Abstract
The stereoselectivities of electroreductive hydrocoupling of chiral N-trans-cinnamoyl-2-oxazolidones are significantly influenced by supporting electrolyte.
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Optimizations were carried out using the PM3 method in the MOPAC 93 program.
The COSMO (Conducter-like Screening Model) method is implemented into the MOPAC 93.
Calculation with the AM1 method also resulted the same tendency.
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Kise, N., Mashiba, Si., Ueda, N. (1998). Electroreductive Intermolecular Coupling of Unsaturated Compounds. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_66
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DOI: https://doi.org/10.1007/978-4-431-65924-2_66
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