Abstract
Electrochemical reduction of alicyclic vinyl triflates (1) under an atmospheric pressure of carbon dioxide with a Pt cathode and a Mg anode resulted in the cleavage of an O-S bond of 1 to give the corresponding β-keto carboxylic acids (2) in good yields.
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References
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© 1998 Springer Japan
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Kamekawa, H., Senboku, H., Tokuda, M. (1998). Synthesis of β-Keto Acids by Electrochemical Carboxylation of Vinyl Triflates. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_75
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DOI: https://doi.org/10.1007/978-4-431-65924-2_75
Publisher Name: Springer, Tokyo
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