Preparative and Structural Studies on Various Substitutions in the Bi-Sr-Ca-Cu-O System

Wenjie, Zhu; Fengxiang, Chen; Neng, Li; Hongyu, Li; Bingxiong, Lin; Youqi, Tang

doi:10.1007/978-4-431-68117-5_45

Zhu Wenjie³,
Chen Fengxiang³,
Li Neng³,
Li Hongyu³,
Lin Bingxiong³ &
…
Tang Youqi³

29 Accesses

Abstract

The samples with the norminal compositions of Bi_1.8 M_0.2 Sr₂ Ca₂ Cu₃ Oy(M = Pb, In, Sb, Nb) and Bi_1.7 Pb_0.2 M_0.1 Sr₂ Ca₂ Cu₃ Oy(M=In, Sb, Nb) have been prepared and investigated. Only the statistical substitution of lead for bismuth results in the formation of the 110K phase. In the crystal structures of two homogeneous phases Bi_1.8 Pb_0.2 Sr₂ Ca₂ Cu₃ O₁₀ and Bi_1.7 Pb_0.2 In_0.1 Sr₂ Ca₂ Cu₃ O₁₀, adjacent bismuth layers with one oxygen layer in between display a perfect Aurivillius type structure, and the structural unit (O₂Cu)Ca(CuO₂)Ca(CuO₂) shifts teragonality.

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Authors and Affiliations

Institute of Physical Chemistry, Peking University, Beijing, 100871, China
Zhu Wenjie, Chen Fengxiang, Li Neng, Li Hongyu, Lin Bingxiong & Tang Youqi

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Zhu Wenjie
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Chen Fengxiang
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Li Neng
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Li Hongyu
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Lin Bingxiong
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Tang Youqi
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Editors and Affiliations

Department of Physics, Kyoto University, Kyoto, 606, Japan
Takehiko Ishiguro
Electrotechnical Laboratory, Tsukuba, 305, Japan
Koji Kajimura

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Wenjie, Z., Fengxiang, C., Neng, L., Hongyu, L., Bingxiong, L., Youqi, T. (1990). Preparative and Structural Studies on Various Substitutions in the Bi-Sr-Ca-Cu-O System. In: Ishiguro, T., Kajimura, K. (eds) Advances in Superconductivity II. Springer, Tokyo. https://doi.org/10.1007/978-4-431-68117-5_45

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DOI: https://doi.org/10.1007/978-4-431-68117-5_45
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-68119-9
Online ISBN: 978-4-431-68117-5
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