperature of homogenization Th = 144°C and nucleation temperature of Tn = 89°C) was selected to make a kinetic study of the lifetime of an isolated microvolume of superheated water. The occluded liquid was placed in the metastable field by isochoric cooling and the duration of the metastable state was measured repetitively for 7 fixed temperatures above Tn. Statistically, metastability lifetimes for the 7 data sets follow the exponential reliability distribution, i.e., the probability of non nucleation within time t equals e −λt. This enabled us to calculate the half-life periods of metastability ρ for each of the selected temperature, and then to predict ρ at any temperature T>Tn for the considered inclusion, according to the equation ρ(s) = 22. l × e1.046×ΔT, (ΔT = T − Tn). Hence we conclude that liquid water in water-filled reservoirs with an average pore size ͌ 10 4μm3 can remain superheated over geological timelengths (1013 s), when placed in the metastable field at 24°C above the average nucleation temperature, which often corresponds to high liquid tensions (͌ −50 MPa).
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References
Pettenati, M., Mercury, L., and Azaroual, M. (2008) Capillary geochemistry in non-saturated zone of soils. Water content and geochemical signatures, Applied Geochem. 23(12), 3799–3818
Meslin, P.Y., Sabroux, J.-C., Berger, L., Pineau, J.-F., and Chassefière, E. (2006) Evidence of 210Po on martian dust at meridiani planum. J. Geophys. Res. 111, art. E09012, 14 p
Jouglet, D., Poulet, F., Milliken, R. E., Mustard, J. F., Bibring, J. P., Langevin, Y., Gondet B., and Gomez, C. (2007) Hydration state of the Martian surface as seen by Mars Express OMEGA: 1. Analysis of the 3 μm hydration feature, J. Geophys. Res. 112, art. E08S06, 20 p
Ramboz, C., and Danis, M. (1990). Superheating in the Red Sea? The heat-mass balance of the Atlantis II Deep revisited, Earth Planet. Sci. Lett. 97, 190–210
Shmulovich, K. I., and Graham, C. M. (2004). An experimental study of phase equilibria in the systems H2O−CO2−CaCl2 and H2O−CO2−NaCl at high pressures and temperatures (500–800°C, 0.5–0.9 GPa): geological and geophysical applications, Contr. Mineral. Petrol. 146, 450–462
Wagner, W., and Pruss, A. (2002) The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use, J. Phys. Chem. Ref. Data 31, 387–535
Kiselev, S. B., and Ely, J. F. (2001) Curvature effect on the physical boundary of metastable states in liquids, Physica A 299, 357–370
Speedy, R. J. (1982) Stability-limit conjecture. An interpretation of the properties of water, J. Phys. Chem. 86, 982–991
Debenedetti, P.G., and D'Antonio, M.C. (1986) On the nature of the tensile instability in metastable liquids and its relationship to density anomalies, J. Chem. Phys. 84(6), 3339–3345
Poole, P. H., Sciortino, F., Essmann, U., and Stanley, H. E. (1992) Phase behaviour of metastable water, Nature 360, 324–328
Mishima, O., and Stanley, H.E. (1998) The relationship between liquid, supercooled and glassy water, Nature 396, 329–335
Sastry, S., Debenedetti, P. G., Sciortino, F., and Stanley, H. E. (1996) Singularity-free interpretation of the thermodynamics of supercooled water, Phys. Rev. E 53, 6144–6154
Stanley, H.E., and Teixeira, J. (1980) Interpretation of the unusual behavior of H2O and D2O at low temperatures: tests of a percolation model, J. Chem. Phys. 73(7), 3404–3422
Shmulovich, K.I., Mercury, L., Thiéry, R., Ramboz, C., and El Mekki, M. (2008) Experimental superheating of water and aqueous solutions. Geochim, Cosmochim. Acta, submitted. Shmulovich K.I. (2008) Long-living superheated aqueous solutions: experiment, thermodynamics, geochemical applications, this volume.
Mercury, L., Azaroual, M., Zeyen, H., and Tardy, Y. (2003) Thermodynamic properties of solutions in metastable systems under negative or positive pressures, Geochim. Cosmochim, Acta 67, 1769–1785
Span, R., and Wagner, W. (1993) On the extrapolation behavior of empirical equation of state, Int. J. Thermophys. 18(6), 1415–1443
Roedder, E. (1967) Metastable superheated ice in liquid-water inclusions under high negative pressure, Science 155, 1413–1417
Green, J. L., Durben, D. J., Wolf, G. H., and Angell, C. A. (1990) Water and solutions at negative pressure: Raman spectroscopic study to -80 Megapascals, Science 249, 649–652
Zheng, Q., Durben, D. J., Wolf, G. H., and Angell, C. A. (1991) Liquids at large negative pressures: water at the homogeneous nucleation limit, Science 254, 829–832
Alvarenga, A. D., Grimsditch, M., and Bodnar, R. J. (1993) Elastic properties of water under negative pressures, J. Chem. Phys. 98, 11, 8392– 8396
Ramboz, C., Orphanidis, E., Oudin, E., Thisse, Y., and Rouer, O. (2008), Metastable fluid discharge by the Atlantis Deep submarine geyser: the heat-mass balance of the stratified lower brine revisited in the light of new fluid inclusion data. This volume.
Debenedetti, P. G. (1996) Metastable liquids. Concepts and principles. Princeton University Press, Princeton, 411 p
Takahashi, M., Izawa, E., Etou, J., and et Ohtani, T. (2002) Kinetic characteristic of bubble nucleation in superheated water using fluid inclusions, J. Phys. Soc. Japan 71(9), 2174–2177
Mercury, L., Pinti, D. L., and Zeyen, H. (2004) The effect of the negative pressure of capillary water on atmospheric noble gas solubility in ground water and palaeotemperature reconstruction, Earth & Planetary Sci. Lett. 223, 147–161
Lassin, A., Azaroual, M., and Mercury, L. (2005) Geochemistry of unsaturated soil systems: aqueous speciation and solubility of minerals and gases in capillary solutions, Geochim. Cosmochim, Acta 69, 22, 5187–5201
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Mekki, M.E., Ramboz, C., Perdereau, L., Shmulovich, K., Mercury, L. (2010). Lifetime of Superheated Water in a Micrometric Synthetic Fluid Inclusion. In: Rzoska, S., Drozd-Rzoska, A., Mazur, V. (eds) Metastable Systems under Pressure. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3408-3_20
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DOI: https://doi.org/10.1007/978-90-481-3408-3_20
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