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Materials and Measurements in Molecular Electronics pp 70–84Cite as

Microscopic and Anisotropic Dynamics of Spin Carriers with/without Charge

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 81))

Abstract

Electron spin resonance (ESR) studies are reviewed, specifically focusing on an experimental parameter of frequency applied to organic conductive materials. By analyzing the ESR linewidth and/or the spin-lattice relaxation rate measured in a wide frequency range such as several MHz to 24 GHz, one can obtain a frequency spectrum of spin motion that gives characteristic parameters of such motion, anisotropic diffusion rates. The first example is a dynamics of so-called “neutral soli-ton” in trans-polyacetylene, which is a topological defect having spin half but no charge. In the case of polarons and/or conduction electrons in conducting materials, the dynamics of spin is equivalent to that of the charged carriers responsible for the electrical conduction. Polyaniline (PANI) and polythiophene (PT) are reviewed as examples of the conducting case with a quasi-one-dimensional electronic state. Recent development of this technique suggesting a new relaxation mechanism will be briefly mentioned.

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Author information

Authors and Affiliations

  1. Dept. of Phys., Tokyo Metropolitan University, Hachi-oji, Tokyo, 192-03, Japan

    Kenji Mizoguchi

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  1. Kenji Mizoguchi
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Editors and Affiliations

  1. Electrotechnical Laboratory, University of Tsukuba, Tsukuba, Ibaraki, 305, Japan

    Koji Kajimura

  2. Electrotechnical Laboratory, Tsukuba, Ibaraki, 305, Japan

    Shin-ichi Kuroda

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© 1996 Springer-Verlag Tokyo

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Mizoguchi, K. (1996). Microscopic and Anisotropic Dynamics of Spin Carriers with/without Charge. In: Kajimura, K., Kuroda, Si. (eds) Materials and Measurements in Molecular Electronics. Springer Proceedings in Physics, vol 81. Springer, Tokyo. https://doi.org/10.1007/978-4-431-68470-1_6

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  • DOI: https://doi.org/10.1007/978-4-431-68470-1_6

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  • Print ISBN: 978-4-431-68472-5

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