Formation of the High Tc Phase of Bi-Pb-Sr-Ca-Cu-O Superconductors

  • Satoshi Koyama
  • Utako Endo
  • Tomoji Kawai
Conference paper


Codecomposition of mixed nitrates of Bi, Pb, Sr, Ca and Cu around 830°C under low oxygen pressure led to the formation of a high Tc superconducting phase of Bi-Pb-Sr-Ca-Cu-O with Tc(zero) at 107.0K. The best starting compositions were in the region close to Bi1.84Pb0.34Sr2Ca2C3Oy with a little excess of Ca and Cu. In this region, the samples showed the absence of the 80K and semiconducting phase, and there was no indication of impurities at all. The reaction under low oxygen pressure has an effect to lower the temperature with broad ranges to render the high Tc phase.


Oxygen Pressure Mixed Nitrate 110K Phase Daikin Industry Conventional Solid Reaction 
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Copyright information

© Springer Japan 1989

Authors and Affiliations

  • Satoshi Koyama
    • 1
  • Utako Endo
    • 1
  • Tomoji Kawai
    • 2
  1. 1.Research and Development Department, Chemical DivisionDaikin Industries, Ltd.Settsu, 566Japan
  2. 2.The Institute of Scientific and Industrial ResearchOsaka UniversityIbaraki, 567Japan

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