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Electroreductive Intermolecular Coupling of Unsaturated Compounds

  • Naoki Kise
  • Syun-ichiro Mashiba
  • Nasuo Ueda
Conference paper

Abstract

The stereoselectivities of electroreductive hydrocoupling of chiral N-trans-cinnamoyl-2-oxazolidones are significantly influenced by supporting electrolyte.

Keywords

Cinnamic Acid Dimethyl Ester Lithium Salt Cinnamic Acid Derivative Electroorganic Synthesis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References and Notes

  1. 1.(a)
    Klemm, L. H.; Olson, D. R. J. Org . Chem. 1973, 58, 3390.Google Scholar
  2. (b).
    Kanetsuna, H.; Nonaka, T. Denki Kagaku 1981, 49, 526.Google Scholar
  3. (c).
    Smith, C. Z.; Utley, H. P. J. Chem. Soc. Chem. Commun. 1981, 492.Google Scholar
  4. (d).
    Nishiguchi, I.; Hirashima, T. Angew. Chem. Int. Ed. Engl. 1983, 22, 52.CrossRefGoogle Scholar
  5. (e).
    Utley, J. H. P.; Güllü, M.; Motevalli, M. J. Chem. Soc. Perkin Trans. 1, 1995, 1961.Google Scholar
  6. (f).
    Fussing, I.; Güllü, M.; Hammerrich, O.; Hussain, A.; Nielsen, M. F.; Utley, J. M. P. J. Chem. Soc. Perkin Trans. 2, 1996, 649.CrossRefGoogle Scholar
  7. 2.
    Kise, N.; Echigo, M.; Shono, T. Tetrahedron Lett. 1994, 35, 189.Google Scholar
  8. 3.
    Optimizations were carried out using the PM3 method in the MOPAC 93 program.Google Scholar
  9. 4.
    The COSMO (Conducter-like Screening Model) method is implemented into the MOPAC 93.Google Scholar
  10. 5.
    Calculation with the AM1 method also resulted the same tendency.Google Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Naoki Kise
    • 1
  • Syun-ichiro Mashiba
    • 1
  • Nasuo Ueda
    • 1
  1. 1.Department of Biochemistry, Faculty of EngineeringTottori UniversityTottori 680Japan

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