Abstract
In the basic research of Langmuir-Blodgett (LB) films, most of the difficulties to deduce the inherent structural and physical properties come from the existence of many small regions with differing orientation as two dimensional (2D) domain plates in each monolayer. To overcome such difficulties we emphasize a strategy of studying the single crystal and the LB films which have the identical molecular organization. As an example, we show a series of comparative studies on a stable conducting LB films of [EDT-TTF(SC18)2]2I3 and its single crystal. The success of growth of the single crystals leads to a proposal of possible 3D model of molecular organization and clarification of the electronic states responsible for the conductivity.
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Izumi, M., Ohnuki, H. (1996). Comparative Study on Langmuir-Blodgett Films and Crystals based on TTF Derivatives with Long Alkyl Chains. In: Kajimura, K., Kuroda, Si. (eds) Materials and Measurements in Molecular Electronics. Springer Proceedings in Physics, vol 81. Springer, Tokyo. https://doi.org/10.1007/978-4-431-68470-1_10
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DOI: https://doi.org/10.1007/978-4-431-68470-1_10
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