Abstract
X-ray photoelectron spectra (XPS) of Cu 2p have been studied for oxygen- and air-sintered samples of Bi2(La,Pr)0.5Ca2.5Cu2Oy and Bi2Nd0.5Ca2.5Cu2Oy. We estimated the number of Cu 3d electrons, n d , and charge transfer energy, Δ, from these results. We point out the possibility that the difference of T C between these compounds with the same doped hole concentrations is associated with the difference of n d . The role of the Cu 3d – O2p charge transfer in superconductivity is discussed.
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© 1991 Springer-Verlag Tokyo
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Ikeda, K., Munakata, F., Itti, R., Kawano, T., Yamauchi, H., Koshizuka, N. (1991). Photoemission Study of Bi2Nd0.5Ca2.5Cu2Oy and Bi2(La,Pr)0.5Ca2.5Cu2Oy Superconductors. In: Kajimura, K., Hayakawa, H. (eds) Advances in Superconductivity III. Springer, Tokyo. https://doi.org/10.1007/978-4-431-68141-0_18
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DOI: https://doi.org/10.1007/978-4-431-68141-0_18
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-68143-4
Online ISBN: 978-4-431-68141-0
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