Abstract
The study of the processes of latex film formation presents many challenges to the experimentalist. Each stage of film formation has specific requirements for any analytical technique.
In the drying stage, there is a need to measure water concentration at various positions laterally and through the depth of a wet film. Latex in the wet state precludes the use of techniques that require the sample to be held in a high vacuum, such as Auger spectroscopy or secondary ion mass spectrometry. Electron microscopy conventionally has a high vacuum in the sample chamber, and so it cannot be used in the standard way.
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References
Anczykowski B., Gotsmann B., Fuchs H., Cleveland J.P., Elings V.B. (1999) How to measure energy dissipation in dynamic mode atomic force microscopy. Appl Surf Sci 140:376–382
Alig I., Lellinger D., Sulimma J., Tadjbakhsch S. (1997) Ultrasonic shear wave reflection method for measurements of the viscoelastic properties of polymer films. Rev Sci Instrum 68:1536–1542
Amalvy J.I., Lasquibar C.A., Arizaga R., Rabal H. and Trivi M. (2001) Application of dynamic speckle interferometry to the drying of coatings. Prog Organic Coat 42:89–99
Arnold C. et al. (2009) Mapping the route from wet to dry. European Coatings Journal 11:28–32
Bahra M., Elliott D., Reading M., Ryan R. (1992) A novel approach to thermal analysis of thin films. J Therm Anal 38:543–555
BallauffM. (2001) SAXS. and SANS studies of polymer colloids. Curr Opin Coll Interf Sci 6:132–139
Bar G., Delineau L., Brandsch R., Bruch M. Whangbo (1999) Importance of the indentation depth in tapping-mode atomic force microscopy study of compliant materials. Appl. Phys. Lett. 75:4198–4200.
Baumgart T., Cramer S., Jahr T., Veniaminov A., Adams J., Fuhrmann J., Jeschke G., Wiesner U., Spiess H.W., Bartsch E., Sillescu H. (2000) Film-forming colloidal dispersions studied by tracer methods. Macromol Symp 151:451–457
Belaroui F., Grohens Y., Boyer H., Holl Y. (2000) Depth profiling of small molecules in dry latex films by confocal Raman spectroscopy. Polymer 41:7641–7645
Belaroui F., Cabane B., Dorget M., Grohens Y., Marie P., Holl Y. (2003) Small-angle neutron scattering study of particle coalescence and SDS desorption during film formation from carboxylated acrylic latices. J Coll Interf Sci 262:409–417
Belaroui F., Hirn M.P., Grohens Y., Marie P., Holl Y. (2003) Distribution of water-soluble and surface-active low-molecular-weight species in acrylic latex films. J Coll Interf Sci 261:336–348
Bennett G., Gorce J.-P., Keddie J.L., McDonald P.J., Berglind H. (2003) Magnetic resonance profiling studies of the drying of film-forming aqueous dispersions and glue layers. Mag Res Imaging 21:235–41.
Betzig E., Trautman J.K., Harris T.D., Weiner J.S., Kostelak R.L. (1991) Breaking the diffraction barrier — Optical microscopy on a nanometric scale. Science 251:1468–1470
Betzig E., Finn P.L., Weiner J.S. (1992) Combined shear force and near-field scanning optical microscopy. Appl Phys Lett 60:2484–2486
Binnig G., Quate C.F., Gerber Ch. (1986) Atomic force microscope. Phys Rev Lett 56:930–933
Boczar E.M., Dionne B.C., Fu Z., Kirk A.B., Lesko P.M., Koller A.D. (1993) Spectroscopic studies of polymer interdiffusion during film formation. Macro-molecules 26:5772–5781
Bogner A., Thollet G., Basset D., Jouneau P.-H., Gauthier C. (2005) Wet STEM: A new development in environmental SEM. for imaging nano-objects included in a liquid phase. Ultramicroscopy 104:290–301
Bradford E.B. (1952) Electron microscope study of plasticized latices. J Appl Phys 23:609–612
Bradford E.B., VanderhoffJ.W. (1963) The morphology of synthetic latexes. J Polym Sci: Pt C. 3:41–64
Breugem A.J., Bouchama F., Koper G.J.M. (2005) Diffusing wave spectroscopy: A novel rheological method for drying paint films. Surf Coat Intern Pt B: Coat Trans 88, B2:83–156
Brun A., Brunel L., Snabre P. (2006) Adaptive speckle imaging interferometry (ASII): New technology of advance drying analysis of coatings. Surface Coatings International Pt B: Coatings Transactions 88:251–254
Brun A., Dihang H., Brunel L. (2008) Film formation of coatings studied by diffusing-wave spectroscopy. Prog Organic Coatings 61:181–191
Butt H.-J., Kuropka R., Christensen B. (1994) Latex film formation studied with the atomic force microscope: Influence of aging and annealing. Coll Polym Sci 272:1218–1223
Butt H.-J., Gerharz B. (1995) Imaging homogeneous and composite latex particles with an atomic force microscope. Langmuir 11:4735–4741
Butt H.-J., Kuropka R. (1995) Surface structure of latex films, varnishes, and paint films studied with an atomic force microscope. J Coatings Tech 67(848):101–107
Cameron R.E., Donald A.M. (1994) Minimizing sample evaporation in the environmental scanning electron microscope. J Microscopy Oxford 173:227– 237
Ciampi E., Goerke U., Keddie J.L., McDonald P.J. (2000) Lateral transport of water during drying of alkyd emulsions. Langmuir 16:1057–1065
Corcoran E.M. (1969) Determining stresses in organic coatings using plate beam deflection. J Paint Techn 41(538):635–40
Cramer S.E., Jeschke G., Spiess H.W. (2002a) EPR studies on film formation of colloidal dispersions, 1. Site selectivity and techniques. Macromol Chem Phys 203:182–191
Cramer S.E., Jeschke G., Spiess H.W. (2002b) EPR studies on film formation of colloidal dispersions, 2. Drying, film annealing, and film rewetting. Macromol Chem Phys 203:192–198
Crowley T.L., Sanderson A.R., Morrison J.D., Barry M.D., Morton-Jones A.J., Rennie A.R. (1992) Formation of bilayers and Plateau borders during the drying of film-forming latexes as investigated by small-angle neutron scattering. Langmuir 8:2110–2123
Danilatos G.D. (1988) Foundations of environmental scanning electron microscopy. Adv Electronics & Electron Phys 71:109–250
Derks D., Wisman H., van Blaaderen A., Imhof A. (2004) Confocal microscopy of colloidal dispersions in shear flow using a counter-rotating cone-plate shear cell. J Phys Condens Matt 16: S3917–S3927
Dillon R.E., Matheson L.A., Bradford E.B. (1951) Sintering of synthetic latex particles. J Coll Sci 6:108–117
Dingenouts N., BallauffM. (1999) First stage of film formation by latexes investigated by small-angle X-ray scattering. Langmuir 15:3283–3288
Dingenouts N., BallauffM. (1998) Assessment of spatial order in dried latexes by small-angle X-ray scattering. Macromolecules 31:7423–7429
Distler D., Kanig G. (1980) Morphology of (meth-)acrylic latex films. Org Coating Plast Chem 43:606–610
Djabourov M., Grillon Y., Leblond J. (1995) The sol-gel transition in gelatin viewed by diffusing colloidal probes. Polym Gels Networks 3:407–428
Dobler F., Pith T., Lambla M., Holl Y. (1992) Coalescence mechanisms of polymer colloids. 2. Coalescence with evaporation of water. J Coll Interf Sci 152:12–21.
Donald A.M., He C.B., Royall C.P., Sferrazza M., Stelmashenko N.A., Thiel B.L. (2000) Applications of environmental scanning electron microscopy to colloi-dal aggregation and film formation. Coll Surf A Physicochem Eng Asp 174:37–53
Donald A.M. (2003) The use of environmental scanning electron microscopy for imaging wet and insulating materials. Nature Materials 2:511–516
Du Chesne A., Gerharz B., Lieser G. (1997) The segregation of surfactant upon film formation of latex dispersions: an investigation by energy filtering transmission electron microscopy. Polym Intern 43:187–196
Dullens R.P.A., Claesson M., Derks D., van Blaaderen A., Kegel W.K. (2003) Preparation and properties of cross-linked fluorescent poly(methyl methacry-late) latex colloids. Langmuir 19:5963–5966
Dullens R.P.A., Claesson E.M., Kegel W.K. (2004) Preparation and properties of cross-linked fluorescent poly(methyl methacrylate) latex colloids. Langmuir 20:658–664
Dürig U., Pohl D.W., Rohner F (1986) Near-field optical-scanning microscopy, J Appl Phys 59:3318–3327.
Eckersley, Rudin A. (1993) The effect of plasticization and pH. on film formation of acrylic latexes. J Appl Polym Sci 48:1369–1381
Eichler H.J., Günther P., Pohl D.W. (1986) Laser-induced dynamic gratings. Springer, Berlin.
Eidmann G., Savelberg R., Blümler P. (1996) The NMR MOUSE, a mobile universal surface explorer. J Magn Res Ser A 122:104–109
Ekanayake P., McDonald P.J., Keddie J.L. (2009) An experimental test of the scaling prediction for the spatial distribution of water during the drying of colloidal films. European Physical Journal — Special Topics 166:21–27.
El-Aasser M.S., Robertson A.A. (19975) Film formation of latexes. J Paint Techn 47(611):50–53
Erich S.J.F., Laven J., Pel L., Huinink H.P., Kopinga K. (2005) Dynamics of cross linking fronts in alkyd coatings. Appl Phys Lett 86:134105 (3 pp)
Erich S.J.F., Laven J., Pel L., Huinink H.P., Kopinga K. (2005b) Comparison of NMR and confocal Raman microscopy as coatings research tools. Prog Org Coat 52:210–216
Erich S.J.F., Laven J., Pel L., Huinink H.P., Kopinga K. (2006) NMR depth profiling of curing alkyd coatings with different catalysts. Prog Org Coat 55:105–111
Erich S.J.F., Laven J., Pel L., Huinink H.P., Kopinga K. (2006b) Influence of catalyst type on the curing process and network structure of alkyd coatings. Polymer 47:1141–1149
Erkselius S., Wadsoe L., Karlsson O.J. (2007) A sorption balance-based method to study the initial drying of dispersion droplets. Coll Polym Sci 285:1707–1712
Faccia, P.A., Pardini O.R., Amalvy J.I., Cap N., Grumel E.E., Arizaga R., Trivi M (2009) Prog Organic Coatings 64:350–355
Farinha J.P.S., Martinho J.M.G., Yekta A., Winnik M.A. (1995) Direct nonradia-tive energy transfer in polymer interphases: fluorescence decay functions from concentration profiles generated by Fickian diffusion. Macromolecules 28:6084–6088
Farinha J.P.S., Martinho J.M.G., Kawaguchi S., Yekta A., Winnik M.A. (1996) Latex film formation probed by nonradiative energy transfer: Effect of grafted and free poly(ethylene oxide) on a poly(n-butyl methacrylate) latex. J Phys Chem 100:12552–12558
Farinha J.P.S., Vorobyova O., Winnik M.A. (2000) An energy transfer study of the interface thickness in blends of poly(butyl methacrylate) and poly(2-ethylhexyl methacrylate). Macromolecules 33:5863–5873
Feng J.R., Winnik M.A. (1997) Effect of water on polymer diffusion in latex films. Macromolecules 30:4324–4331
Feng J.R., Odrobina E., Winnik M.A. (1998) Effect of hard polymer filler particles on polymer diffusion in a low-Tg latex film. Macromolecules 31:5290–5299
Fletcher A.L., Thiel B.L., Donald A.M. (1997) Amplification measurements of alternative imaging gases in environmental SEM J Phys D. 30:2249–2257
Fouchama F., Estramil G., Autin A.J.E., Koper G.J.M. (2002) Film formation from concentrated emulsions studied by simultaneous conductometry and gra-vimetry. Coll Surf A: Physicochem Eng Asp 210:129–135
Gaillard C., Stadelmann P.A., Plummer C.J.G., Fuchs G. (2004) Practical method for high-resolution imaging of polymers by low-voltage scanning electron microscopy. Scanning 26:122–130.
Galembeck A., Costa C.A.R., da Silva M.C.V.M., Souza E.F., Galembeck F. (2001) Scanning electric potential microscopy imaging of polymers: electrical charge distribution in dielectrics. Polymer 42:4845–4851
Glover P.M., Aptaker P.S., Bowler J.R., Ciampi E., McDonald P.J. (1999) A novel high-gradient permanent magnet for the profiling of planar films and coatings. J Magn Reson 139:90–97
Goh M.C., Juhué D., Leung O.-M., Wang Y., Winnik M.A. (1993) Annealing effects on the surface structure of latex films studied by atomic force microscopy. Langmuir 9:1319–1322
Gorce J.-P., McDonald P.J., Keddie J.L. (2002) Vertical water distribution during the drying of polymer films formed from emulsions. Eur Phys J E 8:421–429.
Goudy A., Gee M.L., Biggs S., Underwood S. (1995) Atomic force microscopy study of polystyrene latex film morphology: Effects of aging and annealing. Langmuir 11:4454–4459
Guigner D., Fischer C., Holl (2001) Film formation from concentrated reactive silicone emulsions. 1. Drying mechanism. Langmuir 17:3598–3606
Haley J.C., Liu Y., Winnik M.A., Demmer D., Haslett T., Lau W. (2007) Tracking polymer diffusion in a wet latex film with fluorescence resonance energy transfer. Rev Sci Instrum 78:084101
Haley J.C., Liu Y., Winnik M.A., Lau W. (2008) The onset of polymer diffusion in a drying acrylate latex: how water initially retards coalescence but ultimately enhances diffusion. J Coat Technol Res 5(2):157–168
Hellgren A.-C., Wallin M., Weissenborn P., McDonald P.J., Glover P.M., Keddie J.L. (2001) New techniques for determining the extent of crosslinking in coatings. Prog Org Coatings 43:85–98
Hore P.J. (1995) Nuclear Magnetic Resonance, Oxford University Press
James P.J., Antognozzi M., Tamayo J., McMaster T.J., Newton J.M., Miles M.J (2001) Langmuir 17:349–360
Joanicot M., Wong K., Richard J., Maquet J., Cabane B. (1993) Ripening of cellular latex films. Macromolecules 26:3168–3175
Johannsmann D. (2008) Viscoelastic, mechanical and dielectric measurements on complex samples with the quartz crystal microbalance. Phys Chem Chem Phys 10:4516–4534
Juhué D., Wang Y., Winnik M.A. (1993) Influence of a coalescing aid on polymer diffusion in poly(butyl methacrylate) latex films. Makromol Chem Rapid Commun 14:345–349
Juhué D., Lang J. (1994a) Latex film surface morphology studies by atomic force microscopy: effect of a non-ionic surfactant post-added to latex dispersion. Coll Surf A: Physicochem Eng Asp 87:177–185
Juhué D., Lang J. (1994b) Latex film formation in the presence of organic solvents. Macromolecules 27:695–701
Juhué D., Lang J. (1995) Film formation from dispersions of core-shell latex particles. Macromolecules 28:1306–1308
Juhué D., Wang Y., Lang J., Leung O.-M., Goh M.C., Winnik M.A. (1995) Surfactant exudation in the presence of a coalescing aid in latex films studied by atomic force microscopy. J Polym Sci: Pt B: Pol Phys 33:1123–1133
Keddie J.L. (1997) Film formation of latex. Mat Sci Eng R: Reports, R21:101– 170.
Keddie J.L., Meredith P., Jones R.A.L., Donald A.M (1995) Kinetics of film formation in latex studied with ellipsometry and environmental-SEM Macro-molecules 28:2673–2682
Keddie J.L., Meredith P., Jones R.A.L., Donald A.M. (1996) Film formation of acrylic latices with varying concentrations of non-film-forming latex particles. Langmuir 12:3793–3801.
Keslarek A.J., Costa C.A.R., Galembeck F. (2001) Electric charge clustering and migration in latex films: A study by scanning electric potential microscopy. Langmuir 17:7886–7892
Keslarek A.J., Costa C.A.R., Galembeck F. (2002) Latex film morphology and electrical potential pattern dependence on serum components: A scanning probe microscopy study. J Coll Interf Sci 255:107–114
Keslarek A.J., Galembeck F. (2003) Effect of serum components on styrene/butyl acrylate latex film formation: An in situ examination by ultramicroscopy. J Appl Polym Sci 87:159–167
Kim H.-B., Winnik M.A. (1995) Factors affecting interdiffusion rates in films prepared from latex particles with a surface rich in acid groups and their salts. Macromolecules 28:2033–2041
Kim S.D., Klein A., Sperling L.H., Boczar E.M., Bauer B.J. (2000) SANS study of sulfonate end group effect on polystyrene self-diffusion. Macromolecules 33:8334–8343
Kitching S., Donald A.M. (1998) Beam damage of polypropylene in the environmental scanning electron microscope: an FTIR study. J Microsc Oxford 190:357–365
Knoll A., Magerle R., Krausch G. (2001) Tapping mode atomic force microscopy on polymers: Where is the true sample surface? Macromolecules 34:4159– 4165.
Kobayashi M., Rharbi Y., Winnik M.A. (2001) Effect of inorganic pigments on polymer interdiffusion in a low Tg latex film. Macromolecules 34:1855–1863
Kobayashi M., Rharbi Y., Brauge L., Cao L., Winnik M.A. (2002) Effect of silica as fillers on polymer interdiffusion in poly(butyl methacrylate) latex films. Macromolecules 35:7387–7399
Koenig J.L., Bobiak J.P. (2007) Raman and infrared imaging of dynamic polymer systems. Macromol. Mater. Engin. 292:801–806
König A.M., Weerakkody T.G., Keddie J.L., Johannsmann D. (2008) Heterogeneous drying of colloidal polymer films: Dependence on added salt. Langmuir 24:7580–7589
Kopp-Marsaudon S., Leclère Ph, Dubourg F., Lazzaroni R., Aimé J.P(2000) Quantitative measurement of the mechanical contribution to tapping-mode atomic force microscopy images of soft materials. Langmuir 16:8432–8437.
Lan K.H., Ostrowsky N., Sornette D. (1986) Brownian dynamics close to a wall studied by photon correlation spectroscopy from an evanescent wave. Phys Rev Lett 57:17–20
Leclère Ph, Dubourg F., Kopp-Marsaudon S., Brédas J.L., Lazzaroni R., Aimé J.P. (2002) Dynamic force microscopy analysis of block copolymers: beyond imaging the morphology. Appl. Surf. Sci. 188:524–533.
Lee W.P., Routh A.F. (2006) Time evolution of transition points in drying latex films. J Coatings Techn. Research 3:301–306
Lei C., Ouzineb K., Dupont O., Keddie J.L. (2007) Probing Particle Structure in Waterborne Pressure-Sensitive Adhesives with Atomic Force Microscopy. Journal of Colloid and Interface Science 307:56–63.
Lellinger D., Tadjbach S., Alig I. (2002) Determination of the elastic moduli of polymer films by a new ultrasonic reflection method. Macromol Symp 184:203–213
Lemlich R. (1978) Theory for limiting conductivity of polyhedral foam at low density. J Coll Interf Sci 64:107–110
Lin F., Meier D.J. (1995) A study of latex film formation by atomic force microscopy. 1. A comparison of wet and dry conditions. Langmuir 11:2726–2733
Ludwig I., Schabel W., Kind M., Castaing J.-C., Ferlin P. (2007) Drying and film formation of industrial waterborne latices. AIChE Journal 53:549–560
Ma Y., Davis H.T., Scriven L.E. (2005) Microstructure development in drying latex coatings. Prog Org Coat 52:46–62
Madsen A., Konovalov O., Robert A., Grubel G. (2001) Surface ordering in a concentrated suspension of colloidal particles investigated by x-ray scattering methods. Phys Rev E. 64:061406
Mallégol J., Dupont O., Keddie J.L. (2001) Obtaining and interpreting images of acrylic pressure-sensitive adhesives by tapping-mode atomic force microscopy. Langmuir 17:7022–7031.
Mallégol J., Barry A.M., Ciampi E., Glover P.M., McDonald P.J., Keddie J.L., Wallin M., Motiejauskaite A., Weissenborn P.K. (2002) Influence of drier combination on through-drying in waterborne alkyd emulsion coatings observed with magnetic resonance profiling. J Coatings Techn 74(933):113–124
Mallégol J., Gorce J.-P., Dupont O., Jeynes C., McDonald P.J., Keddie J.L. (2002) Origins and effects of a surfactant excess at the surface of waterborne acrylic pressure-sensitive adhesives. Langmuir 18:4478–4487.
Mallégol J., Dupont O., Keddie J.L. (2003) Morphology and elasticity of waterborne acrylic pressure-sensitive adhesives investigated with atomic force microscopy. J Adhes Sci Techn 17:243–259.
Mallégol J., Bennett G., Dupont O., McDonald P.J., Keddie J.L. (2006) Skin development during the film formation of waterborne acrylic pressure-sensitive adhesives containing tackifying resin. J Adhesion, 82:217–238
Markiewicz P., Goh M.C. (1995) Atomic-force microscope tip deconvolution using calibration arrays. Rev Sci Intrum 66:3186–3190
McDonald P.J. and Newling B. (1998) Stray field magnetic resonance imaging. Rep Prog Phys 61:1441–1493
Ming Y., Takamura K., Davis H.T., Scriven L.E. (1995) Microstructure evolution in latex coatings. Tappi J 78(11):151–159
Mitchell J., Blümler P., McDonald P.J. (2006) Spatially resolved nuclear magnetic resonance studies of planar samples. Progr Nucl Magn Reson Spectrosc 48:161–181
Mulvihill J., Toussaint A., De Wilde M. (1997) Onset, follow up and assessment of coalescence. Prog Org Coat 30:127–139
Narita T., Beauvais C., Hébraud P., Lequeux F. (2004) Dynamics of concentrated colloidal suspensions during drying – aging, rejuvenation and overaging. Eur Phys J E 14:287–292
Narita T., Hébraud P., Lequeux F. (2005) Effects of the rate of evaporation and film thickness on nonuniform drying of film-forming concentrated colloidal suspensions. Eur Phys J E 17:69–75
Newling B., Glover P.M., Keddie J.L., Lane D.M., McDonald P.J. (1997) Concentration profiles in creaming oil-in-water emulsion layers determined with stray field magnetic resonance imaging. Langmuir 13:3621–3626
Nonnenmacher M., O'Boyle M.P., Wickramasinghe H.K. (1991) Kelvin probe force microscopy. App Phys Lett 58:2921–2923
Odin C., Aimé J.P., El Kaakour Z., Bouhacina T. (1994) Tip finite-size effects on atomic-force microscopy in the contact mode — Simple geometrical considerations for rapid estimation of apex radius and tip angle base on the study of polystyrene latex balls. Surf Sci 317:321–340
Oh J.K., Yang J., Tomba J.P., Rademacher J., Farwaha R., Winnik M.A. (2003) Molar mass effect on the rate of polymer diffusion in poly(vinyl acetate-co-butyl acrylate) latex films. Macromolecules 36:8836–8845
Oh J.K., Tomba P., Ye X., Eley R., Rademacher J., Farwaha R., Winnik M.A. (2003b) Film formation and polymer diffusion in poly(vinyl acetate-co-butyl acrylate). Temperature dependence. Macromolecules 36:5804–5814.
Odrobina E., Winnik M.A. (2001) Influence of entanglements on the time dependence of mixing in nonradiative energy transfer studies of polymer diffusion in latex films. Macromolecules 34:6029–6038
Odrobina E., Feng J.R., Pham H.H., Winnik M.A. (2001) Effect of soft filler particles on polymer diffusion in poly(butyl methacrylate) latex films. Macro-molecules 34:6039–6051
Papagiannopoulos A., Fernyhough C.M., Waigh T.A. (2005) The microrheology of polystyrene sulfonate combs in aqueous solution. J Chem Phys 123:214904
Patel A.A., Feng J., Winnik M.A., Vansco G.J., Dittman McBain C.B. (1996) Characterization of latex blend films by atomic force microscopy. Polymer 37:5577–5582
Peckan O., Winnik M.A., Croucher M.D. (1988) Direct energy-transfer studies on doped and labelled polymer latex particles. Phys Rev Lett 61:641–644.
Perera D.Y., Van den Eynde D. (1981) Considerations on a cantilever (beam) method for measuring the internal stress in organic coatings. J Coatings Tech 53 (677):39–44
Petersen C., Heldmann C., Johannsmann D. (1999) Internal stresses during film formation of polymer latices. Langmuir 15:7745–7751
Pohl D.W., Denk W., Lanz M (1984) Optical stethoscopy: Image recording with resolution λ/20, Appl Phys Lett 44:651–653
Protzman T.F., Brown G.L. (1960) An apparatus for the determination of the minimum film temperature of polymer emulsions. J Appl Polym Sci 4:81–85
Raghavan D., VanLandingham M., Gu X., Nguyen T. (2000) Characterization of heterogeneous regions in polymer systems using tapping mode and force mode atomic force microscopy. Langmuir 16:9448–9459.
Rottstegge J., Landfester K., Wilhelm M., Spiess H.W., Heldmann C. (2000) Different types of water in the film formation process of latex dispersions as detected by solid-state nuclear magnetic resonance spectroscopy. Colloid Po-lym. Sci. 278:236–244.
Rottstegge J., Traub B., Wilhelm M., Landfester K., Heldmann C., Spiess H.W. (2003) Investigations on the film-formation process of latex dispersions by solid-state NMR spectroscopy. Macromol. Chem. Phys. 204:787–802
Roulstone B.J., Wilkinson M.C., Hearn J., Wilson A.J. (1991) Studies of polymer latex films: 1. A study of latex film morphology. Polym Intern 24:87–94
Salamanca J.M., Faux D.A., Glover P.M., Keddie J.L., McDonald P.J., Routh A.F. (2001) Lateral drying in thick films of waterborne colloidal particles. Langmuir 17:3202–3207
Santos J.P., Corpart P., Wong K., Galembeck F. (2004) Heterogeneity in styrene-butadiene latex films. Langmuir 20:10576–10582
Schmidt M., Krieger S., Johannsmann D. (1997) Film formation of latex dispersions observed with evanescent dynamic light scattering. Progr Coll Polym Sci 104:191–194
Schrof W., Beck E., Kniger R., Reich W., Schwalm R. (1999) Depth profiling of U.V. cured coatings containing photostabilisers by confocal Raman microscopy. Prog Org Coat 35:197–204
Schallamach A. (1952) Abrasion of rubber by a needle. J Polym Sci 9:385–404
Schwarz U.S., Balaban N.O., Riveline D., Bershadsky A., Geiger B., Safran S.A. (2002) Calculation of forces at focal adhesions from elastic substrate data: The effect of localised force and the need for regularisation. Biophys J 83:1380– 1394.
Scott W.W., Bhushan B. (2003) Use of phase imaging in atomic force microscopy for measurement of viscoelastic contrast in polymer nanocomposites and molecularly thick lubricant films. Ultramicroscopy 97:151–169
Sheehan J.G., Takamura K., Davis H.T., Scriven S.E. (1993) Microstucture development in particulate coatings examined with high-resolution cryogenic scanning electron microscopy. Tappi J 76(12):93–101
Sommer F., Duc T.M., Pirri R., Meunier G., Quet C. (1995) Surface morphology of poly(butyl acrylate)/poly(methyl methacrylate) core shell latex by atomic force microscopy. Langmuir 11:440–448
Tamai T., Pinenq P., Winnik M.A. (1999) Effect of crosslinking on polymer diffusion in poly(butyl methacrylate-co-butyl acrylate) latex films. Macromole-cules 32:6102–6110
Tamayo J., Garcia R. (1997) Effects of elastic and inelastic interactions on phase contrast images in tapping-mode scanning force microscopy. Appl. Phys. Lett. 71:2394–2396.
Teixeira-Neto E., Kaupp G., Galembeck F. (2003) Latex particle heterogeneity and clustering in films. J Phys Chem B. 107:14255–14260
Teixeira-Neto E., Kaupp G., Galembeck F. (2004) Spatial distribution of serum solutes on dry latex sub-monolayers determined by SEPM, SNOM and SC microscopy. Coll Surf A Physicochem Eng Asp 243:79–87
Terris B.D., Stern J.E., Rugar D., Mamin H.J. (1990) Localised charge force microscopy. J Vac Sci Technol A 8:374–377
Tirumkudulu M.S., Russel W.B. (2004) Role of capillary stresses in film formation. Langmuir 20:2947–2961
Tirumkudulu M.S., Russel W.B. (2005) Cracking in drying latex films. Langmuir, 21:4938–4948
Turshatov A., Adams J. (2007) A new monomeric FRET-acceptor for polymer interdiffusion experiments on polymer dispersions. Polymer 48:7444–7448
Turshatov A., Adams J., Johannsmann D. (2008) Interparticle contact in drying polymer dispersions probed by time resolved fluorescence. Macromolecules 41:5365–5372
Tzitzinou A., Jenneson P.M., Clough A.S., Keddie J.L., Lu J.R., Zhdan P., Treacher K.E., Satguru R. (1999) Surfactant concentration and morphology at the surfaces of acrylic latex films. Prog Org Coatings, 35:89–99
Tzitzinou A., Keddie J.L., Geurts J.M., Peters A.C.I.A., Satguru R. (2000) Film formation of latex blends with bimodal particle size distributions: Considera- tion of particle deformability and continuity of the dispersed phase. Macro-molecules 33:2695–2708
Urban M.W. (1997) Surfactants in latex films; interactions with latex components and quantitative analysis using ATR and step-scan PAS FT-IR spectroscopy. Prog Org Coatings 32:215–229
van Tent A., te Nijenhuis K. (1992) Turbidity study of the process of film formation of thin films of aqueous acrylic dispersions. Prog Org Coat 20:459–470
van Tent A., te Nijenhuis K. (1992b) Turbidity study of the process of film formation of polymer particles in drying thin films of acrylic latices. J Coll Interf Sci 150:97–114
van Tent A., te Nijenhuis K. (2000) The film formation of polymer particles in drying thin films of aqueous acrylic latices - II. Coalescence, studied with transmission spectrophotometry. J Coll Interf Sci 232:350–363
Veniaminov A., Jahr T., Sillescu H., Bartsch E. (2002) Length scale dependent probe diffusion in drying acrylate latex films. Macromolecules 35:808–819
Veniaminov A., Jahr T., Sillescu H., Bartsch E. (2003) Probing poly(n-butyl-methacrylate) latex film via diffusion of hydrophilic and hydrophobic dye molecules. Macromolecules 36:4944–4953
ViasnoffV., Lequeux F., Pine D.J. (2002) Multispeckle diffusing-wave spectros-copy: a tool to study slow relaxation and time-dependent dynamics. Rev Sci Instrum 73:2336–2344
von der Ehe K., Johannsmann D. (2007) Maps of the stress distributions in drying latex films. Rev Sci Instrum 78:113904 (5 pages)
Waigh T.A. (2005) Microrheology of complex fluids. Rep Prog Phys 68:685–742
Wallin M., Glover P.M., Hellgren A.-C., Keddie J.L., McDonald P.J. (2000) Depth profiles of polymer mobility during the film formation of a latex dispersion undergoing photo-initiated crosslinking. Macromolecules 33:8443–8452.
Wang Y., Juhué D., Winnik M.A., Leung O.M., Goh M.C. (1992) Atomic force microscopy study of latex film formation. Langmuir 8:760–762
Wang Y., Winnik M.A. (1993) Polymer diffusion across interfaces in latex films. J Phys Chem 97:2507–2515
Wang Y., Song R., Li Y.S., Shen J.S. (2003) Understanding tapping-mode atomic force microscopy data on the surface of soft block copolymers. Surf. Sci. 530:136–148
Wang Y.C., Winnik M.A. (1990) Latex film formation. 3. Effect of coalescing aid on polymer diffusion in latex films. Macromolecules 23:4731–4732
Weil J.A., Bolton J.E., Wertz J.E. (1994) Electron paramagnetic resonance. Wiley, New York.
Winnik M.A., Feng J (1996) Latex blends: An approach to zero VOC coatings, Journal of Coatings Technology 68(852):39–50
Winnik M.A., Wang Y., Haley F. (1992) Latex film formation at the molecular level: The effect of coalescing aids on polymer diffusion. J Coatings Tech 64(811):51–61
Yekta A., Winnik M.A., Farinha J.P.S., Martinho J.M.G. (1997) Dipole-dipole electronic energy transfer. Fluorescence decay functions for arbitrary distribu-tions of donors and acceptors. II. Systems with spherical symmetry. J Phys Chem A 101:1787–1792
Yu M.-F., Kowalewski T., RuoffR.S. (2000) Investigation of the radial deform-ability of individual carbon nanotubes under controlled indentation force. Phys Rev Lett 85:1456–1459
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Keddie, J.L., Routh, A.F. (2010). Established and Emerging Techniques of Studying Latex Film Formation. In: Fundamentals of Latex Film Formation. Springer Laboratory. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2845-7_2
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