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Environmental Life Cycle Analysis of Nonconventional Thin-Film Photovoltaics: The Case of Dye-Sensitized Solar Devices

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Abstract

In the context of constantly growing global energy demand, the interest of the scientific community is progressively moving toward renewable energy sources and sustainable growth. The search for alternative energy sources and the technologies necessary for their exploitation, able to combine efficiency, ease of use, and reduced environmental impact is therefore an important challenge for our civilization. Photovoltaics (PV) is one of the technologies available to produce electricity from solar energy and recent research turned itself to the development of devices based on alternative materials, like the dye-sensitized solar cells (DSCs) that have attracted much interest because of their potentially low cost of production. Thanks to the employment of readily available materials, they actually present drastically lower economic and environmental costs compared with traditional silicon-based cells even though they are not efficient enough yet to be industrially competitive. In this study, we present the results of life cycle assessment (LCA) for the production process of DSCs. The environmental performance of a virtual roof-top grid-connected DSC system in comparison with several advanced thin-film PV technologies for energy production is also described. This analysis will be pivotal in understanding the environmental dynamics, the benefits and drawbacks associated with the production of DSCs in comparison with other thin-film PV technologies.

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References

  • Alsema EA, Nieuwlaar E (2000) Energy viability of photovoltaic systems. Energy Policy 28(14):999–1010

    Article  Google Scholar 

  • Bai Y, Cao Y, Zhang J, Wang M, Li R, Wang P, Nazeeruddin SM, Grätzel M (2008) High-performance dye-sensitized solar cells based on solvent-free electrolytes produced from eutectic melts. Nat Mater 7(8):626–630

    Article  Google Scholar 

  • Bravi M, Parisi ML, Tiezzi E, Basosi R (2010) Life cycle assessment of advanced technologies for photovoltaic panels production. Int J Heat Technol 28(2):133–139

    Google Scholar 

  • Bravi M, Parisi ML, Tiezzi E, Basosi R (2011) Life cycle assessment of a micromorph photovoltaic system. Energy 36(7):4297–4306

    Article  Google Scholar 

  • De Wild-Scholten MJ, Veltkamp AC (2007) Environmental life cycle analysis of dye sensitized solar devices; Status and Outlook. Paper presented at the 22nd European Photovoltaic Solar Energy Conference, Milan, Italy, 3–7 September 2007

    Google Scholar 

  • Dennler G, Bracec C (2008) Socio economics impacts of low cost PV Technologies. In: Brabec C, Scherf U, Dyakonov V (eds) Organic photovoltaics: materials, device physics and manufacturing technologies. Wiley-VCH, Germany, pp 531–567

    Chapter  Google Scholar 

  • DyeSol Australia. http://www.dyesol.com. Accessed 16 Oct 2011

  • Frischknecht R, Jungbluth N, Althaus HJ, Bauer C, Doka G, Dones R (2007a) Implementation of life cycle impact assessment methods. Swiss Centre for Life Cycle Inventories. Technical Report Ecoinvent No. 3, Dübendorf, Switzerland

    Google Scholar 

  • Frischknecht R, Jungbluth N, Althaus HJ, Doka G, Heck T, Hellweg S et al (2007b) Ecoinvent v2.0: overview and methodology. Swiss Centre for Life Cycle Inventories. Technical Report Ecoinvent No. 1, Dübendorf, Switzerland

    Google Scholar 

  • Fthenakis VM, Alsema, EA (2006) Photovoltaics energy payback times, greenhouse gas emissions and external costs: 2004–early 2005 status. Prog Photovolt 14(3):275–280

    Article  Google Scholar 

  • Fthenakis VM, Kim HC, Alsema EA (2008) Emissions from photovoltaic life cycles. Environ Sci Technol 42(6):2168–2174

    Article  Google Scholar 

  • G24 Innovations. Wales (UK). http://www.g24i.com. Accessed 15 Oct 2011

  • Grätzel M (2001) Photoelectrochemical cells. Nature 414:338–344

    Article  Google Scholar 

  • Greijer H, Karlsonb L, Lindquista SE, Hagfeldt A (2001) Environmental aspects of electricity generation from a nanocrystalline dye sensitized solar cell system. Renew Energy 23(1):27–39

    Article  Google Scholar 

  • Guinèe JB, Gorrée M, Heijungs R, Huppes G, Kleijn R, De Koning A, Van Oers L, Wegener Sleeswijk A, Weidema BP (2001) Life cycle assessment; an operational guide to the ISO standards; characterisation and normalisation factors. Centre of Environmental Science (CML), Den Haag and Leiden, The Netherlands

    Google Scholar 

  • Hagfeldt A, Boschloo G, Sun L, Kloo L, Pettersson H (2010) Dye-sensitized solar cell. Chem Rev 110:6595–6664

    Article  Google Scholar 

  • IPCC (2007) GWP 100a v 1.02, Climate Change 2007, IPCC Fourth Assessment Report, The Physical Science Basis

    Google Scholar 

  • ISO (International Organization for Standardization) 14040 standard (2006) Environmental management-Life cycle assessment-Principles and framework

    Google Scholar 

  • ISO (International Organization for Standardization) 14044 standard (2006) Environmental management–Life cycle assessment–Requirements and Guidelines

    Google Scholar 

  • Jäger-Waldau A (2008) PV Status Report 2008, Research, Solar Cell Production and Market Implementation of Photovoltaics. Ispra, Italy: Institute for Energy, Renewable Energies Unit, DG Joint Research Centre; EUR–Scientific and Technical Research Series, ISSN 1018-5593

    Google Scholar 

  • Jungbluth N (2005) Life cycle assessment of crystalline photovoltaics in the Swiss ecoinvent database. Prog Photovolt 13(5):429–446

    Article  Google Scholar 

  • Jungbluth N, Dones R, Frischknecht R (2008) Life cycle assessment of photovoltaics: update of ecoinvent data v2.0. ESU-services Ltd. Uster

    Google Scholar 

  • Kato K, Hibino T, Komoto K, Ihara S, Yamamoto S, Fujihara H (2001) A life-cycle analysis on thin-film CdS/CdTe PV modules. Sol Energy Mater Sol Cells 67:279–287

    Article  Google Scholar 

  • Keoleian GA, Lewis GM (1997) Application of life cycle energy analysis to photovoltaic module design. Prog Photovolt 5:287–300

    Article  Google Scholar 

  • Konarka Technologies Inc. USA. http://www.konarka.com. Accessed 14 Oct 2011

  • National Renewable Energy Laboratory 2008 Solar Technologies Market Report, U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy; January 2010

    Google Scholar 

  • O’Regan B, Grätzel M (1991) A low-cost, high efficiency solar cell based on dye-sensitized colloidal TiO films. Nature 353:737–740

    Article  Google Scholar 

  • Parisi ML, Sinicropi A, Basosi R (2011) Life cycle assessment of Grätzel-type cell production for non conventional photovoltaics from novel organic dyes. Int J Heat Tecchnol 29(2):161–169

    Google Scholar 

  • Parisi ML, Sinicropi A, Basosi R (2012) Life cycle assessment of thin film non conventional photovoltaics the case of dye sensitized solar cells. Paper presented at the 25th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems; Perugia, Italy, 26–29 June 2012

    Google Scholar 

  • Pearsal N (2011) Science, technology and applications group of the EU Photovoltaic Technology Platform, A Strategic Research Agenda for Photovoltaic Solar Energy Technology, Photovoltaic Technology Platform Edition 2. Newcastle upon Tyne, UK: School of CEIS, Northumbria Photovoltaics Applications Centre. ISBN 978-92-79-20172-1

    Google Scholar 

  • PV-TRAC, Photovoltaic Technology Research Advisory Council, EU PV Technology Platform (2005) A vision for photovoltaic technology. European Commission, Brussels

    Google Scholar 

  • Prè Consultants (2008) Sima Pro 7.1. Amersoort, The Netherlands. http://www.pre.nl

  • Raugei M, Bargigli S, Ulgiati S (2007) Life cycle assessment and energy pay-back time of advanced photovoltaic modules: CdTe and CIS compared to poly-Si. Energy 32(8):1310–1318

    Article  Google Scholar 

  • Solaronix SA (2011) Switzerland. http://www.solaronix.ch. Accessed 14 Oct 2011

  • Van Sark W, Alsema EA, Junginger HM, de Moor HH, Schaeffer GJ (2008) Accuracy of progress ratios determined from experience curves: the case of crystalline silicon photovoltaic module technology development. Prog Photovolt 16(5):441–453

    Article  Google Scholar 

  • Yella A, Lee H, Tsao H, Yi C, Chandiran A, Nazzeruddin SM, Diau E, Yeh C, Zakeeruddin S, Grätzel M (2011) Porphyrin-sensitized solar cells with cobalt (II/III)–based redox electrolyte exceed 12 % efficiency. Science 334:629–634

    Article  Google Scholar 

Download references

Acknowledgments

The authors thank Project Fotosensorg (POR FSE 2007–2013) for supporting us financially in Design and synthesis of new organic sensitizers for nonconventional solar cells production. Useful discussions with Prof. M. Taddei (Unisi) and Dr. A. Mordini, G. Reginato and L. Zani (ICCOM-CNR) are acknowledged.

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Correspondence to Riccardo Basosi .

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Parisi, M., Basosi, R. (2015). Environmental Life Cycle Analysis of Nonconventional Thin-Film Photovoltaics: The Case of Dye-Sensitized Solar Devices. In: Reddy, B., Ulgiati, S. (eds) Energy Security and Development. Springer, New Delhi. https://doi.org/10.1007/978-81-322-2065-7_12

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  • DOI: https://doi.org/10.1007/978-81-322-2065-7_12

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  • Publisher Name: Springer, New Delhi

  • Print ISBN: 978-81-322-2064-0

  • Online ISBN: 978-81-322-2065-7

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