Abstract
Wereview the different strategies to produce mechanical oscillations by coupling a gel which swells/deswells as a function of the chemical composition of its solvent (‘chemo-responsive gel’) with an autocatalytic reaction kept far from equilibrium. Afterwards we focus on the case of oscillations obtained by coupling the gel with a reaction that exhibits spatial bistability. The principles are illustrated with a simple swelling and reaction-diffusion model and experimental data obtained with the chlorite-tetrathionate reaction an a polyelec-trolyte gel.
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References
P. De Kepper, J. Boissonade, and I. Szalai, this volume
R. Yoshida, this volume
R. Yoshida, T. Yamaguchi, and H. Ichijo, Mat. Sci. Eng. C 4, 107 (1996).
C.J. Crook, A. Smith, R.A.L. Jones and J. Ryan, Phys. Chem. Chem. Phys. 4, 1367 (2002).
A.J. Ryan et al., Faraday Discuss. 128, 55 (2005).
J.R. Howse, P.D. Topham, C.J. Crook, A.J. Gleeson, W. Bras, R.A.L. Jones, and A. J. Ryan, Nano Lett. 6, 73 (2006).
P.D. Topham, J.R. Howse, C.J. Crook, A.J. Gleeson, W. Bras, S.P. Armes, R.A.L. Jones and A. J. Ryan, Macromolecules 40, 4393 (2007).
R.J. Field and M. Burger, Oscillations and Traveling Waves in Chemical Systems (Wiley, New York, 1985).
R. Kapral and K. Showalter, Chemical Patterns and Waves (Klüwer, Amsterdam, 1995).
I.R. Epstein and J.A. Pojman, An Introduction to Nonlinear Chemical Dynamics (Oxford University Press, New York, Oxford, 1998).
R. Yoshida and T. Takahashi, J. Am. Chem. Soc. 118, 5134 (1996).
R. Yoshida, M. Tanaka, S. Onodera, T. Yamaguchi, and E. Kokufuta, J. Phys. Chem. A104, 7549 (2000).
R. Yoshida, E. Kokufuta, and T. Yamaguchi, Chaos 9, 260 (1999).
K. Miyakawa, F. Sakamoto, R. Yoshida, E. Kokufuta, and T. Yamaguchi, Phys. Rev. E 62, 793 (2000).
V.V. Yashin and A.C. Balasz, Macromolecules 39, 2024 (2006).
K. Sekimoto, J. Phys. II (France) 1, 19 (1991).
K. Sekimoto, J. Phys. II (France) 2, 1755 (1992).
S. Villain, Comportement mécanique de gels soumis à des réactions autocatalytiques (in French). PhD Thesis, Univ. Paris VII (2007).
S. Métens, S. Villain, and P. Borckmans, this volume
V. V. Yashin and A. C. Balasz, Science 314, 798 (2006).
V. V. Yashin and A. C. Balasz, J. Chem. Phys. 126, 124707 (2007).
A.P. Dhanarajan, G.P. Misra, and R.A. Siegel, J. Phys. Chem. A106, 8835 (2002).
G.P. Misra and R.A. Siegel, J. Controll. Release 81, 1 (2002).
X. Zou and R.A. Siegel, J. Chem. Phys. 110, 2267 (1999).
R.A. Siegel, this volume
J. Boissonade, Phys. Rev. Lett. 90, 188302 (2003).
J. Boissonade, Chaos 15, 023703 (2005).
F. Gauffre, V. Labrot, J. Boissonade, and P. De Kepper, “Spontaneous deformations in polymer gels driven by chemomechanical instabilities” in Nonlinear Dynamics in Polymeric Systems, ed. J.A. Pojman and Q. Tran-Cong-Miyata (ACS Symposium Series 869, ACS, Washington, DC, 2003), p. 80
V. Labrot, Structures chimio-mécaniques entretenues: couplage entre une réaction à autocatalyse acide et un gel de polyélectrolyte (in French). PhD Thesis, Univ. Bordeaux I (2004).
V. Labrot, P. De Kepper, J. Boissonade, I. Szalai, and F. Gauffre, J. Phys. Chem. B109, 21476 (2005).
J. Boissonade, P. De Kepper, F. Gauffre and I. Szalai, Chaos 16, 037110 (2006).
M. Fuentes, M.N. Kuperman, J. Boissonade, E. Dulos, F. Gauffre and P. De Kepper, Phys. Rev. E 66, 056205 (2002).
F. Gauffre, V. Labrot, J. Boissonade, P. De Kepper, and E. Dulos, J. Phys. Chem. A107, 4452 (2003).
D. Strier and J. Boissonade, Phys. Rev. E 70, 016210 (2004).
I. Szalai, F. Gauffre, V. Labrot, J. Boissonade, and P. De Kepper, J. Phys. Chem. A109, 7849 (2005).
A. Toth, I. Lagzi, and D. Horvath, J. Phys. Chem. 100, 14837 (1996).
D. Horvath and A. Toth, J. Chem. Phys. 108, 1447 (1997).
P. Blanchedeau and J. Boissonade, Phys. Rev. Lett., 81, 5007 (1998).
P. Blanchedeau, J. Boissonade, and P. De Kepper, Physica D 147, 283 (2000).
K. Benyaich, T. Erneux, S. Métens, S. Villain, and P. Borckmans, Chaos 16, 037100 (2006).
I. Szalai and P. De Kepper, Phys. Chem. Chem. Phys. 8, 1105 (2006).
Z. Virányi, I. Szalai, J. Boissonade, and P. De Kepper, J. Phys. Chem. 111A, 8090 (2007).
P. Borckmans and S. Métens, this volume
M. Doi, Introduction to Polymer Physics (Clarendon Press, Oxford University Press, Oxford, 1996).
T. Tanaka and D.J. Fillmore, J. Chem. Phys. 70, 1214 (1979).
A. Onuki, Adv. Polym. Sci. 109, 63 (1993).
T. Tomari and M. Doi, Macromolecules 28, 8334 (1995).
M.A.T. Bisschops, K.Ch.A.M. Luyben and L.A.M. van der Wielen, Ind. Eng. Chem. Res. 37, 3312 (1998).
E.C. Achilleos, K.N. Christodoulou and I.G. Kevrekidis, Comp. Theor. Polym. Sci. 11, 63 (2001).
B. Barrière and L. Leibler, J. Polym. Sc. 41, 166 (2003).
J. Dolbow, E. Fried and H. Ji, J. Mech. Phys. Solids 52, 51 (2004).
T. Yamaue and M. Doi, Phys. Rev. E 69, 041402 (2004).
T. Yamaue, T. Tanigushi and M. Doi, Mol. Phys. 102, 167 (2004).
A.G. Ogston, B.N. Preston and J.D. Wells, Proc. R. Soc. Lond. A 333, 297 (1973).
A.Y. Grossberg and A.R. Khokhlov, Statistical Physics of Macromolecules (AIP Press, New York, 1994).
G. Strobl, The Physics of Polymers (Springer, Berlin, Heidelberg, New York, 1997).
B. Erman and J.E. Mark, Structure and Properties of Rubberlike Networks (Oxford University Press, Oxford 1997).
J. Bastide and S.J. Candau, “Structure of gels investigated by static scattering techniques” in Physical Properties of Polymeric Gels, ed. J.P. Cohen Addad (Wiley, Chichester, 1996), p. 143
P.J. Flory, Principles of Polymer Chemisty (Cornell University Press, Ithaca, NY, 1953).
E.M. Cussler, Diffusion: Mass Transfer in Fluid Systems (Cambridge University Press, Cambridge, 1997).
M.M. Tomadakis and S.V. Sotirchos, AIChE J. 39 397 (1993).
J. Rička and T. Tanaka, Macromolecules 17, 2916 (1984).
J. Newman and K.E. Thomas-Alyea, Electrochemical Systems (Wiley, New York, 2004).
J. Boissonade, Eur. Phys. J. E 28, 337 (2009).
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Boissonade, J., De Kepper, P. (2009). Chemomechanics: Oscillatory Dynamics in Chemoresponsive Gels. In: Borckmans, P., De Kepper, P., Khokhlov, A.R., Métens, S. (eds) Chemomechanical Instabilities in Responsive Materials. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2993-5_4
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DOI: https://doi.org/10.1007/978-90-481-2993-5_4
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