Abstract
The recent advances in olefin metathesis highlight the impact of Ring Opening Metathesis Polymerisation (ROMP) as a powerful technique for macromolecular engineering and synthesis of smart materials with well-defined structures. ROMP has attracted a considerable research attention recently particularly by industry largely due to the development of well-defined metal complexes as initiators and also because of the award of the Noble Prize for Chemistry in 2005 to three scientists (Chauvin, Grubbs, Schrock) for their contributions in this area. This chapter discusses several interesting examples in order to demonstrate that ROMP is a power tool in macromolecular engineering and that it allows the design and synthesis of polymers with novel topologies.
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Khosravi, E., Castle, T.C., Kujawa, M., Leejarkpai, J., Hutchings, L.R., Hine, P.J. (2009). Romp: The Method of Choice for Precise Macromolecular Engineering and Synthesis of Smart Materials. In: Khosravi, E., Yagci, Y., Savelyev, Y. (eds) New Smart Materials via Metal Mediated Macromolecular Engineering. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3278-2_14
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