Electrochemical Route to Fluorinated Kethoesters

  • B. I. Martynov
  • A. A. Stepanov
Conference paper


Electrochemical reduction of organic fluorohalogen compounds in the presence of trimethylchlorosilane enables to obtain the fluorinated silanes in synthetic yields. Trifluoroacetic acid esters at the same conditions forms condensation product — pentafluoroacetoacetic ester.


Current Efficiency Electrochemical Reduction State Research Institute Galvanostatic Condition Electrochemical Generation 
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Copyright information

© Springer Japan 1998

Authors and Affiliations

  • B. I. Martynov
    • 1
  • A. A. Stepanov
    • 2
  1. 1.State Research Institute of Organic Chemistry & TechnologyMoscowRussia
  2. 2.A.N.Nesmeyanov Institute of Organoelement Compounds Russian Academy of SciencesMoscowRussia

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