Abstract
All Solid State Lithium Polymer Batteries (LPBs) have been fabricated by using solid polymer blend electrolyte (SPE) composed of biodegradable polymers, polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP) blend with lithium perchlorate LiClO4 at a different weight percent ratio. The effect of addition of lithium salt with blend polymers is investigated by XRD, FTIR, Electrochemical impedance (EIS), and Cyclic Voltammetry measurements as well as the charge–discharge performance. The room temperature electrolytic conductivity of the order of 10−4 S cm−1 has been achieved in the composition of 70PVA: 30PVP: 25 Wt % LiClO4. The conductivity–temperature plot is found to follow the Arrhenius nature, which showed the decrease in activation energy with the increasing salt concentration. The electrolyte with the highest ion conductivity has been used in the fabrication of Lithium/Polymer battery with the configuration of Li (metal foil)/SPE/LiCoO2. The galvanostatic charge/discharge performance is carried out from 3 to 4.6 V versus Li+/Li. The electrochemical stability of the polymer blend electrolyte membrane has been found to be stable up to ~4.6 V versus Li/Li+.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Gray FM (1991) Solid polymer electrolytes fundamentals and technological applications. VCH, New York
Maccallum JR, Vincent CA (eds) (1987 and 1989) Polymer electrolyte reviews, vol 1 and 2. Elsevier, London
Kelly IE, Owen JR, Steele BCH (1985) Poly (ethylene oxide) electrolytes for operation at near room temperature. J Power Sources 14:13
Koksbang R, Oslen II, Shackle D (1994) Review of hybrid polymer electrolytes and rechargeable lithium batteries. Solid State Ionics, 69:320
Michael MS, Prabaharan SRS (2004) Rechargeable lithium battery employing a new ambient temperature hybrid polymer electrolyte based on PVK + PVdF-HFP (copolymer). J Power Sources 136:408–415
De Queiroz AAA, Soares DTAW, Tizesniak P, Abraham GA (2001) Resistive-type humidity sensors based on PVP-Co and PVP-I2 complexes. J Polym Sci B: Polym Phys 39:459
Feng H, Feng Z, Shen L (1993) A high resolution solid-state n.m.r and d.s.c study of miscibility and crystallization behavior of Poly (Vinyl alcohol)/Poly (N-Vinyl-2-pyrrolidone) blends. Polym 34:2516
Zhang X, Takegoshi K, Hikichi K (1992) High resolution solid-state 13C nuclear magnetic resonance study on Poly (Vinyl alcohol)/Poly (Vinyl-pyrrolidone) blends. Polym 33:712
Awadhia A, Agrawal SL (2007) Structural, thermal and electrical characterizations of PVA:DMSO:NH4SCN gel electrolytes. Solid State Ionics 178:951–958
Sun HY, Takeda Y, Imanishi N, Yamamoto O, Sohn HJ (2000) Ferroelectric materials as a ceramic filler in solid composite polyethylene oxide base electrolytes. J Electrochem Soc 147:2462
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2012 Springer India
About this paper
Cite this paper
Rajeswari, N., Selvasekarapandian, S., Kawamura, J., Prabaharan, S.R.S. (2012). Fabrication and Electrochemical Properties of All Solid State Lithium Battery Based on PVA–PVP Polymer Blend Electrolyte. In: Sathiyamoorthy, S., Caroline, B., Jayanthi, J. (eds) Emerging Trends in Science, Engineering and Technology. Lecture Notes in Mechanical Engineering. Springer, India. https://doi.org/10.1007/978-81-322-1007-8_52
Download citation
DOI: https://doi.org/10.1007/978-81-322-1007-8_52
Published:
Publisher Name: Springer, India
Print ISBN: 978-81-322-1006-1
Online ISBN: 978-81-322-1007-8
eBook Packages: EngineeringEngineering (R0)