π-d interaction in phthalocyanine conductors

  • Kyuya Yakushi
  • Toshihiro Hiejima
  • Hideo Yamakado
Part of the Springer Proceedings in Physics book series (SPPHY, volume 81)


Partially oxidized phthalocyanine conductors such as CoPc(AsF6)0.5 and NiPc(AsF6)0.5consist of one-dimensional double chain comprising a transition-metal and organic macrocycle chains. Each of these chains generates a narrow d-band and a wide π-band. The d-band is located near the Fermi level of the π-conduction-band. The interplay between these π- and d-bands will be introduced. The first examples of the interplay is the influence of the magnetic moments of unpaired d-electrons at the Co site to the itinerant π-holes on Pc chain. The exchange coupling with these magnetic moments suppresses the coherent motion of π-holes in CoPc(AsF6)0.5. This conclusion was derived from the comparative study of the isostructural conductors, non-magnetic NiPc(AsF6)0.5 and magnetic CoPc(AsF6)0.5. Another example is the transfer of holes from π-to d-band which is induced by high pressure. This charge transfer occurs at 0.5 GPa and continues up to 6 GPa in NiPc(AsF6)0.5.. The same phenomenon was observed in CoPc(AsF6)0.5 as well. A metal-nonmetal transition is induced by the pressure at which the charge transfer begins in NiPc(AsF6)0.5.


Pressure Dependence Interband Transition Plasmon Absorption Counter Anion Organic Conductor 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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Copyright information

© Springer-Verlag Tokyo 1996

Authors and Affiliations

  • Kyuya Yakushi
    • 1
  • Toshihiro Hiejima
    • 1
  • Hideo Yamakado
    • 1
  1. 1.Institute for Molecular Science and Graduate University for Advanced StudiesOkazaki, Aichi 444Japan

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