Electroreductive Intermolecular Coupling of Unsaturated Compounds

  • Naoki Kise
  • Syun-ichiro Mashiba
  • Nasuo Ueda
Conference paper


The stereoselectivities of electroreductive hydrocoupling of chiral N-trans-cinnamoyl-2-oxazolidones are significantly influenced by supporting electrolyte.


Cinnamic Acid Dimethyl Ester Lithium Salt Cinnamic Acid Derivative Electroorganic Synthesis 
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References and Notes

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    Utley, J. H. P.; Güllü, M.; Motevalli, M. J. Chem. Soc. Perkin Trans. 1, 1995, 1961.Google Scholar
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    Fussing, I.; Güllü, M.; Hammerrich, O.; Hussain, A.; Nielsen, M. F.; Utley, J. M. P. J. Chem. Soc. Perkin Trans. 2, 1996, 649.CrossRefGoogle Scholar
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    Kise, N.; Echigo, M.; Shono, T. Tetrahedron Lett. 1994, 35, 189.Google Scholar
  8. 3.
    Optimizations were carried out using the PM3 method in the MOPAC 93 program.Google Scholar
  9. 4.
    The COSMO (Conducter-like Screening Model) method is implemented into the MOPAC 93.Google Scholar
  10. 5.
    Calculation with the AM1 method also resulted the same tendency.Google Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Naoki Kise
    • 1
  • Syun-ichiro Mashiba
    • 1
  • Nasuo Ueda
    • 1
  1. 1.Department of Biochemistry, Faculty of EngineeringTottori UniversityTottori 680Japan

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