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N-Heterocyclic Carbene Complexes in other Transition Metal Mediated Reactions

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N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 32))

Abstract

This chapter describes reactions involving NHC-transition metal complexes that have not been considered in previous chapters. The reactions are treated in six sections, presenting borrowing hydrogen reactions where C–C and C–N bonds are formed from alcohols in the first section. Then dehydration reactions either with or without coupling are discussed. The dynamic kinetic resolution of alcohols using a combination of NHC–TM catalysed racemisation coupled with enzyme-catalysed resolution is described. The next section considers the emerging area of dehydrogenation reactions, followed by a section discussing the isomerisation of alkene-containing substrates. The final section details hydrogen/deuterium exchange reactions within aryl and alkyl substrates.

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Authors and Affiliations

  1. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK

    Jonathan M. J. Williams

Authors
  1. Tracy D. Nixon
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  2. Jonathan M. J. Williams
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Corresponding author

Correspondence to Jonathan M. J. Williams .

Editor information

Editors and Affiliations

  1. School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife, KY16 9ST, United Kingdom

    Catherine S.J. Cazin

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Nixon, T.D., Williams, J.M.J. (2010). N-Heterocyclic Carbene Complexes in other Transition Metal Mediated Reactions. In: Cazin, C. (eds) N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis. Catalysis by Metal Complexes, vol 32. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2866-2_11

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