Abstract
Electron energy-loss spectroscopy (EELS) is one of the most popular analytical electron microscopy techniques, similar to energy dispersive X-ray spectroscopy (EDS). In the past, EELS was thought to be effective in compositional analysis only for light elements but useless in general for quantitative analysis in comparison with EDS. However, the accuracy of analysis by EELS is much improved recently owing to high performance of the detector and usage of a FEG. Furthermore, an energy-filter system that provides energy-filtered images has been installed on an electron microscope. Thus, currently EELS has attracted much attention for new applications such as elemental mapping and background subtraction in electron diffraction patterns.
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References
Shuman H (1981) Parallel recording of electron energy loss spectra. Ultramicroscopy 6:163
Krivanek OL, Ahn CC, Keeney RB (1987) Parallel detection electron spectrometer using quadrupole lenses. Ultramicroscopy 22:103
Terauchi M, Kuzuo R, Satoh F, Tanaka M, Tsuno K, Ohyama J (1991) Performance of a new highresolution electron energy-loss spectroscopy microscope. Microsc Microanal Microstruct 2:351
Lee C-W, Ikematsu Y, Shindo D (2002) Measurement of mean free paths for inelastic electron scattering of Si and Si02. J Electron Microsc, p 143
Oikawa T, Bando Y, Hosoi J, Kokubo Y (1985) Advantages of a HVEM in electron energy loss spectroscopy: in situ experiments with high voltage electron microscopes. In: Proceeding of the international symposium on “behavior of lattice imperfections in materials-in situ experiments with HVEM”, Osaka, 409
Egerton RF (1978) Quantitative energy-loss spectroscopy. In: Johari O (ed) Scanning electron microscopy. SEM, Chicago, 1, p 133
Isaacson MS, Silcox J (1976) Report of a workshop on analytical electron microscopy held at Cornell University. Ultramicroscopy 2:89
Suenaga K, Ténce M, Mory C, Colliex C, Kato H, Okazaki T, Shinohara H, Hirahara K, Bandow S, Iijima S (2000) Element-selective single atom imaging. Science 290:2280
Egerton RF (1996) Electron energy-loss spectroscopy in the electron microscope, 2nd edn. Plenum, New York
Raether H (1980) Excitation of plasmons and interband transitions by electrons. In: Springer tracts in modern physics, vol 88 Springer, Berlin Heidelberg New York
Auerhammer JM, Rez P (1989) Dipole-fobidden excitations in electron-energy-loss spectroscopy. Phys Rev B40:2024
Jones W, Sparrow TG, Williams BG, Herley PJ (1984) Evidence for the formation of single crystals of sodium metal during the decomposition of sodium aluminum hydride: an electron microscopic study. Mater Lett 2:377
Kunz C (1966) Messung Charakteristischer Energieverluste von Elektronen an leichtoxydierbaren Metallen im Ultrahochvakuum. Z Phys 196:311
Kloos T (1973) Plasmaschwingungen in Al, Mg, Li, Na and K angeregt durch schnelle Elektronen. Z Phys 265:225 15.
Daniels J, Festenberg CV, Raether H, Zeppenfeld K (1970) Optical constants of solids by electron spectroscopy. In: Springer tracts in modern physics, vol 54 Springer, Berlin Heidelberg New York, p 78
Zeppenfeld K, Raether H (1966) Energieverluste von 50 keV-Elektronen an Ge und Si. Z Phys 193:471
Sueoka O (1965) Plasma oscillation of electrons in Be, Mg, Al, Si, Ge, Sn, Sb and Bi. J Phys Soc Jpn 20:2203
Aiyama T, Yada K (1974) Plasmon damping in Be, Mg, Al, Si, Ge and Sn. J Phys Soc Jpn 36:1554
Oikawa T, Hosoi J, Inoue M, Harada Y (1982) Applications of electron energy analyzer. JEOL News 20E:8
Nishino D, Nakafuji A, Yang J-M, Shindo D (1998) Precise morphology analysis on platelet-type hematite particles by transmission electron microscopy. ISIJ Int 38:1369
Egerton RF (1980) Instrumentation and software for energy-loss microanalysis. In: Johari O (ed) Scanning electron microscopy. SEM, Chicago, 1, p 41
Lee Y- S, Murakami Y, Shindo D, Oikawa T (2000) Effect of scattering angle on energy loss near-edge structure of h-BN. Mater Trans JIM 41:555
Ichinose H, Zhang Y, Ishida Y, Ito K, Nakanose M (1996) Morphology, atomic structure and electron structure of artificial diamond grain boundary. JEOL News 32E:16
Hosoi J, Oikawa T, Kokubo Y (1985) Computed deconvolution in electron energy loss spectroscopy (EELS). J Electron Microsc 34:73
Shindo D, Ohishi K, Hiraga K, Syono Y, Hojou K, Furuno S (1991) Oxygen K-edge fine structure of La2-xMxCuO4, (M = Sr, Ba and Ca) studied by electron energy loss spectroscopy. Mater Trans JIM 32:872
Murakami Y, Shindo D, Chiba H, Kikuchi M, Syono Y (1999) Charge ordering in Bi1-xCaxMnO3 (x > 0.75) studied by electron-energy-loss spectroscopy. Phys Rev B59:6395
Pearson DH, Fultz B, Ahn CC (1988) Measurements of 3d state occupancy in transition metals using electron energy loss spectrometry. Appl Phys Lett 53:1405
Murakami Y, Shindo D, Otsuka K, Oikawa T (1998) Electronic structure changes associated with a martensitic transformation in Ti50Ni48Fe2 alloy studied by electron energy-loss spectroscopy. J Electron Microsc 47:301
Shindo D, Hiraga K, Tsai A-P, Chiba A (1993) Cu L2,3 white lines of Cu compounds studied by electron energy loss spectroscopy. J Electron Microsc 42:48
Zanchi G, Perez JP, Sevely J (1975) Adaptation of a magnetic filtering device on a one megavolt electron microscope. Optik 43:495.
Castaing R, Hennequin JF, Henry L, Slodgian G (1967) The magnetic prism as an optical system. In: Septier A (ed) Focusing of charged particle, Academic Press, New York, p 265
Krivanek OL, Gubbens AJ, Dellby N (1991) Developments in EELS instrumentation for spectroscopy and imaging. Microsc Microanal Microstrct 2:315
Hashimoto H, Makita Y, Nagaoka N (1992) Atomic structure images formed by core loss electrons. In: Bailey GW, Bentley J, Small JA (eds) Proceedings of the 50th Annual EMSA Meeting, Boston, p 1194
Ajika N, Hashimoto H, Endo H, Yamaguchi K, Tomita M, Egerton RF (1983) Construction of analyzer for energy-filtered lattice image. In: Proceedings of the Japanese Society of Electron Microscopy, annual meeting, p 134 (in Japanese)
Taya S, Taniguchi Y, Nakazawa E, Usukura J (1996) Development of γ--type energy filtering TEM. J Electron Microsc 45:307
Oikawa T, Sasaki H, Matsuo T, Kokubo Y (1982) Elemental filtergrams obtained by means of electron energy analyzer combined with image storage system. In: Bailey GW (ed) Proceedings of the 40th annual EMSA meeting, Washington, DC, p 736
Segawa M, Taniyama A, Shindo D (1998) HREM observation of the interface between Laves-phases and matrix phases in Inconel 718 by using a highvoltage electron microscope. ISIJ Int 38:1375
Sears VF, Shelley SA (1991) Debye-Waller factor for elemental crystals. Acta Cryst A47:441
Ferrel RA (1956) Angular dependence of the characteristic energy loss of electrons passing through metal foils. Phys Rev 101:554
Spence JCH, Zuo JM (1992) Electron microdiffraction. Plenum, New York
Gomyo A, Makita K, Hino I, Suzuki T (1994) Observation of a new ordered phase in AlxIn1_xAs alloy and relation between ordering structure and surface reconstruction during molecular-beamepitaxial growth. Phys Rev Lett 72:673
Shindo D, Spence JCH, Gomyo A (1995) Evaluation of electron diffuse scattering by energy filtering. In: Shin KS, Yoon JK, Kim SJ (eds) Proceedings of the 2nd Pacific Rim International Conference on advanced materials and processing. Korean Institute of Metals and Materials, Seoul, p 1077
Shindo D, Gomyo A, Zuo J-M, Spence JCH (1996) Short-range ordered structure of Ga0.47In0.53As studied by energy-filtered electron diffraction and HREM. J Electron Microsc 45:99
Murakami Y, Shindo D (1999) Lattice modulation preceding to the R-phase transformation in a Ti50Ni48Fe2 alloy studied by TEM with energyfiltering. Mater Trans JIM 40:1092
Shindo D, Murakami Y (2000) Advanced transmission electron microscopy study on premartensitic state of Ti50Ni48Fe2. Sci Technol Adv Mater 1:117
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Shindo, D., Oikawa, T. (2002). Electron Energy-Loss Spectroscopy. In: Analytical Electron Microscopy for Materials Science. Springer, Tokyo. https://doi.org/10.1007/978-4-431-66988-3_3
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DOI: https://doi.org/10.1007/978-4-431-66988-3_3
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