Skip to main content
SpringerLink
Log in

NMR in magnetic single molecule magnets

  • Chapter
NMR-MRI, μSR and Mössbauer Spectroscopies in Molecular Magnets

Abstract

In the last years there has been a great interest in magnetic systems formed by a cluster of transition metal ions covalently bonded via superexchange bridges, embedded in a large organic molecule. Following the synthesis and the structural and magnetic characterization of these magnetic molecules by chemists, the physicists realized the great interest of these systems as a practical realization of zero-dimensional model magnetic systems. In fact the magnetic molecules can be synthesized in crystalline form whereby each molecule is magnetically independent since the intramolecular exchange interaction among the transition metal ions is dominant over the weak intermolecular, usually dipolar, magnetic interaction.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

Molecular nanomagnets

  1. D. Gatteschi and R. Sessoli, Magnetism: Molecules to Materials III, ed by J. S. Miller and M. Drillon (Wiley-VHC, Verlag GmbH, Weinheim 2002)

    Google Scholar 

  2. D. Gatteschi et al: Science 265, 1055 (1994)

    Article  ADS  Google Scholar 

  3. A. Muller et al: Chem. Phys. Chem. 2, 517 (2001)

    Google Scholar 

  4. K. Wieghardt, K. Pohl, H. Jibril and G. Huttner: Angew. Chem. Int. Ed. Engl. 23, 77 (1984)

    Article  Google Scholar 

  5. T. Lis: Acta Cryst. B36, 2042 (1980)

    Google Scholar 

  6. D. Gatteschi, A. Caneschi, R. Sessoli and A. Cornia: Chem. Soc. Rev. 2, 101 (1996); K.L. Taft, C.D. Delfs, G.C, Papaefthymoiu, S. Foner, D. Gatteschi and S.J. Lippard: J. Am. Chem. Soc. 116, 823 (1994)

    Article  Google Scholar 

  7. G. Cristou, D. Gatteschi, D.N. Hendrickson, and R. Sessoli: MRS Bull. 25, 66 (2000)

    Google Scholar 

  8. O. Kahn, Molecular Magnetism (Wiley-VCH, Weinheim, Germany 1993)

    Google Scholar 

Review paper on NMR in molecular nanomagnets

  1. F. Borsa, A. Lascialfari and Y. Furukawa: NMR in magnetic molecular rings and clusters. In: New developments in Magnetic Resonance, (Springer & Verlag 2006 and cond-mat/0404378,0404379)

    Google Scholar 

NMR and relaxation in magnetic systems

  1. A. Abragam: The principles of Nuclear Magnetism (Clarendon Press, Oxford 1961)

    Google Scholar 

  2. T. Moriya: Prog. Theor. Phys. 16, 23 (1956), ibidem 28, 371 (1962)

    Article  ADS  Google Scholar 

  3. F. Borsa and A. Rigamonti. In: Magnetic Resonance of Phase Transitions, (Academic Press 1979)

    Google Scholar 

NMR relaxation in one dimensional paramagnets

  1. F. Borsa and M. Mali: Phys. Rev. B 9, 2215 (1974)

    Article  ADS  Google Scholar 

  2. J. P. Boucher, M. Ahmed Bakheid, M. Nechschtein, G. Bonera, M. Villa, and F. Borsa: Phys. Rev. 13, 4098 (1976)

    Article  ADS  Google Scholar 

Theory of spin dynamics in molecular nanomagmets at high temperature

  1. A. Lascialfari, D. Gatteschi, A. Cornia, U. Balucani, M.G. Pini and A. Rettori: Phys. Rev. B 57, 1115 (1998)

    Article  ADS  Google Scholar 

  2. J. H. Luscombe and M. Luban: J. Phys. Condens. Matter 9, 6913 (1997)

    Article  ADS  Google Scholar 

  3. J. Tang, S. N. Dikshit, and J. R. Norris: J. Chem. Phys. 103, 2873 (1995)

    Article  ADS  Google Scholar 

  4. J.H. Luscombe, M. Luban and F. Borsa: J. Chem. Phys. 108, 7266 (1998)

    Article  ADS  Google Scholar 

NMR and relaxation in molecular nanomagnets at high temperature

  1. A. Lascialfari, Z.H. Jang, F. Borsa, D. Gatteschi and A. Cornia: J. Appl. Phys. 83, 6946 (1998)

    Article  ADS  Google Scholar 

  2. A. Lascialfari, D. Gatteschi, F. Borsa and A. Cornia: Phys. Rev. B 55, 14341 (1997)

    Article  ADS  Google Scholar 

  3. D. Procissi, B.J. Suh, J.K. Jung, P. Kogerler, R. Vincent and F. Borsa: J. of Applied Physics 93, 7810 (2003)

    Article  ADS  Google Scholar 

  4. A. Lascialfari, Z.H. Jang, F. Borsa, A. Cornia, D. Rovai, A. Caneschi and P. Carretta: Phys.Rev.B 61, 6839 (2000)

    Article  ADS  Google Scholar 

Static magnetic properties in molecular nanomagnets by NMR

  1. Y. Furukawa, K. Kumagai, A. Lascialfari, S. Aldrovandi, F. Borsa, R. Sessoli and D. Gatteschi: Phys. Rev. B 64, 094439 (2001)

    Article  ADS  Google Scholar 

  2. T. Goto, T. Koshiba, T. Kubo, and K. Awaga, Phys. Rev. B 67, 104408 (2003)

    Article  ADS  Google Scholar 

  3. T. Goto, T. Kubo, T. Koshiba, Y. Fuji, A. Oyamada, J. Arai, T. Takeda and K. Awaga: Physica B 284–288, 1277 (2000)

    Google Scholar 

  4. Y. Furukawa, K. Watanabe, K. Kumagai, F. Borsa and D. Gatteschi: Phys. Rev. B 64, 104401 (2001)

    Article  ADS  Google Scholar 

  5. Y. Furukawa, S. Kawakami, K. Kumagai, S-H. Baek and F. Borsa: Phys. Rev. B 68, 180405(R) (2003)

    Article  ADS  Google Scholar 

  6. Y. Furukawa, K. Watanabe, K. Kumagai, F. Borsa and D. Gatteschi: Physica B 329–333, 1146 (2003)

    Article  Google Scholar 

  7. S.H. Baek, S. Kawakami, Y. Furukawa, B.J. Suh, F. Borsa, K. Kumagai, and A. Cornia: Journal of Magnetism and Magnetic Materials 272–276, 771 (2004)

    Article  Google Scholar 

  8. E. Micotti, Y. Furukawa, K. Kumagai, S. Caretta, A. Lascialfari, F. Borsa, G.A. Timco and R.E.P. Winpenny: Phys. Rev. Lett. 97, 267204 (2006)

    Article  ADS  Google Scholar 

  9. T. Kubo, T. Goto, T. Koshiba, K. Takeda and K. Agawa: Phys. Rev.B 65, 224425 (2002)

    Article  ADS  Google Scholar 

NMR Relaxation in molecular nanomagnets at intermediate temperatures

  1. A. Lascialfari, D. Gatteschi, F. Borsa and A. Cornia: Phys. Rev. B 55, 14341 (1997)

    Article  ADS  Google Scholar 

  2. J.K. Jung, D. Procissi, R. Vincent, B.J. Suh, F. Borsa, C. Schroder, M. Luban, P. Kogerler and A. Muller: J. of Applied Physics 91, 7388 (2002)

    Article  ADS  Google Scholar 

  3. D. Procissi, B.J. Suh, J.K. Jung, P. Kogerler, R. Vincent and F. Borsa: J. of Applied Physics 93, 7810 (2003)

    Article  ADS  Google Scholar 

  4. B.J. Suh, D. Procissi, K.J. Jung, S. Budko, W.S. Jeon, Y.J. Kim and D.Y. Jung: J. of Applied Physics 93, 7098 (2003)

    Article  ADS  Google Scholar 

  5. S.H. Baek, M. Luban, A. Lascialfari, E. Micotti, Y. Furukawa, F. Borsa, J. van Slageren and A. Cornia: Phys. Rev. B 70, 134434 (2004)

    Article  ADS  Google Scholar 

  6. M. Belesi, A. Lascialfari, D. Procissi, Z.H. Jang and F. Borsa: Phys.Rev.B 72, 014440 (2005)

    Article  ADS  Google Scholar 

  7. P. Santini, S. Carretta, E. Liviotti, G. Amoretti, P. Carretta, M. Filibian, A. Lascialfari and E. Micotti: Phys. Rev. Lett. 94, 077203 (2005)

    Article  ADS  Google Scholar 

  8. M. Corti, M. Filibian, P. Carretta, L. Zhao and L.K. Thompson: Phys. Rev B 72, 064402 (2005)

    Article  ADS  Google Scholar 

NMR at level crossing in AF rings

  1. M.H. Julien, Z.H. Jang, A. Lascialfari, F. Borsa, H. Horvatic, A. Caneschi and D. Gatteschi: Phys. Rev. Lett. 83, 227 (1999)

    Article  ADS  Google Scholar 

  2. M. Affronte, A. Cornia, A. Lascialfari, F. Borsa, D. Gatteschi, J. Hinderer, M. Horvatic, A.G.M. Jansen, and M.-H. Julien: Phys. Rev. Lett. 88, 167201 (2002)

    Article  ADS  Google Scholar 

  3. E. Micotti, A. Lascialfari, F. Borsa, M.-H. Julien, C. Berthier, M. Horvatic, J. Van Slageren and D. Gatteschi: Phys. Rev. B 72, 020405(R) (2005)

    Article  ADS  Google Scholar 

NMR and the energy gap of AFM rings in the magnetic ground state

  1. A. Lascialfari, F. Tabak, G. L. Abbati, F. Borsa, M. Corti and D. Gatteschi: Journal of Applied Physics 85, 4539 (1999)

    Article  ADS  Google Scholar 

  2. A. Lascialfari, Z.H. Jang, F. Borsa, A. Cornia, D. Rovai, A. Caneschi and P. Carretta: Phys.Rev.B 61, 6839 (2000)

    Article  ADS  Google Scholar 

  3. D. Procissi, A. Shastri, I. Rousochadsakis, M. Al Rifai, P. Kogerler, M. Luban, B.J. Suh and F. Borsa: Phys. Rev.B 69, 094436 (2004)

    Article  ADS  Google Scholar 

  4. S. Maegawa and M. Ueda: Physica B 329, 1144 (2003); T. Yamasaki, M. Ueda and S. Maegawa: Physica B 329, 1187 (2003)

    Article  ADS  Google Scholar 

NSLR due to thermal fluctuations

  1. A. Lascialfari, Z.H. Jang, F. Borsa, P. Carretta and D. Gatteschi: Phys. Rev. Lett. 81, 3773 (1998)

    Article  ADS  Google Scholar 

  2. S. Yamamoto and T. Nakanishi: Phys. Rev. Lett. 89, 157603 (2002); H. Hori and S. Yamamoto: Phys.Rev. B 68, 054409 (2003)

    Article  ADS  Google Scholar 

  3. Goto, T. Koshiba, T. Kubo, and K. Awaga: Phys. Rev. B 67, 104408 (2003)

    Article  ADS  Google Scholar 

  4. Y. Furukawa, K. Watanabe, K. Kumagai, F. Borsa and D. Gatteschi: Phys.Rev.B 64, 104401 (2001)

    Article  ADS  Google Scholar 

  5. Y. Furukawa, K. Kumagai, A. Lascialfari, S. Aldrovandi, F. Borsa, R. Sessoli and D. Gatteschi: Phys.Rev.B 64, 094439 (2001)

    Article  ADS  Google Scholar 

Theory of spin-phonon coupling in molecular nanomagnets

  1. M.N. Leuenberger and D. Loss: Phys. Rev. B 61, 1286 (2000)

    Article  ADS  Google Scholar 

  2. J. Villain, F. Hartmann-Boutron, R. Sessoli, and A. Rettori: Europhys. Lett. 27, 537 (1994); F. Hartmann-Boutron, P. Politi, and J. Villain: Int. J. Mod. Phys. 10, 2577 (1996)

    Article  Google Scholar 

Theory and experiments on QTM in molecular nanomagnets

  1. I. Tupitsyn and B. Barbara, Magnetism: Molecules to Materials III, ed by J. S. Miller and M. Drillon (Wiley-VHC, Verlag GmbH, Weinheim 2002)

    Google Scholar 

  2. M. Luis, F.L. Mettes and L. Jos de Jongh, Magnetism: Molecules to Materials III, ed by J. S. Miller and M. Drillon (Wiley-VHC, Verlag GmbH, Weinheim 2002)

    Google Scholar 

NMR detection of QTM

  1. M. Ueda, S. Maegawa and S. Kitagawa: Phys. Rev. B 66, 073309 (2002)

    Article  ADS  Google Scholar 

  2. A. Morello, O.N. Bakharev, H.B. Brom and L.J. de Jongh: Polyhedron 22, 1745 (2003)

    Article  Google Scholar 

  3. A. Morello, O.N. Bakharev, H.B. Brom, R. Sessoli and L.J. de Jongh: Phys. Rev. Lett. 93, 197202 (2004)

    Article  ADS  Google Scholar 

  4. Y. Furukawa, K. Aizawa, K. Kumagai, R. Ullu, A. Lascialfari and F. Borsa: J. Appl. Phys. 93, 7813 (2003) see also Phys. Rev B 69, 014405 (2004)

    Article  ADS  Google Scholar 

  5. S.H. Baek, F. Borsa, Y. Furukawa, Y. Hatanaka, S. Kawakami, K. Kumagai, B.J. Suh and A. Cornia: Phys.Rev. B 71, 214436 (2005)

    Article  ADS  Google Scholar 

  6. Y. Furukawa, K. Watanabe, K. Kumagai, Z.H. Jang, A. Lascialfari, F. Borsa and D. Gatteschi: Phys.Rev B 62, 14246 (2000).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Fisica “A.Volta”, University of Pavia, Via Bassi, 6, 27100, Pavia, Italy

    Ferdinando Borsa

Authors
  1. Ferdinando Borsa
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 2007 Springer-Verlag Italia

About this chapter

Cite this chapter

Borsa, F. (2007). NMR in magnetic single molecule magnets. In: NMR-MRI, μSR and Mössbauer Spectroscopies in Molecular Magnets. Springer, Milano. https://doi.org/10.1007/978-88-470-0532-7_2

Download citation

Publish with us

Policies and ethics

Search

Navigation